Dichloro(ethanol-κO){(E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazonato-κ3 N,N′,S}indium(III)

2007 ◽  
Vol 63 (3) ◽  
pp. m845-m846 ◽  
Author(s):  
Ying-Ju Fan ◽  
Le Wang ◽  
Jian-Ping Ma ◽  
Zhong-Xi Sun
Keyword(s):  
Title Complex ◽  
Enol Form ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Ethanol Molecule ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Cl Atoms

Reaction of indium(III) chloride with (E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazide afforded the title complex, [In(C8H9N4S)Cl2(C2H5OH)]. The ligand is in the enol form coordinating to the InIII atom through one S atom and two N atoms. The InIII atom is further coordinated by two Cl atoms and an ethanol molecule to complete a distorted octahedral coordination geometry.

Bis{(E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazonato-κ3 N,N′,S}gallium(III) nitrate

2007 ◽  
Vol 63 (11) ◽  
pp. m2663-m2663 ◽  
Author(s):  
Ying-Ju Fan ◽  
Jian-Ping Ma ◽  
Zhong-Xi Sun
Keyword(s):  
Title Complex ◽  
Enol Form ◽  
Octahedral Coordination ◽  
Nitrate Anion ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Charge Balancing

Reaction of gallium(III) nitrate with (E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazide (petc) afforded the title complex, [Ga(C8H9N4S)2]NO3. The title complex contains one GaIII cation and two enol-form petc anions, accompanied by one charge-balancing disordered nitrate anion. The petc is in the enol form, coordinating to the GaIII centre via one S atom and two N atoms. Thus, the GaIII centre assumes a distorted octahedral coordination geometry.

catena-Poly[[(di-2-pyridylamine-κ2 N,N′)copper(II)]-μ-benzene-1,4-dicarboxylato-κ4 O,O′:O′′,O′′′]

2006 ◽  
Vol 62 (5) ◽  
pp. m1079-m1080
Author(s):  
E Yang ◽  
Yi Zheng ◽  
Gu-Yong Chen
Keyword(s):  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Polymeric Complex ◽  
Distorted Octahedral Coordination ◽  
Π Stacking ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the title complex, [Cu(C8H4O4)(C10H9N3)] n , the benzene-1,4-dicarboxylate dianions bridge the CuII atoms to form polymeric complex chains. The CuII atom has a distorted octahedral coordination geometry. The centroid-to-centroid separation of 3.932 (2) Å indicates π–π stacking between nearly parallel pyridine rings.

scholarly journals Crystal structure of hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc

2014 ◽  
Vol 70 (12) ◽  
pp. 483-485
Author(s):  
Olgerd O. Shtokvish ◽  
Lyudmila I. Koval ◽  
Vasyl I. Pekhnyo
Keyword(s):  
Crystal Structure ◽  
Metal Cations ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Linear Fashion ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The title complex, systematic name hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ9O2,O4:O2;2:3κ9O2,O4:O2-trizinc, [Zn3(C8H13O3)6], synthesized fromtert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an approximateC3isymmetry. The three metal cations are arranged in a linear fashion, with the central ZnIIatom located on a centre of symmetry. All three metal cations exhibit a distorted octahedral coordination geometry. The terminal ZnIIcations are chelated by threetert-butyl acetoacetate ligands and these units are connected to the central ZnIIatom by the bridging enolate O atoms.

Bis{2-methoxy-6-[3-(methylamino)propyliminomethyl]phenolato}nickel(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2654-m2654 ◽  
Author(s):  
Chun-Bao Tang
Keyword(s):  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The title complex, [Ni(C12H17N2O2)2], possesses a crystallographically imposed center of symmetry occupied by the NiII ion. Each 2-methoxy-6-[3-(methylamino)propyliminomethyl]phenolate ligand coordinates the Ni atom in a tridentate mode [Ni—O = 2.0356 (18) Å, and Ni—N = 2.048 (2) and 2.184 (2) Å], resulting in a distorted octahedral coordination geometry.

Poly[[diaquacobalt(II)]-μ-2,5-dicarboxybenzene-1,4-dicarboxylato-μ-di-4-pyridylethene]

2006 ◽  
Vol 62 (7) ◽  
pp. m1506-m1507 ◽  
Author(s):  
Huan-Ran Xing ◽  
Xin-Hua Li
Keyword(s):  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the polymeric title complex, [Co(TBC)(BPE)(H2O)2] n [TBC is the 2,5-dicarboxybenzene-1,4-dicarboxylate dianion (C10H4O8) and BPE is 1,2-bis(4-pyridyl)ethene (C12H10N2)], the CoII ion, located on an inversion centre, assumes a distorted octahedral coordination geometry. The TBC and BPE ligands are located across individual inversion centres and bridge neighbouring CoII ions to form two-dimensional polymeric sheets.

scholarly journals trans-Dibromidotetrakis(pyridine-κN)ruthenium(II)

2013 ◽  
Vol 69 (2) ◽  
pp. m105-m105 ◽  
Author(s):  
Xiu-Li Wu ◽  
Ru-Fei Ye ◽  
Ai-Quan Jia ◽  
Qun Chen ◽  
Qian-Feng Zhang
Keyword(s):  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
A Site

The title complex, [RuBr2(C5H5N)4], contains two independent complex molecules in each of which the RuIIatom is located on a site of 222 symmetry and has a distorted octahedral coordination geometry with four pyridine N atoms and two Br atoms. The Br aroms aretrans-disposed as a result of symmetry.

scholarly journals Bis(dimethylamido-κN)bis[2-(pyrrol-2-ylmethyleneamino)-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl-κ2N,N′]vanadium(IV) toluene monosolvate

IUCrData ◽  
2016 ◽  
Vol 1 (9) ◽  
Author(s):  
Qiuwen Wang ◽  
Yihan Xiong ◽  
Xuebin Deng
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Schiff Base Ligands ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

Reaction of the Schiff base ligand (R)-2-(pyrrol-2-ylmethyleneamino)-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl with tetrakis(dimethylamido)vanadium in toluene gives the mononuclear VIVtitle complex, [V(C2H6N)2(C20H19N2O)2]·C7H8, which was isolated as red crystals. The VIVcation is coordinated by two monoanionic bidentate Schiff base ligands and two N atoms of two dimethylamide anions in a VN6distorted octahedral coordination geometry, in which two N atoms from the dimethylamide anions are placed in acis-configuration.

catena-Poly[[(2,2′-bipyridine-κ2 N,N′)manganese(II)]-μ-3,5-dinitro-2-oxidobenzoato-κ4 O,O′:O′,O 2]

2007 ◽  
Vol 63 (3) ◽  
pp. m737-m739 ◽  
Author(s):  
Wen-Dong Song ◽  
Xian-Xia Guo ◽  
Guo Rong-Fa
Keyword(s):  
Crystal Packing ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Bipyridine Ligand

In the title complex, [Mn(C7H2N2O7)(C10H8N2)] n , the MnII atom has a distorted octahedral coordination geometry, defined by two N atoms from the 2,2′-bipyridine ligand and four O atoms from two 3,5-dinitrosalicylate dianions. One carboxylate O atom acts as a bridge between adjacent metal centres to form a one-dimensional chain. The Mn...Mn distance is 4.315 (6) Å. The crystal packing is stabilized by intermolecular C—H...O hydrogen interactions.

μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]iron(III)} bis(hexafluoridophosphate)

2007 ◽  
Vol 63 (11) ◽  
pp. m2722-m2722 ◽  
Author(s):  
Ying Liu ◽  
Jianmin Dou ◽  
Dacheng Li ◽  
Xianxi Zhang
Keyword(s):  
Title Compound ◽  
Chloride Ion ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Amine Ligand

The dinuclear FeIII complex in the title compound, [Fe2Cl2O(C18H18N4)2](PF6)2, lies on a center of inversion. The FeIII atom is chelated by a tetradentate tris(2-pyridylmethyl)amine ligand via four N atoms and further coordinated by one chloride ion and one bridging oxide O atom, giving a distorted octahedral coordination geometry.

trans-Dichloro(1,4,8,11-tetraazacyclotetradecane)cobalt(III) chloride

2006 ◽  
Vol 62 (7) ◽  
pp. m1553-m1554 ◽  
Author(s):  
Radoslava Ivaniková ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Anna Mašlejová
Keyword(s):  
Equatorial Plane ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Site Symmetry ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the structure of the title compound, [CoCl2(C10H24N4)]Cl, the CoIII atom has a six-coordinate arrangement displaying distorted octahedral coordination geometry with the four N atoms from the 1,4,8,11-tetraazacyclotetradecane ring in the equatorial plane and two chloride anions in axial positions. The Co atom is located on a centre of inversion; the two Cl ions not bonded to Co are located on special positions of site symmetry \overline{4}.

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