Übergangsmetall-Carbin-Komplexe, LX [1]. Neue Triphenylsilyl-Carben-Komplexe des Rheniums durch Umsetzung eines kationischen Carbinkomplexes mit Nucleophilen / Transition Metal Carbyne Complexes, LX [1] Novel Triphenylsilyl Carbene Complexes of Rhenium by Reaction of a Cationic Carbyne Complex with Nucleophiles
1980 ◽
Vol 35
(9)
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pp. 1083-1087
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Keyword(s):
X Ray
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The reaction between C5H5Re(CO)3 and LiSi(C6H5)3 affords the compound C5H5(CO)2ReC(OCH3)Si(C6H5)3 after subsequent alkylation with CH3SO3F. This complex reacts with BF3 to yield [C5H5(CO)2ReCSi(C6H5)3]BF4. This cationic carbyne complex yields C5H5(CO)2ReC(CH1)Si(C6H5)3 with LiCH3 and C5H5(CO)2ReC(H)Si(C6H5)3 with (C4H9)4NBH4. Reaction conditions, properties and spectroscopic data of the new compounds as well as an X-ray structure determination of C5H5(CO)2ReC(H)Si(C6H5)3 are reported.
1982 ◽
Vol 37
(10)
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pp. 1274-1278
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1992 ◽
Vol 47
(5)
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pp. 645-655
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1985 ◽
Vol 40
(11)
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pp. 1500-1503
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1988 ◽
pp. 1001-1010
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Keyword(s):