Investigation in the Vicinity of the Critical Point

1988 ◽  
Vol 43 (8-9) ◽  
pp. 734-740
Author(s):  
I. R. Yukhnovskii

Abstract It is shown that the events occuring in the vicinity of the critical point can be described in full by means of the collective variables with the appropriate reference system. The partition function containing the explicit form for the quartic measure density is obtained and integrated. Expressions for the critical temperature, critical density and critical chemical potential surfaces are calculated.

Author(s):  
A.D. Alekhin

A brief review of the results of studies of the effect of gravity in inhomogeneous substance near a critical state of a critical fluid (CF) has been presented in paper, based on the data of light scattering, refractometry, and slow neutron transmission methods.Based on these data, the field-altitude asymmetry of various properties of an inhomogeneous substance has been analyzed, namely order parameter Dr(z), scattered light intensity I(z), density gradient dr(z)/dz of the substance. It had been shown that the field-altitude asymmetries of the scattered light intensity I(z)~dr/dm(h) and the density gradient dr(z)/dz~dr/dh(h) of the substance are diametrically opposite. The different altitudinal asymmetry of these quantities dr/dh(h) and dr/dm(h) is explained in paper by the altitude asymmetry of the derivative of the chemical potential dm/dh, and hence with the altitude asymmetry of the chemical potential Dm(h)>>h in the external field h.To the present time, the physical mechanism of the altitude asymmetry of the gravity effect has not been studied. In this regard the mechanism of the formation of the vertical asymmetry of the internal critical field Dm(h) has proposed in paper to be associated with the kinetic characteristics of the inhomogeneous critical fluid: the diffusion coefficients D (h) and viscosity coefficients h(h), when the system passes from a homogeneous state to an inhomogeneous one under the action of an internal asymmetric fields |DU(z)|= |Dm(z)|>>|h=rcgz/Pc|. For this purpose, a high-pressure cell with a height L, with a critical filling density of the substance is considered in paper.It has been shown that when the system is under critical density filling by substance =rc  the critical level of substance z = 0 with the critical density rc  at the critical temperature Tc is realized above the middle of the sample with an inhomogeneous substance. Based on the literature data of P-V-T-measurements and the gravity effect in benzene and ethane, the values of the altitudinal change in the internal critical field have been found. It has been shown that the value of the critical internal inhomogeneous field in the inhomogeneous critical fluid significantly exceeds the variable of the Earth's gravity |DU(h,Tc)|= |Dm(h,Tc)>>|h|  It has been also shown that the magnitude of this field according to the cubic law depends on the critical temperature Tc of the substance: |Dm(z,Tc1)/|Dm(z,Tc2) » (Tc1/Tc2)3.


1954 ◽  
Vol 32 (2) ◽  
pp. 98-112 ◽  
Author(s):  
H. W. Habgood ◽  
W. G. Schneider

Extensive PVT measurements of xenon extending from 1.8° above the critical temperature to the critical temperature, and in a few cases to 4 ° below the critical temperature, have been carried out at densities ranging from somewhat above the critical density to well below. In order to make the corrections for hydrostatic head small and easily calculable, a bomb having a height of only 1.0 cm. was used in the present measurements. The previously reported value for the critical temperature 16.590° is confirmed. The critical density is estimated to be 1.099 ± 0.002 gm./ml. compared with 1.105 gm./ml. found previously. The critical pressure is found to be 57.636 ± 0.005 atm.The isotherms at temperatures above the temperatures of meniscus disappearance do not appear to have any flat portions. However, the critical isotherm is considerably flatter and broader over a range of densities than that corresponding to a van der Waals equation, and at the critical point the third and fourth derivatives of pressure with respect to volume appear to be zero.


2009 ◽  
Vol 642 ◽  
pp. 15-48 ◽  
Author(s):  
GUENTER AHLERS ◽  
BERND DRESSEL ◽  
JAECHUL OH ◽  
WERNER PESCH

Measurements of fluctuations and convection patterns in horizontal layers of fluid heated from below and near the onset of Rayleigh–Bénard convection (RBC) are reported under conditions where the fluid properties vary strongly over the temperature range ΔT = Tb − Tt (Tb and Tt are the temperatures at the bottom and top of the sample, respectively). To facilitate a comparison with the data, the theory of Busse (J. Fluid Mech., vol. 30, 1967, p. 625) of these so called non-Oberbeck–Boussinesq (NOB) effects, which applies to the case of relatively weak (and linear) temperature dependences, was extended to arbitrary variations with temperature. It is conceptually useful to divide the variations with temperature of the fluid properties into two disjunct parts. One part is chosen so that it preserves the reflection symmetry of the system about the horizontal midplane, while the remainder breaks that symmetry. The latter, exclusively considered by Busse, leads (in contrast to the formation of the typical convection rolls in RBC) to hexagons immediately above the transition to convection at the critical temperature difference ΔTc. The symmetric part, on the other hand, does not prevent the bifurcation to rolls, but may become very important for the determination of ΔTc. In the experiment the fluid was sulfur hexafluoride at temperatures above but close to the gas–liquid critical point, where all fluid properties vary strongly with temperature. All measurements were done along isobars by varying ΔT. Patterns were observed above onset (ΔT ≳ ΔTc), while for the conduction state at ΔT < ΔTc there were only fluctuations induced by Brownian motion. When the mean temperature Tm = (Tb + Tt)/2 was such that the density ρ at Tm was equal to the critical density ρ*, the mirror symmetry about the horizontal midplane of the sample was essentially preserved. In that case, as expected, we found a direct transition to rolls and the critical temperature difference ΔTc was considerably shifted compared to the critical value ΔTc,OB in the absence of NOB effects. When, on the other hand, Tm was not located on the critical isochore, the NOB effects broke the reflection symmetry and led to a hysteretic transition from fluctuations to hexagonal patterns. In this latter case the hexagonal pattern, the observed hysteresis at onset and the transition from hexagons to rolls at larger ΔT were consistent with the ‘classical’ predictions by Busse.


2008 ◽  
Vol 73 (4) ◽  
pp. 518-532 ◽  
Author(s):  
Horst L. Vörtler

We study the influence of geometric restrictions on vapour/liquid coexistence properties and critical data of square-well fluids. Starting with three-dimensional bulk systems, we model the confinement by slit-like pores with decreasing slit widths arriving finally at planar (two-dimensional) fluid layers. For both bulk and confined fluids, we use a uniform approach performing series of canonical ensemble Monte Carlo simulations with Widom-like (virtual) particle insertions to estimate chemical potential versus density isotherms. By estimating the corresponding vapour/liquid coexistence densities using a Maxwell-like equal area rule for the subcritical chemical potential isotherms, we are able to study the influence of the confinement not only on chemical potentials but also on the coexistence properties. Critical point data are calculated from the coexistence densities by means of scaling relations. In particular, we study the change of the critical temperature and critical density varying the slit width and including the two- and three-dimensional bulk fluids as limiting cases. While the difference between the bulk and the slit critical temperature is found to decay exponentially with an exponent reciprocal to a linear function in the slit width, no comparable simple relation describing the influence of the confinement on the critical density is found.


2020 ◽  
Vol 2020 (10) ◽  
Author(s):  
Francesco Alessio ◽  
Glenn Barnich

Abstract The temperature inversion symmetry of the partition function of the electromagnetic field in the set-up of the Casimir effect is extended to full modular transformations by turning on a purely imaginary chemical potential for adapted spin angular momentum. The extended partition function is expressed in terms of a real analytic Eisenstein series. These results become transparent after explicitly showing equivalence of the partition functions for Maxwell’s theory between perfectly conducting parallel plates and for a massless scalar with periodic boundary conditions.


1978 ◽  
Vol 56 (9) ◽  
pp. 1140-1141 ◽  
Author(s):  
P. Palffy-Muhoray ◽  
D. Balzarini

The index of refraction at 6328 Å has been measured for germane in the density range 0.15 to 0.9 g/cm3. The temperature and density ranges over which measurements are made are near the coexistence curve. The coefficient in the Lorenz–Lorentz expression, [Formula: see text], is constant to within 0.5% within experimental error for the temperature range and density range studied. The coefficient is slightly higher near the critical density. The critical density is measured to be 0.503 g/cm3. The critical temperature is measured to be 38.92 °C.


1993 ◽  
Vol 08 (06) ◽  
pp. 1139-1152
Author(s):  
M.A. MARTÍN-DELGADO

The discrete model of the real symmetric one-matrix ensemble is analyzed with a cubic interaction. The partition function is found to satisfy a recursion relation that solves the model. The double scaling-limit of the recursion relation leads to a Miura transformation relating the contributions to the free energy coming from oriented and unoriented random surfaces. This transformation is the same kind as found with a quartic interaction.


2018 ◽  
Vol 172 ◽  
pp. 08002
Author(s):  
Alejandro Ayala ◽  
Jorge David Castaño-Yepes ◽  
José Antonio Flores ◽  
Saúl Hernández ◽  
Luis Hernández

We study the QCD phase diagram using the linear sigma model coupled to quarks. We compute the effective potential at finite temperature and quark chemical potential up to ring diagrams contribution. We show that, provided the values for the pseudo-critical temperature Tc = 155 MeV and critical baryon chemical potential μBc ≃ 1 GeV, together with the vacuum sigma and pion masses. The model couplings can be fixed and that these in turn help to locate the region where the crossover transition line becomes first order.


Sign in / Sign up

Export Citation Format

Share Document