Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ3-methanolato-tetra-μ2-methanolato-tetrairon(III)
2015 ◽
Vol 71
(8)
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pp. 976-979
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Keyword(s):
The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetylacetonate), crystallizes in the orthorhombicPbcaspace group with one half of the molecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C—H...Cl intermolecular interactions result in a two-dimensional layered structure parallel to theacplane.
2015 ◽
Vol 71
(8)
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pp. 965-971
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2019 ◽
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pp. 1808-1811
2015 ◽
Vol 71
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pp. 463-465
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2012 ◽
Vol 68
(8)
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pp. o2389-o2389
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2016 ◽
Vol 72
(2)
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pp. 124-127
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2015 ◽
Vol 71
(10)
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pp. 1255-1258
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2013 ◽
Vol 69
(9)
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pp. 1010-1012
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2014 ◽
Vol 1033-1034
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pp. 615-618
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2016 ◽
Vol 72
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pp. 616-619