scholarly journals The crystal structures of the rare earth binary gallides

1984 ◽  
Vol 40 (a1) ◽  
pp. C243-C243
Author(s):  
E. I. Hladyshevsky ◽  
Ya. P. Yarmolyuk ◽  
Yu. N. Hryn
Keyword(s):  
Rare Earth ◽  
Crystal Structures ◽  
The Rare Earth

Structure and stereochemistry in 'f-block' complexes of high coordination number. VIII. The [M(unidentate)9] system. Crystal structures of [M(OH2)9] [CF3SO3]3, M = La, Gd, Lu, Y

1983 ◽  
Vol 36 (3) ◽  
pp. 483 ◽  
Author(s):  
JM Harrowfield ◽  
DL Kepert ◽  
JM Patrick ◽  
AH White
Keyword(s):  
Rare Earth ◽  
Crystal Structures ◽  
Ethyl Sulfate ◽  
Rare Earth Atom ◽  
Repulsion Energy ◽  
High Coordination Number ◽  
Tricapped Trigonal Prism ◽  
Cell Dimensions ◽  
High Coordination ◽  
The Rare Earth

The crystal structures of the nonahydrates of the rare earth trifluoromethanesulfonates, [M(OH2)9] [CF3SO3]3 have been determined at 295 K for the configurations fO, f7, f14, i.e. M = La, Gd, Lu, together with that of the yttrium analogue. The structures are similar to those of the rare earth ethyl sulfate nonahydrates, belonging to space group P6,/m (hexagonal) with cell dimensions a ≈ 13.7, c ≈ 7.5 �, Z 2, with the coordination about the rare earth atom being a tricapped trigonal prism. The structure is compared with that found from repulsion energy calculations.

scholarly journals Darstellung und Struktur ternärer Silizide und Germanide des Lithiums mit den Seltenen Erden Y und Gd im Fe2P-Typ / Preparation and Crystal Structure of Ternary Silicides and Germanides of Lithium with the Rare-Earth-Metals Y and Gd in the Fe2P-Type Structure

1979 ◽  
Vol 34 (8) ◽  
pp. 1057-1058 ◽  
Author(s):  
Axel Czybulka ◽  
Günter Steinberg ◽  
Hans-Uwe Schuster
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Crystal Structures ◽  
Rare Earth Metals ◽  
Type Structure ◽  
Space Group ◽  
X Ray ◽  
P Type ◽  
Type Lattice ◽  
The Rare Earth

In the systems Li-M-X = (M = Y, Gd; X = Si, Ge) the compounds LiYSi, LiYGe and LiGdGe were prepared. Their crystal structures were determined by X-ray investigations. They crystallize hexagonally (space group P 6̄2m), and a C22-(Fe2P-type) lattice was found

scholarly journals Flux Synthesis, Crystal Structures, and Magnetic Ordering of the Rare-Earth Chromium(II) Oxyselenides RE2CrSe2O2 (RE = La–Nd)

2017 ◽  
Vol 56 (4) ◽  
pp. 2241-2247 ◽  
Author(s):  
Simon Peschke ◽  
Valentin Weippert ◽  
Anatoliy Senyshyn ◽  
Martin Johann Mühlbauer ◽  
Oliver Janka ◽  
...  
Keyword(s):  
Rare Earth ◽  
Crystal Structures ◽  
Magnetic Ordering ◽  
Flux Synthesis ◽  
The Rare Earth

The 1-N amides 1∞[Eu2(Pyr)4(PyrH)2(NH3)] · PyrH and [Yb2(Cbz)4(NH2)2(NH3)4] · 3CbzH: Distinctions in the crystal structures, thermal properties and ammonolysis tendency

2005 ◽  
Vol 220 (2/3) ◽  
Author(s):  
Klaus Müller-Buschbaum ◽  
Caterina C. Quitmann
Keyword(s):  
Thermal Properties ◽  
Rare Earth ◽  
Low Temperature ◽  
Crystal Structures ◽  
Liquid Ammonia ◽  
Rare Earth Metals ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
The Rare Earth

AbstractThe low-temperature oxidation of the rare earth metals europium and ytterbium with the 1-N amines pyrrole and carbazole in liquid ammonia gave the pyrrolate

Structural trends and the electronic structure of the rare-earth oxomolybdates RMo5O8 (R = La, Ce, Pr, Nd, Sm, Eu and Gd) containing chains of bioctahedral Mo10 clusters

2003 ◽  
Vol 59 (4) ◽  
pp. 472-478 ◽  
Author(s):  
P. Gougeon ◽  
P. Gall ◽  
J.-F. Halet ◽  
R. Gautier
Keyword(s):  
Crystal Structure ◽  
Electronic Structure ◽  
Rare Earth ◽  
Single Crystal ◽  
Crystal Structures ◽  
Monoclinic Space Group ◽  
Space Group ◽  
Theoretical Investigations ◽  
Bonding Mode ◽  
The Rare Earth

The crystal structures of the rare-earth members of the series RMo5O8 (R = Ce to Eu) have been investigated and compared with those of the La and Gd members previously published in order to understand the influences of the size and the charge of the cation on the different Mo—Mo bonds. The RMo5O8 compounds crystallize in the monoclinic space group P21/c. Their crystal structure is characterized by bioctahedral Mo10 clusters forming extended chains. The results of our single-crystal studies show that the modification of charge predominantly affects the Mo—Mo bonds between the Mo10 clusters and, to a lesser extent, the intra-cluster distances, while the cationic size induces only small variations. Theoretical investigations confirm this statement and allow the understanding of the bonding mode in these compounds.

The crystal structures of the rare earth pyrosilicates

1970 ◽  
Vol 26 (5) ◽  
pp. 484-492 ◽  
Author(s):  
Yu. I. Smolin ◽  
Yu. F. Shepelev
Keyword(s):  
Rare Earth ◽  
Crystal Structures ◽  
The Rare Earth
Sign in / Sign up

Export Citation Format

Share Document