Структурные и электронные свойства нового соединения SrOs-=SUB=-2-=/SUB=-O-=SUB=-6-=/SUB=--=SUP=-*-=/SUP=-

It was shown theoretically that a new material SrOs2O6 can exist; the crystal structure of SrOs2O6 is formed by the layers of OsO6 octahedra having common edges and forming a honeycomb type lattice. The structural and electronic properties of SrOs2O6 were investigated by the first-principal calculations. An antiferromagnetic structure was found to be energetically favorable for the studied compound.

Impact of Silica Additions on the Phase Composition and Electrical Transport Properties of Ruddlesden-Popper La2NiO4+δ Mixed Conducting Ceramics

The present work explores the possibility of incorporation of silicon into the crystal structure of Ruddlesden-Popper La2NiO4+δ mixed conducting ceramics with the aim to improve the chemical compatibility with lanthanum silicate-based solid electrolytes. Ceramics with the nominal composition La2Ni1−ySiyO4+δ (y = 0, 0.02 and 0.05) were prepared by the glycine nitrate combustion technique and sintered at 1450 °C. While minor changes in the lattice parameters of the tetragonal K2NiF4-type lattice may suggest incorporation of a small fraction of Si into the Ni sublattice, combined XRD and SEM/EDS studies indicate that this fraction is very limited (≪2 at.%, if any). Instead, additions of silica result in segregation of apatite-type La10−xSi6O26+δ and La2O3 secondary phases as confirmed experimentally and supported by the static lattice simulations. Both total electrical conductivity and oxygen-ionic transport in La2NiO4+δ ceramics are suppressed by silica additions. The preferential reactivity of silica with lanthanum oxide opens a possibility to improve the compatibility between lanthanum silicate-based solid electrolytes and La2NiO4+δ-based electrodes by appropriate surface modifications. The promising potential of this approach is supported by preliminary tests of electrodes infiltrated with lanthanum oxide.

Optical lattice with spin-dependent sub-wavelength barriers

We analyze a tripod atom light coupling scheme characterized by two dark states playing the role of quasi-spin states. It is demonstrated that by properly configuring the coupling laser fields, one can create a lattice with spin-dependent sub-wavelength barriers. This allows to flexibly alter the atomic motion ranging from atomic dynamics in the effective brick-wall type lattice to free motion of atoms in one dark state and a tight binding lattice with a twice smaller periodicity for atoms in the other dark state. Between the two regimes, the spectrum undergoes significant changes controlled by the laser fields. The tripod lattice can be produced using current experimental techniques. The use of the tripod scheme to create a lattice of degenerate dark states opens new possibilities for spin ordering and symmetry breaking.

CURT1A and CURT1C mediate distinct stages of plastid conversion in Arabidopsis

The crystalline structure of prolamellar bodies (PLBs) and light-induced etioplasts-to-chloroplasts transformation have been investigated with electron microscopy methods. However, these studies suffer from chemical fixation artifacts and limited volumes of tomographic reconstruction. We have examined Arabidopsis thaliana cotyledon samples preserved by high-pressure freezing with scanning transmission electron tomography to visualize larger volumes in etioplasts and their conversion into chloroplasts. PLB tubules were arranged in a zinc blende-type lattice like carbon atoms in diamonds. Within 2 hours after illumination, the lattice collapsed from the PLB exterior and the disorganized tubules merged to form fenestrated sheets that eventually matured into lamellar thylakoids. These planar thylakoids emerging from PLBs overlapped or folded into grana stacks in PLBs’ vicinity. Since the nascent lamellae had curved membrane at their tips, we examined the localization of CURT1 proteins. CURT1A transcript was most abundant in de-etiolating cotyledon samples, and CURT1A concentrated at the peripheral PLB. In curt1a mutant etioplasts, thylakoid sheets were swollen and failed to develop stacks. In curt1c mutant, however, PLBs had cracks in their lattices, indicating that CURT1C contributes to cubic crystal growth under darkness. Our data provide evidence that CURT1A and CURT1C play distinct roles in the etioplast and chloroplast biogenesis.

A Quantum-Mechanical Study of Antiphase Boundaries in Ferromagnetic B2-Phase Fe2CoAl Alloy

In this study, we performed a quantum mechanical examination of thermodynamic, structural, elastic, and magnetic properties of single-phase ferromagnetic Fe2CoAl with a chemically disordered B2-type lattice with and without antiphase boundaries (APBs) with (001) crystallographic orientation. Fe2CoAl was modeled using two different 54-atom supercells with atoms on the two B2 sublattices distributed according to the special quasi-random structure (SQS) concept. Both computational models exhibited very similar formation energies (−0.243 and −0.244 eV/atom), B2 structure lattice parameters (2.849 and 2.850 Å), magnetic moments (1.266 and 1.274 μB/atom), practically identical single-crystal elastic constants (C11 = 245 GPa, C12 = 141 GPa, and similar C44 = 132 GPa) and auxetic properties (the lowest Poisson ratio close to −0.1). The averaged APB interface energies were observed to be 199 and 310 mJ/m2 for the two models. The studied APBs increased the total magnetic moment by 6 and 8% due to a volumetric increase as well as local changes in the coordination of Fe atoms (their magnetic moments are reduced for increasing number of Al neighbors but increased by the presence of Co). The APBs also enhanced the auxetic properties.

Optimization Design of Lattice Structures in Internal Cooling Channel with Variable Aspect Ratio of Gas Turbine Blade

Traditional cooling structures in gas turbines greatly improve the high temperature resistance of turbine blades; however, few cooling structures concern both heat transfer and mechanical performances. A lattice structure (LS) can solve this issue because of its advantages of being lightweight and having high porosity and strength. Although the topology of LS is complex, it can be manufactured with metal 3D printing technology in the future. In this study, an integral optimization model concerning both heat transfer and mechanical performances was presented to design the LS cooling channel with a variable aspect ratio in gas turbine blades. Firstly, some internal cooling channels with the thin walls were built up and a simple raw of five LS cores was taken as an insert or a turbulator in these cooling channels. Secondly, relations between geometric variables (height (H), diameter (D) and inclination angle(ω)) and objectives/functions of this research, including the first-order natural frequency (freq1), equivalent elastic modulus (E), relative density (ρ¯) and Nusselt number (Nu), were established for a pyramid-type lattice structure (PLS) and Kagome-type lattice structure (KLS). Finally, the ISIGHT platform was introduced to construct the frame of the integral optimization model. Two selected optimization problems (Op-I and Op-II) were solved based on the third-order response model with an accuracy of more than 0.97, and optimization results were analyzed. The results showed that the change of Nu and freq1 had the highest overall sensitivity Op-I and Op-II, respectively, and the change of D and H had the highest single sensitivity for Nu and freq1, respectively. Compared to the initial LS, the LS of Op-I increased Nu and E by 24.1% and 29.8%, respectively, and decreased ρ¯ by 71%; the LS of Op-II increased Nu and E by 30.8% and 45.2%, respectively, and slightly increased ρ¯; the LS of both Op-I and Op-II decreased freq1 by 27.9% and 19.3%, respectively. These results suggested that the heat transfer, load bearing and lightweight performances of the LS were greatly improved by the optimization model (except for the lightweight performance for the optimal LS of Op-II, which became slightly worse), while it failed to improve vibration performance of the optimal LS.