Transient Thermal Model for Proton Exchange Membrane Fuel Cells

Author(s):  
Faycel Khemili ◽  
Mustapha Najjari ◽  
Sassi Ben Nasrallah

This paper presents one-dimensional transient thermal model for the membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEMFC). This model accounts for various heat generating mechanisms, including irreversible heat due to electrochemical reactions, entropic heat, and Joule heating arising from the electrolyte ionic resistance. Numerical results show the effects of many important factors on the transient phenomena in the PEMFC system.

Author(s):  
Britta Mayerhöfer ◽  
Konrad Ehelebe ◽  
Florian Dominik Speck ◽  
Markus Bierling ◽  
Johannes Bender ◽  
...  

Bipolar membrane|electrode interface water electrolyzers (BPEMWE) were found to outperform a proton exchange membrane (PEM) water electrolyzer reference in a similar membrane electrode assembly (MEA) design based on individual porous...


2018 ◽  
Vol 778 ◽  
pp. 275-282
Author(s):  
Noaman Khan ◽  
Saim Saher ◽  
Xuan Shi ◽  
Muhammad Noman ◽  
Mujahid Wasim Durani ◽  
...  

Highly porous ZIF-67 (Zeolitic imidazole framework) has a conductive crystalline metal organic framework (MOF) structure which was served as a precursor and template for the preparation of nitrogen-doped carbon nanotubes (NCNTs) electrocatalysts. As a first step, the chloroplatinic acid, a platinum (Pt) precursor was infiltrated in ZIF-67 with a precise amount to obtain 0.12 mg.cm-2 Pt loading. Later, the infiltrated structure was calcined at 700°C in Ar:H2 (90:10 vol%) gas mixture. Multi-walled nitrogen-doped carbon nanotubes were grown on the surface of ZIF-67 crystals following thermal activation at 700°C. The resulting PtCo-NCNTs electrocatalysts were deposited on Nafion-212 solid electrolyte membrane by spray technique to study the oxygen reduction reaction (ORR) in the presence of H2/O2 gases in a temperature range of 50-70°C. The present study elucidates the performance of nitrogen-doped carbon nanotubes ORR electrocatalysts derived from ZIF-67 and the effects of membrane electrode assembly (MEA) steaming on the performance of proton exchange membrane fuel cell (PEMFC) employing PtCo-NCNTs as ORR electrocatalysts. We observed that the peak power density at 70°C was 450 mW/cm2 for steamed membrane electrode assembly (MEA) compared to 392 mW/cm2 for an identical MEA without steaming.


Nanoscale ◽  
2017 ◽  
Vol 9 (20) ◽  
pp. 6910-6919 ◽  
Author(s):  
Yachao Zeng ◽  
Xiaoqian Guo ◽  
Zhiqiang Wang ◽  
Jiangtao Geng ◽  
Hongjie Zhang ◽  
...  

2010 ◽  
Vol 447-448 ◽  
pp. 775-779 ◽  
Author(s):  
Kurniawan Miftah ◽  
Wan Ramli Wan Daud ◽  
Edy Herianto Majlan

Stress applying in the stack of Proton Exchange Membrane Fuel Cell (PEMFC) effects the performance of PEMFC. High pressure in the Membrane Electrode Assembly (MEA) can reduce electrical contact resistance between bipolar plate and MEA. Nevertheless, too high pressure in the PEMFC can destroy MEA. Performance of PEMFC can be optimized by make proportional stress in the assembly of PEMFC. Finite element analysis (FEA) is one of method that can be used for analysis of stress in the PEMFC stack. However, setting of parameter in the analysis using FEA still became one of problem if realistic result must be desired. This paper reports setting of parameters in the stress analysis of PEMFC assembly using FEA method and study relationship of stress analysis with electrical contact resistance.


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