Cerium intermetallics with TiNiSi-type structure

2016 ◽  
Vol 71 (7) ◽  
pp. 737-764 ◽  
Author(s):  
Oliver Janka ◽  
Oliver Niehaus ◽  
Rainer Pöttgen ◽  
Bernard Chevalier
Keyword(s):  
High Pressure ◽  
Type Structure ◽  
Pressure Effects ◽  
Equiatomic Composition ◽  
Structure Property ◽  
Structure Property Relationships ◽  
Hydrogenation Reactions ◽  
Cerium Intermetallics ◽  
High Pressure Effects ◽  
Cerium Compounds

AbstractIntermetallic compounds with the equiatomic composition CeTX that crystallize with the orthorhombic TiNiSi-type structure can be synthesized with electron-rich transition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn, As, Sb, and Bi. The present review focusses on the crystal chemistry and chemical bonding of these CeTX phases and on their physical properties, 119Sn and 121Sb Mössbauer spectra, high-pressure effects, hydrogenation reactions and the formation of solid solutions in order to elucidate structure–property relationships. This paper is the final one of a series of four reviews on equiatomic intermetallic cerium compounds [Part I: Z. Naturforsch. 2015, 70b, 289; Part II: Z. Naturforsch. 2015, 70b, 695; Part III: Z. Naturforsch. 2016, 71b, 165].

Cerium intermetallics CeTX – review III

2016 ◽  
Vol 71 (3) ◽  
pp. 165-191 ◽  
Author(s):  
Rainer Pöttgen ◽  
Oliver Janka ◽  
Bernard Chevalier
Keyword(s):  
High Pressure ◽  
Solid Solutions ◽  
Spectroscopic Data ◽  
Structure Property ◽  
The Third ◽  
Structure Property Relationships ◽  
High Pressure Studies ◽  
Hydrogenation Reactions ◽  
Cerium Intermetallics ◽  
Cerium Compounds

AbstractThe structure–property relationships of CeTX intermetallics with structures other than the ZrNiAl and TiNiSi type are systematically reviewed. These CeTX phases form with electron-poor and electron-rich transition metals (T) and X = Mg, Zn, Cd, Hg, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As, Sb, and Bi. The review focusses on the crystal chemistry, the chemical bonding peculiarities, and the magnetic and transport properties. Furthermore 119Sn Mössbauer spectroscopic data, high-pressure studies, hydrogenation reactions and the formation of solid solutions are reviewed. This paper is the third of a series of four reviews on equiatomic intermetallic cerium compounds [Part I: R. Pöttgen, B. Chevalier, Z. Naturforsch. 2015, 70b, 289; Part II: R. Pöttgen, B. Chevalier, Z. Naturforsch. 2015, 70b, 695].

Cerium intermetallics with ZrNiAl-type structure – a review

2015 ◽  
Vol 70 (5) ◽  
pp. 289-304 ◽  
Author(s):  
Rainer Pöttgen ◽  
Bernard Chevalier
Keyword(s):  
High Pressure ◽  
Electrical Properties ◽  
Transition Metals ◽  
Crystal Chemistry ◽  
Solid Solutions ◽  
Chemical Bonding ◽  
Type Structure ◽  
High Pressure Studies ◽  
Hydrogenation Reactions ◽  
Cerium Intermetallics

AbstractEquiatomic CeTX intermetallics with the hexagonal ZrNiAl type structure are formed with electron-rich transition metals (T) and X = Mg, Zn, Cd, Al, Ga, In, Tl, Sn, and Pb. Their crystal chemistry, chemical bonding, magnetic and electrical properties, and formation of solid solutions are reviewed. The results of 119Sn Mössbauer spectroscopy, high-pressure studies, and hydrogenation reactions are presented.

High pressure effects on the multiplet structure of the emission spectrum of coronene in a n‐alkane matrix

1977 ◽  
Vol 66 (2) ◽  
pp. 875-876 ◽  
Author(s):  
M. Lamotte ◽  
S. Risemberg ◽  
A. M. Merle ◽  
J. Joussot‐Dubien
Keyword(s):  
High Pressure ◽  
Emission Spectrum ◽  
Pressure Effects ◽  
Multiplet Structure ◽  
High Pressure Effects

High Pressure effects on electrical resistivity and dielectric properties of nanocrystalline SnO2

2005 ◽  
Vol 66 (10) ◽  
pp. 1621-1627 ◽  
Author(s):  
P. Thangadurai ◽  
A. Chandra Bose ◽  
S. Ramasamy ◽  
R. Kesavamoorthy ◽  
T.R. Ravindran
Keyword(s):  
High Pressure ◽  
Electrical Resistivity ◽  
Dielectric Properties ◽  
Pressure Effects ◽  
High Pressure Effects

scholarly journals Crystal Growth and High-Pressure Effects of Bi-Based Superconducting Whiskers

ACS Omega ◽  
2021 ◽  
Author(s):  
Ryo Matsumoto ◽  
Sayaka Yamamoto ◽  
Yoshihiko Takano ◽  
Hiromi Tanaka
Keyword(s):  
High Pressure ◽  
Crystal Growth ◽  
Pressure Effects ◽  
High Pressure Effects

Interpretation of the high-pressure effects in the rare-earth orthoferrites

1975 ◽  
Vol 11 (7) ◽  
pp. 2705-2706 ◽  
Author(s):  
C. Boekema ◽  
F. van der Woude ◽  
G. A. Sawatzky
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
Pressure Effects ◽  
High Pressure Effects ◽  
The Rare Earth

scholarly journals Probing the structure of framework materials by high pressure and the example of a magnetic, non-porous coordination polymer

2015 ◽  
Vol 71 (3) ◽  
pp. 247-249 ◽  
Author(s):  
Francesca P. A. Fabbiani
Keyword(s):  
High Pressure ◽  
Coordination Polymer ◽  
Coordination Compounds ◽  
Functional Materials ◽  
Research Tool ◽  
Structure Property ◽  
Framework Materials ◽  
Porous Framework ◽  
Structure Property Relationships ◽  
Porous Coordination Polymer

High pressure has become an indispensable research tool in the quest for novel functional materials. High-pressure crystallographic studies on non-porous, framework materials based on coordination compounds are markedly on the rise, enabling the unravelling of structural phenomena and taking us a step closer to the derivation of structure–property relationships.

High pressure effects on benzoic acid dimers: Vibrational spectroscopy

2014 ◽  
Vol 73 ◽  
pp. 138-143 ◽  
Author(s):  
Yuchuan Tao ◽  
Zbigniew A. Dreger ◽  
Yogendra M. Gupta
Keyword(s):  
High Pressure ◽  
Benzoic Acid ◽  
Vibrational Spectroscopy ◽  
Pressure Effects ◽  
High Pressure Effects
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