scholarly journals Spatial Distribution, Source Discrimination, and Health Risk Assessment of Arsenic and Fluoride in Drinking Water Around Brick Kilns of Vehari, Punjab, Pakistan.

Author(s):  
Muhammad Akram ◽  
Rukhsar Fatima ◽  
Atta Rasool ◽  
Allah Wasaya

Abstract Water is very important to maintaining life on earth. Fluoride and Arsenic pollution in groundwater is an emerging issue in the world. Atomic absorption spectrometry was used to measure total arsenic, while ion chromatography was used to determine fluoride. The present study was conducted for the health risk assessment of fluoride and arsenic in groundwater around brick kilns. 58 samples of groundwater were collected from district Vehari Punjab and were analyzed for arsenic concentration ranges from 0.330 to 11.120 µg/L, higher than the WHO recommended permissible level of arsenic in drinking water (10 µg/L). The mean value of fluoride in the water supply for drinking is 2.599 mg/L as its concentration ranges are 0.680 to 9.690 mg/L respectively. All the values of fluoride in drinking water were higher than the permissible limit according to WHO standard 1.5 mg/L. The spatial distribution of arsenic and fluoride in groundwater indicates their direct contamination with rock weathering, coal burning, and the use of cheap fuel in brick kilns. The estimated average dose (ADD), hazards quotient (HQ), as well as cancer risk (CR), were computed using statistical formulae to determine the health risks of arsenic and fluoride. The hazard quotient (HQ) values of As and F− in this research area were higher protection and safe limits (HQ > 1), having health risks to the people in this region, caused by brick kilns. Statistical parameters correlation and cluster analysis were used to determining possible contaminant sources in the study area.

Author(s):  
Reza Aghlmand ◽  
Saeed Rasi Nezami ◽  
Ali Abbasi

In recent years, in addition to water resources’ quantity, their quality has also received much attention. In this study, the quality of the urban water distribution network in northwestern Iran was evaluated using the water quality index (WQI) method. Then, some important trace elements were investigated, and finally, the health risk assessment was evaluated for both carcinogenic elements (Ni, Cd, Cr, Pb, and As) and non-carcinogenic elements (Ca, Mg, Na, K, F, NO3, and Cu) using carcinogenic risk (CR) and hazard quotient (HQ), respectively. In the present study, the WQI was calculated based on both World Health Organization (WHO) and Iranian drinking water standards. Comparing the results of these standards revealed that the WQI based on the Iranian standard was slightly higher. Regarding the calculated WQI for the study region, the status of water quality for drinking consumption is in the good water quality class (25 < WQI < 50). It was observed that Cu and Cd have the highest and lowest concentrations in all sampling points, respectively. Hazard Index (HI) results showed that the non-carcinogenic substances studied had a low risk for both adults and children (<1.0). However, the CR results showed that Ni, Cd, and As were above the desired level for both children and adults. The results of this study can be applied for efficient water management and human health protection programs in the study area.


Author(s):  
Muhammad Syafiq N ◽  
◽  
Shaharuddin MS ◽  
Zaenal Abidin ◽  
◽  
...  

ABSTRACT Introduction: Contamination of nitrate is one of the most common groundwater problems worldwide. Around 70% of residents in the state of Kelantan still rely on groundwater as their primary source of water supply. Extensive usage of fertilizer in agricultural areas may cause nitrate leaching into the groundwater. This study aimed to determine the level of nitrate in groundwater and health risk assessment at three villages in Tanah Merah District, Kelantan, Malaysia. Subjects and Method: This was a cross-sectional study conducted at Tanah Merah district, Kelantan, in January 2020. A total of 52 residents was selected by purposive sampling. The inclusion criteria for study subjects were long life residents, age ≥18 years old, and groundwater as a primary source of drinking supply. The study variables were (1) Level of nitrate in groundwater measured according to age (year), depth (meter), and distance (meter) of well from the agricultural area; and (2) Health risk assessment measured by hazard quotient (HQ). A set of questionnaires consisted of four sections to gather information related to socio-demographic, water usage, living environment, and health status. Groundwater samples were collected in duplicates and were analysed using a Hanna Instruments portable pH/ORP/ISE meter with an attached nitrate electrode. The data were reported descriptively. Results: Nitrate levels were found to be under the maximum acceptable value of 10 mg/L, as stated by the Drinking Water Quality Standard of Malaysia. Nitrate level ranged from 0.22 to 8.81 mg/L (Mean= 2.94; SD= 2.27). Spearman rho correlation showed that nitrate level was significantly and negatively correlated the age of wells (r= -0.31; p= 0.025). Nitrate level was not significantly correlated with the depth (r= 0.19; p= 0.183) and distance of wells (r= -0.05; p= 0.751). Hazard quotient (HQ) for all study subjects was <1, which means that exposure to nitrate contained drinking water in study subjects was not detrimental to health. Conclusion: Nitrate levels were below the maximum acceptable value, but continuous monitoring from health authorities is essential since other seasons of paddy planting may contribute higher deposition of nitrate into groundwater. Keywords: nitrate, groundwater, levels, hazard quotient, Tanah Merah Correspondence: Muhammad Syafiq N. Department of Environmental and Occupational Health, Faculty of Medicine and Health Sciences, Universiti Putra Malaysia. UPM Serdang, Selangor, Malaysia. Email: [email protected]. Mobile: +601140731881. DOI: https://doi.org/10.26911/the7thicph.01.27


Author(s):  
Xue Bai ◽  
Kai Song ◽  
Jian Liu ◽  
Adam Khalifa Mohamed ◽  
Chenya Mou ◽  
...  

To provide theoretical support for the protection of dispersed drinking water sources of groundwater, we need to accurately evaluate the time and scope of groundwater pollution hazards to human health. This helps the decision-making process for remediation of polluted soil and groundwater in service stations. In this study, we conducted such an evaluation by coupling numerical modeling with a health risk assessment. During the research, soil and groundwater samples were collected and analyzed for 20 pollutants. Fifty-six percent of the heavy contaminants and 100% of the organic contaminants exhibited maximum values at the location of the oil depot. Gray correlation analysis showed that the correlation between background samples and soil underlying the depot was 0.375–0.567 (barely significant to insignificant). The correlation between the reference sequence of other points was 0.950–0.990 (excellent correlation). The correlation of environmental impact after oil depot leakage followed the order: organic pollutants > heavy metals > inorganic pollutants. The groundwater simulation status and predictions indicated that non-carcinogenic health risks covered 25,462 m2 at the time of investigation, and were predicted to extend to 29,593 m2 after five years and to 39,873 m2 after 10 years. Carcinogenic health risks covered 21,390 m2 at the time of investigation, and were predicted to extend to 40,093 m2 after five years and to 53,488 m2 after 10 years. This study provides theoretical support for the protection of a dispersed drinking water source such as groundwater, and also helps the decision-making process for groundwater and soil environment improvement.


2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Defang Zeng ◽  
Saijun Zhou ◽  
Bozhi Ren ◽  
Tengshu Chen

Heavy metal pollution in soils caused by mining and smelting has attracted worldwide attention for its potential health risks to residents. This paper studies the concentrations and accumulations of Sb and As in both soils and vegetables and the human health risks of Sb and As in vegetables from Xikuangshan (XKS) Sb mine, Hunan, China. Results showed that the soils were severely polluted by Sb and As; Sb and As have significant positive correlation. Sb and As concentrations in vegetables were quite different:Coriandrum sativumL. was the highest in Sb,Allium fistulosumL. was the highest in As, andBrassica pekinensisL. was the lowest in both Sb and As;Daucus carotaL. andCoriandrum sativumL. showed advantage in accumulating Sb and As;Coriandrum sativumL. had higher capacity of redistributing Sb and As within the plant. Health risk assessment results showed that the hazard quotient (HQ) values of Sb and As in vegetables were in the ranges of 1.61–3.33 and 0.09–0.39, respectively; the chronic daily intake (CDI) and hazard quotient (HQ) values of Sb were over the safe limit recommended by FAO and WHO, indicating that long-term consumption of vegetables from the surrounding soils of XKS mine may bring health risks to residents.


Author(s):  
Simge Varol

Abstract Groundwater is an important water resource used for drinking, domestic and agricultural activities in Akşehir and surroundings. However, intensive agricultural and human activities in the region adversely affect groundwater quality. In this study, 31 water samples were collected from wells. According to the Piper diagram, groundwater in the study area was in the Ca–Mg–HCO3 and Ca–HCO3 water facies. As a result, it is not appropriate to use groundwater as drinking water in the study area in terms of trace elements and pollutant analysis results of water samples compared to limit values determined by WHO and ITHASY drinking water guidelines. The arsenic concentration in groundwater was studied in detail. The origin and concentration of arsenic in groundwater is associated with agricultural activities and pesticides in the region. Accordingly, a health risk assessment was carried out for the use of groundwater in the study area as drinking water. The results for all samples analyzed indicate that the groundwater concerned was not suitable for drinking purposes because of arsenic concentrations which exceeded maximum acceptable levels.


Author(s):  
Jun Li ◽  
Xiongyi Miao ◽  
Yupei Hao ◽  
Zhouqing Xie ◽  
Shengzheng Zou ◽  
...  

Wild fish caught by anglers (WFAs) were confirmed to be usually contaminated with metals, and the contamination status is radically affected by the growth and length of the fish. To determine the contamination levels of metals and health risks in WFAs with different length ranges of fish, this study ascertained the concentration of eight metals, including Cu, Pb, Zn, Cr, Cd, As, Hg and Se, in 171 wild fishes collected from the watershed of Liujiang River. The assessment of metal pollution and health risks from the consumption of these fishes with seven length ranges were accomplished. The obtained results implied a relatively high concentration of Zn, Cr, and Cd up to 109.294 mg/kg, 4.226 mg/kg, and 0.196 mg/kg (wet weight), respectively, which exceed the corresponding Maximum Residue Limit (MRL). The negative correlation between Cu, Zn, Cr, and Cd was observed to be significant with fish length, signifying a possible occurrence of biological dilution on these metals. The WFAs were mostly contaminated with Cr and Cd irrespective of the length ranges of fish, which were denoted by the average pollution index (Pi) of Cr and Cd and were commonly found to be beyond 0.2. Based on the results of health risk assessment analysis, most of the target hazard quotient (THQ) values of Cr were below 1, implying that the consumption of wild fish for adults has insignificant health risk. For children, the total target hazard quotient (TTHQ) values of beyond 1 were found in fishes with the length range of <25 cm, particularly a TTHQ value 1.627 in the range of 10–15 cm, indicating that children are being prone to serious health risks owing to the consumption of WFAs. The weekly recommended consumption of WFAs with the length range of 10–15 cm for adults and children was 0.298 kg/week and 0.149 kg/week, respectively. These are substantially lower than the current rate of fish consumption (0.42 kg/week), and therefore, the wild fish with the length range of 10–15 cm should be avoided for consumption.


Chemosphere ◽  
2020 ◽  
Vol 239 ◽  
pp. 124811 ◽  
Author(s):  
Lei Zhang ◽  
Liang Zhao ◽  
Qiang Zeng ◽  
Gang Fu ◽  
Baojia Feng ◽  
...  

2021 ◽  
Vol 2 (1) ◽  
pp. 73-80
Author(s):  
Shaharuddin Mohd Sham ◽  
Muhammad Azri Mat Yusof

Nitrate is one of the compounds of nitrogen found in the nitrogen cycle that is which originates from both natural and anthropogenic sources. Most rural areas in Kelantan state still depend on well water as their primary water source. Their main economic activity is agriculture which uses high amountsof nitrate fertilizer to nurture their crops. The increased use of nitrate fertilizers has a possible risk factor associated to health problems such as methemoglobinemia and cancers. Health risk assessment can be conducted to quantify the probability of harmful effects of nitrate to individuals or populations from certain human activities. To determine levels of nitrate in groundwater and to perform health risk assessment among respondents in Keting village, Bachok district, Kelantan state. A total of 47 respondents were chosen for this study and groundwater samples in duplicates were collected from the respondents’ houses. The samples werethen analyzed by using a portable Hanna Instrument multimeter model HI98191 and probe model HI4113. while a set of questionnaireswereusedto collect information for health risk assessment of the exposure. Nitrate levels in groundwater did not exceed the maximum concentration value of Drinking Water Quality Standard (44.3 ppm nitrate – NO3) with a mean ± sd of 5.34 ± 4.94 (ppm). Spearman’s rho correlation analysis shows that only depth of well (meter) is correlated (r = - 0.348) to nitrate levels (p0.05). The Hazard Quotient (HQ)for the study population was less than 1. In terms of nitrate, the groundwater analyzed in the study area was considered safe for drinking and cooking purposes. The result for HQ indicated that the non-carcinogenic risk related to nitrate was not significant to the study population. However, nitrate levels in drinking water should be concerned by the consumers as it will give bad health impact to them in long-term exposures.


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