At the high or extra-high temperatures in a natural gas oilfield, where the premium connection is employed by casing, gas leakage in the wellbore is always detected after several years of gas production. As the viscoelastic material’s mechanical properties change with time and temperature, the relaxation of the contact pressure on the connection sealing surface is the main reason for the gas leakage in the high-temperature gas well. In this article, tension-creep experiments were conducted. Furthermore, a constitutive model of the casing material was established by the Prony series method. Moreover, the Prony series’ shift factor was calculated to study the thermo-rheological behavior of the casing material ranging from 120°C to 300°C. A linear viscoelastic model was implemented in ABAQUS, and the simulation results are compared to our experimental data to validate the methodology. Finally, the viscoelastic finite element model is applied to predict the relaxation of contact pressure on the premium connections’ sealing surface versus time under different temperatures. And, the ratio of the design contact pressure and the intending gas sealing pressure is recommended for avoiding the premium connections failure in the high-temperature gas well.