Tissue Integration of Two Different Shape-Memory Polymers with Poly(ε-Caprolactone) Switching Segment in Rats

2008 ◽  
Author(s):  
Bernhard Hiebl ◽  
Dorothee Rickert ◽  
Rosemarie Fuhrmann ◽  
Friedrich Jung ◽  
Andres Lendlein ◽  
...  
2007 ◽  
Vol 539-543 ◽  
pp. 663-668 ◽  
Author(s):  
Silvia Farè ◽  
Luigi de Nardo ◽  
S. De Cicco ◽  
M. Jovenitti ◽  
Maria Cristina Tanzi

In the last few years, clinical procedures undergone huge modifications. Among them, mini-invasive surgery has modified the clinical practice and the quality of life of patients. Shape Memory Polymers (SMPs), a class of stimuli-responsive materials, can be considered ideal candidates for the design of devices for mini-invasive surgical procedures. Such a device can be inserted in a packed in, temporary shape and later can expand at body temperature. A bone defect could be filled by a SMP porous structure, that improves the tissue integration and healing. In this work, two different processing techniques to obtain porous shape memory polymer scaffolds from Calo MER™ and MM-4520, two SMPs, are presented. Porous structures were obtained by micro-extrusion with different chemical foaming agents or with sodium chloride, or by solvent casting/particulate leaching. The morphology, the thermo-mechanical and the shape recovery properties of the SMP porous samples were investigated. Tridimensional porous structures showed a well interconnected morphology, with a pore size in the range aimed for bone interaction applications. The shape memory properties were not significantly affected by the transformation processes: a good ability of recovering the original shape was verified. Therefore, the porous structures, obtained from these SMP materials, appear adequate for an use as bone filler.


2013 ◽  
Author(s):  
Patrick T. Mather ◽  
H. J. Qi ◽  
Martin Dunn

Author(s):  
Tianjiao Wang ◽  
Jun Zhao ◽  
Chuanxin Weng ◽  
Tong Wang ◽  
Yayun Liu ◽  
...  

Shape memory polymers (SMPs) that change shapes as designed by external stimuli have become one of the most promising materials as actuators, sensors, and deployable devices. However, their practical applications...


2021 ◽  
pp. 2002111
Author(s):  
Calen J. Leverant ◽  
Yifan Zhang ◽  
Maria A. Cordoba ◽  
Sin‐Yen Leo ◽  
Nilesh Charpota ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.


Polymer ◽  
2021 ◽  
Vol 214 ◽  
pp. 123351
Author(s):  
Cheng Yan ◽  
Xiaming Feng ◽  
Collin Wick ◽  
Andrew Peters ◽  
Guoqiang Li

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wang Zhang ◽  
Hao Wang ◽  
Hongtao Wang ◽  
John You En Chan ◽  
Hailong Liu ◽  
...  

AbstractFour-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D printing of a SMP in the submicron length scale, extending its applications to nanophononics. We report a new SMP photoresist based on Vero Clear achieving print features at a resolution of ~300 nm half pitch using two-photon polymerization lithography (TPL). Prints consisting of grids with size-tunable multi-colours enabled the study of shape memory effects to achieve large visual shifts through nanoscale structure deformation. As the nanostructures are flattened, the colours and printed information become invisible. Remarkably, the shape memory effect recovers the original surface morphology of the nanostructures along with its structural colour within seconds of heating above its glass transition temperature. The high-resolution printing and excellent reversibility in both microtopography and optical properties promises a platform for temperature-sensitive labels, information hiding for anti-counterfeiting, and tunable photonic devices.


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