Optimization of Apparent Peak Viscosity in Carboxymethyl Cellulose Fracturing Fluid: Interactions of High Total Dissolved Solids, pH Value, and Crosslinker Concentration
Summary It has been common practice to use a freshwater source (either ground water or surface water) as the base fluid for hydraulic fracturing with crosslinked-gel fluids. Currently, oil and gas operators are beginning to reuse and recycle the main byproduct of oil extraction, which is produced water. However, because of the high variability of produced-water quality (temporal and spatial), and the high content of total dissolved solids (TDS), the viscosity targets for the fluid can be difficult to achieve. The research described in this paper examines the sensitivity of higher-salinity waters to several variables related to the gel-formation process. The polymer used for the gel fluid was a carboxymethyl cellulose (CMC) derivative, and zirconium (Zr) was used as the crosslinking metal. Rheology experiments were conducted at different pH values, polymer loading, and crosslinker concentrations. The outcome of this research is presented in 3D contour-peak-viscosity maps that can be used by oil and gas operators and service companies to optimize the chemicals that are applied, thus reducing costs.