Study of Enhanced-Oil-Recovery Mechanism of Alkali/Surfactant/Polymer Flooding in Porous Media From Experiments

SPE Journal ◽  
2009 ◽  
Vol 14 (02) ◽  
pp. 237-244 ◽  
Author(s):  
Pingping Shen ◽  
Jialu Wang ◽  
Shiyi Yuan ◽  
Taixian Zhong ◽  
Xu Jia

Summary The fluid-flow mechanism of enhanced oil recovery (EOR) in porous media by alkali/surfactant/polymer (ASP) flooding is investigated by measuring the production performance, pressure, and saturation distributions through the installed differential-pressure transducers and saturation-measurement probes in a physical model of a vertical heterogeneous reservoir. The fluid-flow variation in the reservoir is one of the main mechanisms of EOR of ASP flooding, and the nonlinear coupling and interaction between pressure and saturation fields results in the fluid-flow variation in the reservoir. In the vertical heterogeneous reservoir, the ASP agents flow initially in the high-permeability layer. Later, the flow direction changes toward the low- and middle-permeability layers because the resistance in the high-permeability layer increases on physical and chemical reactions such as adsorption, retention, and emulsion. ASP flooding displaces not only the residual oil in the high-permeability layer but also the remaining oil in the low- and middle-permeability layers by increasing both swept volume and displacement efficiency. Introduction Currently, most oil fields in China are in the later production period and the water cut increases rapidly, even to more than 80%. Waterflooding no longer meets the demands of oilfield production. Thus, it is inevitable that a new technology will replace waterflooding. The new technique of ASP flooding has been developed on the basis of alkali-, surfactant-, and polymer-flooding research in the late 1980s. ASP flooding uses the benefits of the three flooding methods simultaneously, and oil recovery is greatly enhanced by decreasing interfacial tension (IFT), increasing the capillary number, enhancing microscopic displacing efficiency, improving the mobility ratio, and increasing macroscopic sweeping efficiency (Shen and Yu 2002; Wang et al. 2000; Wang et al. 2002; Sui et al. 2000). Recently, much intensive research has been done on ASP flooding both in China and worldwide, achieving some important accomplishments that lay a solid foundation for the extension of this technique to practical application in oil fields (Baviere et al. 1995; Thomas 2005; Yang et al. 2003; Li et al. 2003). In previous work, the ASP-flooding mechanism was studied visually by using a microscopic-scale model and double-pane glass models with sand (Liu et al. 2003; Zhang 1991). In these experiments, the water-viscosity finger, the residual-oil distribution after waterflooding, and the oil bank formed by microscopic emulsion flooding were observed. In Tong et al. (1998) and Guo (1990), deformation, threading, emulsion (oil/water), and strapping were observed as the main mechanisms of ASP flooding in a water-wetting reservoir, while the interface-producing emulsion (oil/water), bridging between inner pore and outer pore, is the main mechanism of ASP flooding in an oil-wetting reservoir. For a vertical heterogeneous reservoir, ASP flooding increases displacement efficiency by displacing residual oil through decreased IFT, simultaneously improving sweep efficiency by extending the swept area in both vertical and horizontal directions. Some physical and chemical phenomena, such as emulsion, scale deposition, and chromatographic separation, occur during ASP flooding (Arihara et al. 1999; Guo 1999). Because ASP flooding in porous media involves many complicated physicochemical properties, many oil-recovery mechanisms still need to be investigated. Most research has been performed on the microscopic displacement mechanism of ASP flooding, while the fluid-flow mechanism in porous media at the macroscopic scale lacks sufficient study. In this paper, a vertical-heterogeneous-reservoir model is established, and differential-pressure transducers and saturation-measuring probes are installed. The fluid-flow mechanism of increasing both macroscopic sweep efficiency and microscopic displacement efficiency is studied by measuring the production performance and the variation of pressure and saturation distributions in the ASP-flooding experiment. An experimental database of ASP flooding also is set up and provides an experimental base for numerical simulation.

2007 ◽  
Author(s):  
Jialu Wang ◽  
Shiyi Yuan ◽  
Pingping Shen ◽  
Taixian Zhong ◽  
Xu Jia

2021 ◽  
Author(s):  
Randy Agra Pratama ◽  
Tayfun Babadagli

Abstract Our previous research, honoring interfacial properties, revealed that the wettability state is predominantly caused by phase change—transforming liquid phase to steam phase—with the potential to affect the recovery performance of heavy-oil. Mainly, the system was able to maintain its water-wetness in the liquid (hot-water) phase but attained a completely and irrevocably oil-wet state after the steam injection process. Although a more favorable water-wetness was presented at the hot-water condition, the heavy-oil recovery process was challenging due to the mobility contrast between heavy-oil and water. Correspondingly, we substantiated that the use of thermally stable chemicals, including alkalis, ionic liquids, solvents, and nanofluids, could propitiously restore the irreversible wettability. Phase distribution/residual oil behavior in porous media through micromodel study is essential to validate the effect of wettability on heavy-oil recovery. Two types of heavy-oils (450 cP and 111,600 cP at 25oC) were used in glass bead micromodels at steam temperatures up to 200oC. Initially, the glass bead micromodels were saturated with synthesized formation water and then displaced by heavy-oils. This process was done to exemplify the original fluid saturation in the reservoirs. In investigating the phase change effect on residual oil saturation in porous media, hot-water was injected continuously into the micromodel (3 pore volumes injected or PVI). The process was then followed by steam injection generated by escalating the temperature to steam temperature and maintaining a pressure lower than saturation pressure. Subsequently, the previously selected chemical additives were injected into the micromodel as a tertiary recovery application to further evaluate their performance in improving the wettability, residual oil, and heavy-oil recovery at both hot-water and steam conditions. We observed that phase change—in addition to the capillary forces—was substantial in affecting both the phase distribution/residual oil in the porous media and wettability state. A more oil-wet state was evidenced in the steam case rather than in the liquid (hot-water) case. Despite the conditions, auspicious wettability alteration was achievable with thermally stable surfactants, nanofluids, water-soluble solvent (DME), and switchable-hydrophilicity tertiary amines (SHTA)—improving the capillary number. The residual oil in the porous media yielded after injections could be favorably improved post-chemicals injection; for example, in the case of DME. This favorable improvement was also confirmed by the contact angle and surface tension measurements in the heavy-oil/quartz/steam system. Additionally, more than 80% of the remaining oil was recovered after adding this chemical to steam. Analyses of wettability alteration and phase distribution/residual oil in the porous media through micromodel visualization on thermal applications present valuable perspectives in the phase entrapment mechanism and the performance of heavy-oil recovery. This research also provides evidence and validations for tertiary recovery beneficial to mature fields under steam applications.


Processes ◽  
2018 ◽  
Vol 6 (10) ◽  
pp. 178 ◽  
Author(s):  
Richeng Liu ◽  
Yujing Jiang

The fluid flow in fractured porous media plays a significant role in the characteristic/assessment of deep underground reservoirs such as CO2 sequestration [1–3], enhanced oil recovery [4,5] and geothermal energy development [...]


2011 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Muhammad Taufiq Fathaddin ◽  
Asri Nugrahanti ◽  
Putri Nurizatulshira Buang ◽  
Khaled Abdalla Elraies

In this paper, simulation study was conducted to investigate the effect of spatial heterogeneity of multiple porosity fields on oil recovery, residual oil and microemulsion saturation. The generated porosity fields were applied into UTCHEM for simulating surfactant-polymer flooding in heterogeneous two-layered porous media. From the analysis, surfactant-polymer flooding was more sensitive than water flooding to the spatial distribution of multiple porosity fields. Residual oil saturation in upper and lower layers after water and polymer flooding was about the same with the reservoir heterogeneity. On the other hand, residual oil saturation in the two layers after surfactant-polymer flooding became more unequal as surfactant concentration increased. Surfactant-polymer flooding had higher oil recovery than water and polymer flooding within the range studied. The variation of oil recovery due to the reservoir heterogeneity was under 9.2%.


SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2243-2259 ◽  
Author(s):  
Pengfei Dong ◽  
Maura Puerto ◽  
Guoqing Jian ◽  
Kun Ma ◽  
Khalid Mateen ◽  
...  

Summary Oil recovery in heterogeneous carbonate reservoirs is typically inefficient because of the presence of high-permeability fracture networks and unfavorable capillary forces within the oil-wet matrix. Foam, as a mobility-control agent, has been proposed to mitigate the effect of reservoir heterogeneity by diverting injected fluids from the high-permeability fractured zones into the low-permeability unswept rock matrix, hence improving the sweep efficiency. This paper describes the use of a low-interfacial-tension (low-IFT) foaming formulation to improve oil recovery in highly heterogeneous/fractured oil-wet carbonate reservoirs. This formulation provides both mobility control and oil/water IFT reduction to overcome the unfavorable capillary forces preventing invading fluids from entering an oil-filled matrix. Thus, as expected, the combination of mobility control and low-IFT significantly improves oil recovery compared with either foam or surfactant flooding. A three-component surfactant formulation was tailored using phase-behavior tests with seawater and crude oil from a targeted reservoir. The optimized formulation simultaneously can generate IFT of 10−2 mN/m and strong foam in porous media when oil is present. Foam flooding was investigated in a representative fractured core system, in which a well-defined fracture was created by splitting the core lengthwise and precisely controlling the fracture aperture by applying a specific confining pressure. The foam-flooding experiments reveal that, in an oil-wet fractured Edward Brown dolomite, our low-IFT foaming formulation recovers approximately 72% original oil in place (OOIP), whereas waterflooding recovers only less than 2% OOIP; moreover, the residual oil saturation in the matrix was lowered by more than 20% compared with a foaming formulation lacking a low-IFT property. Coreflood results also indicate that the low-IFT foam diverts primarily the aqueous surfactant solution into the matrix because of (1) mobility reduction caused by foam in the fracture, (2) significantly lower capillary entry pressure for surfactant solution compared with gas, and (3) increasing the water relative permeability in the matrix by decreasing the residual oil. The selective diversion effect of this low-IFT foaming system effectively recovers the trapped oil, which cannot be recovered with single surfactant or high-IFT foaming formulations applied to highly heterogeneous or fractured reservoirs.


Author(s):  
Fengqi Tan ◽  
Changfu Xu ◽  
Yuliang Zhang ◽  
Gang Luo ◽  
Yukun Chen ◽  
...  

The special sedimentary environments of conglomerate reservoir lead to pore structure characteristics of complex modal, and the reservoir seepage system is mainly in the “sparse reticular-non reticular” flow pattern. As a result, the study on microscopic seepage mechanism of water flooding and polymer flooding and their differences becomes the complex part and key to enhance oil recovery. In this paper, the actual core samples from conglomerate reservoir in Karamay oilfield are selected as research objects to explore microscopic seepage mechanisms of water flooding and polymer flooding for hydrophilic rock as well as lipophilic rock by applying the Computed Tomography (CT) scanning technology. After that, the final oil recovery models of conglomerate reservoir are established in two displacement methods based on the influence analysis of oil displacement efficiency. Experimental results show that the seepage mechanisms of water flooding and polymer flooding for hydrophilic rock are all mainly “crawling” displacement along the rock surface while the weak lipophilic rocks are all mainly “inrushing” displacement along pore central. Due to the different seepage mechanisms among the water flooding and the polymer flooding, the residual oil remains in hydrophilic rock after water flooding process is mainly distributed in fine throats and pore interchange. These residual oil are cut into small droplets under the influence of polymer solution with stronger shearing drag effect. Then, those small droplets pass well through narrow throats and move forward along with the polymer solution flow, which makes enhancing oil recovery to be possible. The residual oil in weak lipophilic rock after water flooding mainly distributed on the rock particle surface and formed oil film and fine pore-throat. The polymer solution with stronger shear stress makes these oil films to carry away from particle surface in two ways such as bridge connection and forming oil silk. Because of the essential attributes differences between polymer solution and injection water solution, the impact of Complex Modal Pore Structure (CMPS) on the polymer solution displacement and seepage is much smaller than on water flooding solution. Therefore, for the two types of conglomerate rocks with different wettability, the pore structure is the main controlling factor of water flooding efficiency, while reservoir properties oil saturation, and other factors have smaller influence on flooding efficiency although the polymer flooding efficiency has a good correlation with remaining oil saturation after water flooding. Based on the analysis on oil displacement efficiency factors, the parameters of water flooding index and remaining oil saturation after water flooding are used to establish respectively calculation models of oil recovery in water flooding stage and polymer flooding stage for conglomerate reservoir. These models are able to calculate the oil recovery values of this area controlled by single well control, and further to determine the oil recovery of whole reservoir in different displacement stages by leveraging interpolation simulation methods, thereby providing more accurate geological parameters for the fine design of displacement oil program.


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