Alkaline cleavage of trihaloacetophenones
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Rate constants for haloform cleavage of trifluoro-, trichloro-, and tribromoacetophenone have been measured in aqueous solution; apparent second-order rate constants for reaction by the monoanion are in the ratio 1:5.3 × 1010:2.2 × 1013. Keywords: haloform cleavage, reactivity, trihalomethide leaving groups.
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1998 ◽
Vol 63
(7)
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pp. 1021-1030
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2017 ◽
Vol 95
(7)
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pp. 723-728
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1988 ◽
Vol 60
(02)
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pp. 247-250
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1999 ◽
Vol 64
(11)
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pp. 1770-1779
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1987 ◽
Vol 42
(9)
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pp. 1009-1013
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