Conductivities of Binary Molten Alkalihalide/Silverhalide Mixtures

1991 ◽  
Vol 46 (1-2) ◽  
pp. 206-210
Author(s):  
H.-P. Boßmann ◽  
J. Richter ◽  
N. Struck

AbstractThe electric conductivities of molten (Na, Ag)Cl, (Rb.Ag)Cl, (Na,Ag)Br, (Rb. Ag)Br, and (Cs, Ag)Br are determined as functions of composition and temperature from the melting point to 1100 K. The relation of the temperature coefficients to the phase diagram of the systems (K.Ag)Cl, (Rb. Ag)Cl, (Cs, Ag)Cl, and (Cs, Ag)I near and at the phase transition (liquid-solid) is studied. The molar conductivities and mobilities of the cations with reference to the common anion are evaluated.

2012 ◽  
Vol 184 ◽  
pp. 333-338 ◽  
Author(s):  
Francesco Cordero ◽  
Francesco Trequattrini ◽  
Floriana Craciun ◽  
Carmen Galassi

Anelastic and dielectric spectroscopy measurements are presented, which, together with previous measurements [1], clarify some controversial aspects of the phase diagram of PbZr1xTixO3close to the border with the antiferroelectric (AFE) phase, and at the morphotropic phase boundary (MPB). No evidence is found of a border separating monoclinic (M) from rhombohedral (R) phases, supporting recent structural studies according to which the two phases coexist, with the fraction of M prevailing near the MPB. A large frequency independent softening at the MPB indicates a genuine M phase over only finely twinned R phase. A new phase transition is found in both the anelastic and dielectric spectra atx= 0.1, at a temperatureTITbetween the Curie temperatureTCand the boundaryTTto the phases with tilted octahedra. Such a diffuse transition is interpreted as onset of disordered tilts, which finally become ordered belowTT. In this manner, the phase diagram of PZT is rationalised with respect to the common tendency of perovskites to undergo tilting when the mismatch between the cation sizes exceeds a threshold.


Author(s):  
L. T. Pawlicki ◽  
R. M. Siegoczyński ◽  
S. Ptasznik ◽  
K. Marszałek

AbstractThe main purpose of the experiment was a thermodynamic research with use of the electric methods chosen. The substance examined was olive oil. The paper presents the resistance, capacitive reactance, relative permittivity and resistivity of olive. Compression was applied with two mean velocities up to 450 MPa. The results were shown as functions of pressure and time and depicted on the impedance phase diagram. The three first order phase transitions have been detected. All the changes in material parameters were observed during phase transitions. The material parameters measured turned out to be the much more sensitive long-time phase transition factors than temperature. The values of material parameters and their dependence on pressure and time were compared with the molecular structure, arrangement of molecules and interactions between them. Knowledge about olive oil parameters change with pressure and its phase transitions is very important for olive oil production and conservation.


1992 ◽  
Vol 280 ◽  
Author(s):  
Yasumasa Tanishiro ◽  
Masahiko Fukuyamaand ◽  
Katsumichi Yagi

ABSTRACTStructure changes of Si(111)-Pb surfaces due to deposition and heat treatment are studied by REM-RHEED. Surface structures observed are summarized as a phase diagram. Formation of an incommensurate layer(α) and a phase transition between incommensurate structures of α and α' is described.


2001 ◽  
Vol 16 (17) ◽  
pp. 1129-1138 ◽  
Author(s):  
M. SADZIKOWSKI

The Nambu–Bogoliubov–de Gennes method is applied to the problem of superconducting QCD. The effective quark–quark interaction is described within the framework of the Nambu–Jona-Lasinio model. The details of the phase diagram are given as a function of the strength of the quark–quark coupling constant G′. It is found that there is no superconducting phase transition when one uses the relation between the coupling constants G′ and G of the Nambu–Jona-Lasinio model which follows from the Fierz transformation. However, for other values of G′ one can find a rich phase structure containing both the chiral and the superconducting phase transitions.


1992 ◽  
Vol 47 (1-2) ◽  
pp. 177-181 ◽  
Author(s):  
Shi-Qi Dou ◽  
Alarich Weiss

AbstractThe two line 35Cl NQR spectrum of 4,5-dichloroimidazole was measured in the temperature range 77≦ T/K ≦ 389. The temperature dependence of the NQR frequencies conforms with the Bayer model and no phase transition is indicated in the curves v ( 35Cl)= f(T). Also the temperature coefficients of the 35Cl NQR frequencies are "normal". At 77 K the 35Cl NQR frequencies are 37.409 MHz and 36.172 MHz and at 389 K 35.758 MHz and 34.565 MHz. The compound crystallizes at room temperature with the tetragonal space group D44-P41212, Z = 8 molecules per unit cell; at 295 K : a = 684.2(5) pm, c = 2414.0(20) pm. The relations between the crystal structure and the NQR spectrum are discussed.


2015 ◽  
Vol 2015 ◽  
pp. 1-15 ◽  
Author(s):  
Abdel Nasser Tawfik ◽  
Niseem Magdy

Sensitivity of Polyakov Nambu-Jona-Lasinio (PNJL) model and Polyakov linear sigma-model (PLSM) has been utilized in studying QCD phase-diagram. From quasi-particle model (QPM) a gluonic sector is integrated into LSM. The hadron resonance gas (HRG) model is used in calculating the thermal and dense dependence of quark-antiquark condensate. We review these four models with respect to their descriptions for the chiral phase transition. We analyze the chiral order parameter, normalized net-strange condensate, and chiral phase-diagram and compare the results with recent lattice calculations. We find that PLSM chiral boundary is located in upper band of the lattice QCD calculations and agree well with the freeze-out results deduced from various high-energy experiments and thermal models. Also, we find that the chiral temperature calculated from HRG is larger than that from PLSM. This is also larger than the freeze-out temperatures calculated in lattice QCD and deduced from experiments and thermal models. The corresponding temperature and chemical potential are very similar to that of PLSM. Although the results from PNJL and QLSM keep the same behavior, their chiral temperature is higher than that of PLSM and HRG. This might be interpreted due the very heavy quark masses implemented in both models.


ACS Omega ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 18227-18233 ◽  
Author(s):  
Junbo Gong ◽  
Xiaodong Fan ◽  
Rucheng Dai ◽  
Zhongping Wang ◽  
Zejun Ding ◽  
...  

2016 ◽  
Vol 435 ◽  
pp. 1-5 ◽  
Author(s):  
S.M. Wan ◽  
G.M. Zheng ◽  
D.X. Feng ◽  
Y.N. Yao ◽  
Y. Zhao ◽  
...  

2017 ◽  
Vol 45 ◽  
pp. 1760059
Author(s):  
Clebson A. Graeff ◽  
Débora P. Menezes

We analyse the hadron/quark phase transition described by the Nambu-Jona-Lasinio (NJL) model [quark phase] and the extended Nambu-Jona-Lasinio model (eNJL) [hadron phase]. While the original formulation of the NJL model is not capable of describing hadronic properties due to its lack of confinement, it can be extended with a scalar-vector interaction so it exhibits this property, the so-called eNJL model. As part of this analysis, we obtain the equations of state within the SU(2) versions of both models for the hadron and the quark phases and determine the binodal surface.


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