Oil-soluble ionic liquid to lubricate silicon

2021 ◽  
pp. 135065012098488
Author(s):  
Waleed Al-Sallami ◽  
Pourya Parsaeian ◽  
Abdel Dorgham ◽  
Anne Neville
Keyword(s):  
Ionic Liquid ◽  
High Temperature ◽  
Friction And Wear ◽  
Tribological Performance ◽  
Considerable Reduction ◽  
Zinc Dialkyldithiophosphate ◽  
Lubrication Mechanism ◽  
Wear Coefficient ◽  
Wear Performance ◽  
Micro Scale

Trihexyltetradecylphosphonium bis(2-ethylhexyl)phosphate (phosphonium phosphate) ionic liquid is soluble in non-polar lubricants. It has been proposed as an effective anti-wear additive comparable to zinc dialkyldithiophosphate. Previously, phosphonium phosphate has shown a better anti-wear performance under some conditions such as high temperature. In this work, the tribological performance and the lubrication mechanism of phosphonium phosphate are compared with that of zinc dialkyldithiophosphate when lubricating silicon under various tribological conditions. This can lead to an understanding of the reasons behind the superior anti-wear performance of phosphonium phosphate under some conditions. A micro-scale study is conducted using a nanotribometer. The results show that both additives lead to a considerable reduction in both friction and wear coefficients. The reduction in the wear coefficient is mainly controlled by the formation of the tribofilm on the rubbing surfaces. Zinc dialkyldithiophosphate can create a thicker tribofilm, which results in a better anti-wear performance. However, the formation of a thicker film will lead to a faster depletion and thus phosphonium phosphate can provide better anti-wear performance when the depletion of zinc dialkyldithiophosphate starts.

A Brief Overview on High Temperature Friction and Wear

2010 ◽  
Author(s):  
Mustafa Bulut Coskun ◽  
Mahmut Faruk Aksit
Keyword(s):  
High Temperature ◽  
Gas Turbines ◽  
Friction And Wear ◽  
Oxidation Behavior ◽  
Elevated Temperatures ◽  
Wear Performance ◽  
Large Pressure ◽  
Higher Power ◽  
Vibratory Motion ◽  
Increasing Temperature

With the race for higher power and efficiency new gas turbines operate at ever increasing pressures and temperatures. Increased compression ratios and firing temperatures require many engine parts to survive extended service hours under large pressure loads and thermal distortions while sustaining relative vibratory motion. On the other hand, wear at elevated temperatures limits part life. Combined with rapid oxidation for most materials wear resistance reduces rapidly with increasing temperature. In order to achieve improved wear performance at elevated temperatures better understanding of combined wear and oxidation behavior of high temperature super alloys and coatings needed. In an attempt to aid designers for high temperature applications, this work provides a quick reference for the high temperature friction and wear research available in open literature. High temperature friction and wear data have been collected, grouped and summarized in tables.

The friction and wear performance of plasma-sprayed ceramic coatings at high temperature

Wear ◽  
1989 ◽  
Vol 129 (2) ◽  
pp. 223-234 ◽  
Author(s):  
Yinglong Wang ◽  
Yuansheng Jin ◽  
Shizhu Wen
Keyword(s):  
High Temperature ◽  
Friction And Wear ◽  
Ceramic Coatings ◽  
Wear Performance ◽  
Plasma Sprayed

Some Tribological Properties of an Ionic Liquid

2005 ◽  
Author(s):  
Takashi Nogi
Keyword(s):  
Ionic Liquid ◽  
Coefficient Of Friction ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Wear Performance ◽  
Lubrication Regime ◽  
Pin On Disc ◽  
The Coefficient Of Friction

Some tribological properties of an ionic liquid were investigated by using a pin-on-disc friction and wear tester. Due to running-in, the coefficient of friction of the ionic liquid decreased with time to a very low value of 0.02 which suggests that the lubrication regime was hydrodynamic at the end of the tests. Anti-wear performance of the ionic liquid was substantially comparable to a paraffin-based oil.

Tribological Properties of the Overbased Calcium Sulfonate Complex Greases Containing Different Lubricant Additives

2013 ◽  
Vol 645 ◽  
pp. 133-136
Author(s):  
Peng Qiao ◽  
Yan Qiu Xia ◽  
Xiang Yu Ge
Keyword(s):  
Ionic Liquid ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Sliding Friction ◽  
Tribological Performance ◽  
Mining Equipment ◽  
Wear Properties ◽  
Friction Tester ◽  
Calcium Sulfonate ◽  
Friction And Wear Properties

Overbased calcium sulfonate complex greases have excellent friction and wear properties and have been widely used in metallurgy and mining equipment. The effects and tribological performance of molybdenum dialkydithiocarbamate (MoDTC) and ionic liquid 1-(2-hydroxyethyl)-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ([C2OHMim][NTf2]), 1-(2-hydroxyethyl)-3-hexylimidazolium bis (trifluoromethylsulfonyl) imide ([C2OHHim][NTf2s]), added in overbased calcium sulfonate complex grease as additives were investigated by using reciprocating ball-on-disk sliding friction tester. The results showed that the two kinds of additives with a certain range of concentration could improve the tribological properties of greases.

HIGH-TEMPERATURE TRIBOLOGICAL BEHAVIORS OF TiNi/Ti2Ni ALLOYED LAYER ON SURFACE OF Ti6Al4V ALLOY

2017 ◽  
Vol 24 (03) ◽  
pp. 1750028 ◽  
Author(s):  
ZHENXIA WANG ◽  
HAIRUI WU ◽  
NAIMING LIN ◽  
XIAOHONG YAO ◽  
ZHIYONG HE ◽  
...  
Keyword(s):  
High Temperature ◽  
Friction Coefficient ◽  
Friction And Wear ◽  
Room Temperature ◽  
Alloyed Layer ◽  
Surface Alloying ◽  
Wear Performance ◽  
Ti6al4v Substrate ◽  
Oxidation Wear ◽  
Plasma Surface Alloying

Plasma surface alloying (PSA) technique was employed with nickel as incident ions to prepare the TiNi/Ti2Ni alloyed layer on surface of Ti6Al4V. High-temperature friction and wear performance of TiNi/Ti2Ni alloyed layer and the Ti6Al4V substrate were evaluated at 500[Formula: see text]C. The results indicated that the TiNi/Ti2Ni alloyed layer exhibited superior high-temperature wear performance. The variations of friction coefficient were the same rule but wear rate was lower compared to Ti6Al4V substrate. The wear mechanism of TiNi/Ti2Ni alloyed layer was mainly slight abrasion and the Ti6Al4V substrate showed abrasion and oxidation wear. The friction coefficient of the TiNi/Ti2Ni alloyed layer decreased from 0.90 to 0.50 with the increase of temperature from room temperature to 500[Formula: see text]C.

High Temperature Tribological Performance of Steel/Copper Friction Pairs Lubricated With a Modified C-WS2-(Fe3O4+TiN) Nanoadditives in Non-Copper Coated Solid Wires

2021 ◽  
Author(s):  
Hong Li ◽  
Jing Zhu ◽  
Yu Zhang ◽  
Zhuoxin Li ◽  
Bo Meng
Keyword(s):  
High Temperature ◽  
Friction And Wear ◽  
Ball Bearing ◽  
Tribological Performance ◽  
Wear Volume ◽  
Test Results ◽  
Nanoparticle Concentration ◽  
Tribological Test ◽  
Average Coefficient ◽  
Worn Surface

Abstract In this study, four kinds of nanoparticles: graphite, WS2, Fe3O4 and TiN were used as lubricating additives for steel/copper friction pairs to solve the problem of welding contact tube wear with non-copper-coated solid wire at high temperature. The single and composite nanoparticles have excellent dispersion stability in absolute ethanol under the action of the compound surfactant NaSTA+OA+PVP. The tribological test results showed that the maximum decrement with reference to the average coefficient of friction and wear volumes were measured with nanoparticle concentration in 1:1:1 ratio at 300℃. Compared with dry friction, the average friction coefficient and wear volume are reduced by 74.3% and 84.8%, respectively, which may be attributed to the formation of a stable tribo-film mainly composed of C-O, Fe2O3, WO3, TiO2, TiNxOy composite on the worn surface. Therefore, it is considered that the combined lubrication effects of the ball-bearing effect, repairing of worn surfaces and the tribo-film resulted in the lowest friction and wear.

scholarly journals Tribological Performance and Lubrication Mechanism of Alkylimidazolium Dialkyl Phosphates Ionic Liquids as Lubricants for Si3N4-Ti3SiC2Contacts

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Hai-zhong Wang ◽  
Dan Qiao ◽  
Song-wei Zhang ◽  
Da-peng Feng ◽  
Jin-jun Lu
Keyword(s):  
Ionic Liquids ◽  
Friction And Wear ◽  
Room Temperature ◽  
Tribological Performance ◽  
Load Carrying Capacity ◽  
Lubrication Mechanism ◽  
Experimental Conditions ◽  
Comparison Results ◽  
Protective Films ◽  
Load Carrying

The tribological performance of Si3N4-Ti3SiC2contacts lubricated by alkylimidazolium dialkyl phosphates ionic liquids (ILs) was investigated using an Optimol SRV-IV oscillating reciprocating friction and wear tester at room temperature (25°C) and 100°C. Glycerol and tributyl phosphate (TBP) were also selected as lubricants for Si3N4-Ti3SiC2contacts to study the tribological properties under the same experimental conditions for comparison. Results show that the alkylimidazolium dialkyl phosphates ILs were effective in reducing the friction and wear for Si3N4-Ti3SiC2contacts, and their performance is superior to that of glycerol and TBP. The SEM/EDS and XPS results reveal that the excellent tribological endurance of alkylimidazolium dialkyl phosphates ILs is mainly attributed to the high load-carrying capacity of the ILs and the formation of surface protective films consisting of TiO2, SiOx, titanium phosphate, amines, and nitrogen oxides by the tribochemical reactions.

Tribological Property of Biocarbon-Based Magnesium Silicate Hydroxide Nanocomposite as Lubricant Additive at Different Concentrations of Additive and Dispersant

2020 ◽  
Vol 143 (7) ◽  
Author(s):  
Rongqin Gao ◽  
Wenbo Liu ◽  
Qiuying Chang ◽  
Hao Zhang ◽  
Yang Liu
Keyword(s):  
Electron Microscope ◽  
Friction And Wear ◽  
Magnesium Silicate ◽  
Lubricant Additive ◽  
Tribological Performance ◽  
Third Body ◽  
Wear Performance ◽  
Optimal Value ◽  
Friction Surfaces ◽  
Scanning Electron

Abstract The tribological performance of biocarbon-based magnesium silicate hydroxide nanocomposite was examined as a lubricant additive by using a four-ball friction and wear tester. The effect of different concentrations of additives and dispersants was evaluated. The results show the nanocomposite exhibits excellent anti-wear performance and the optimal value is proposed when the content of additive and dispersant is 0.7 wt% and 3 wt% respectively. Through analyzing the friction surfaces by scanning electron microscope and Raman, we proposed the additives acted by a combination of “bearing,” “third body,” and sliding effect to achieve outstanding tribological properties.

Tribological performance and lubrication mechanism of new gemini quaternary phosphonium ionic liquid lubricants

2020 ◽  
pp. 114522 ◽  
Author(s):  
Qiangliang Yu ◽  
Chaoyang Zhang ◽  
Jiangbing Wang ◽  
Fengqi Fan ◽  
Zhiquan Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Tribological Performance ◽  
Lubrication Mechanism ◽  
Phosphonium Ionic Liquid

Friction and Wear Performance of Ti-Al Matrix Composites under 650°C

2014 ◽  
Vol 1004-1005 ◽  
pp. 501-504
Author(s):  
Xiu Ling Wang ◽  
Li Ying Yang ◽  
Shou Ren Wang ◽  
Yi Zhang ◽  
Hang Hai Yu
Keyword(s):  
High Temperature ◽  
Friction And Wear ◽  
Al Alloy ◽  
Matrix Composites ◽  
Alloy Matrix ◽  
Wear Performance ◽  
Al Matrix Composites ◽  
Hot Pressing Sintering ◽  
Al Matrix ◽  
Self Lubricating Composites

Ti-Al alloy matrix self-lubricating composites were fabricated by the method of high temperature hot pressing sintering. The friction and wear performance of self-lubricating Ti-Al matrix composites were studied at high temperature. The study found that the friction coefficient decreased with the increase of solid lubricant, CaF2 and BaF2 had played good lubrication. when the lubricant BaF2-CaF2 mass fraction was 10%, the wear rate of composites to the lowest, it was 0.29×10−7cm3N-1m-1in 650°C high temperature.

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