Electron Diffraction Investigation of the Molecular Structure of Trifluoromethanesulphonic acid (triflic acid)
1981 ◽
Vol 36
(8)
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pp. 917-918
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Keyword(s):
Abstract The molecular geometry of triflic acid is characterized by the following bond lengths (rg) and bond angles from an electron diffraction study: S-C 183.3±0.5, F-C 133.2 ±0.2, S=O 141.8±0.2, S-O 155.8±0.3 pm, S-C-F 110.3 ±0.3, F-C-F 108.6 ±0.3, C-S=O 105.4±1.1, C-S-O 102.3 ±2.3, O-S= O 109.9±0.7, and O=S=O 122.0 ±1.3°. The heavy-atom-skeleton is staggered with respect to the rotation about the S-C bond with an estimated barrier of rotation of 15 kJ mol-1.
1985 ◽
Vol 129
(1-2)
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pp. 69-79
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Keyword(s):
1974 ◽
Vol 20
(3)
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pp. 393-401
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Keyword(s):
Electron-diffraction study of the vapor-state molecular structure of trimethylamine-trimethylgallium
1987 ◽
Vol 28
(1)
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pp. 122-123
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Keyword(s):
1982 ◽
Vol 23
(2)
◽
pp. 292-294
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Keyword(s):
1986 ◽
Vol 144
(3-4)
◽
pp. 343-350
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2000 ◽
Vol 41
(2)
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pp. 217-230
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Keyword(s):
1979 ◽
Vol 56
◽
pp. 215-219
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