Research on the Size and Shape of Large Molecules and Colloidal Particles. 1: Light Scattering of Spherical Colloidal Particles. 2: The Determination of Particle Size and Refractive Index Near the Turbidity Maximum in Monodisperse Suspensions of Spherical Particles

1954 ◽  
Author(s):  
Wilfried Heller ◽  
William J. Pangonis
2021 ◽  
Author(s):  
Paola Formenti ◽  
Claudia Di Biagio ◽  
Yue Huang ◽  
Jasper Kok ◽  
Marc Daniel Mallet ◽  
...  

Abstract. Optical particle counters (OPC) are widely used to measure the aerosol particle number size distribution at atmospheric ambient conditions and over a large size range. Their measurement principle is based on the dependence of light scattering on particle size. However, this dependence is not monotonic at all sizes and light scattering also depends on the particle composition (i.e., the complex refractive index, CRI) and morphology. Therefore, the conversion of the measured scattered intensity to the desired particle size depends on the microphysical properties of the sampled aerosol population and might not be unique at all sizes. While these complexities have been addressed before, corrections are typically applied ad-hoc and are not standardised. This paper addresses this issue by providing a consistent and extended database of pre−computed correction factors for a wide range of complex refractive index values representing the composition variability of atmospheric aerosols. These correction factors are calculated for five different commercial OPCs (USHAS, PCASP, FSSP, GRIMM and its airborne version Sky− GRIMM, CDP) by assuming Mie theory for homogeneous spherical particles, and by varying the real part of the CRI between 1.33 and 1.75 in steps of 0.01 and the imaginary part between 0.0 and 0.4 in steps of 0.001. Correction factors for mineral dust are provided at the CRI of 1.53 – 0.003i and account for the asphericity of these particles. The datasets described in this paper are distributed at open-access repository: https://doi.org/10.25326/234 (license CC BY, Formenti et al., 2021) maintained by the French national center for Atmospheric data and services AERIS to data users/geophysicists who number size distribution measurements from OPC for their research on atmospheric aerosols. Application and caveats of the CRI-corrections factors are presented and discussed. The dataset presented in this paper is not only useful for correcting the size distribution from an OPC when the particle refractive index is known, but even when only assumptions can be made. Furthermore, this dataset can be useful in calculating uncertainties or sensitivities of aerosol volume/mass/extinction from OPCs given no or limited knowledge of refractive index.


1947 ◽  
Vol 25b (3) ◽  
pp. 255-265 ◽  
Author(s):  
J. Bardwell ◽  
C. Sivertz

A critical study has been made of the various observations necessary for the determination of the size of small dielectric particles by the Debye–Einstein equation, which can take the form:[Formula: see text]The turbidity measurements were made with a Beckman spectrophotometer and those of refractive index with a Zeiss dipping refractometer. This article deals especially with the determination of the turbidity and refractive index gradients. The method was applied to the determination of latex particle size and gave results in good agreement with independent methods.


Clay Minerals ◽  
1993 ◽  
Vol 28 (4) ◽  
pp. 495-508 ◽  
Author(s):  
R. A. Slepetys ◽  
A. J. Cleland

AbstractCharacterization of platiness of kaolin pigments was derived from the divergence of measurements of their particle size distribution by two different techniques: sedimentation and light scattering. A numerical shape factor, which is related to the ratio of kaolin particle face diameter to its thickness, can be calculated to provide a quantitative measure of such platiness. Two sets of kaolin pigments were prepared from a Middle Georgia kaolin: delaminated and non-delaminated. Shape factors of delaminated samples were higher than those of non-delaminated ones. Maximum platiness was found between equivalent volume diameters of 1·0 and 2·0 μm. Examples are presented where properties of coated paper are correlated with the size and shape of kaolin pigments.


2006 ◽  
Vol 88 (8) ◽  
pp. 084101 ◽  
Author(s):  
N. Ghosh ◽  
P. Buddhiwant ◽  
A. Uppal ◽  
S. K. Majumder ◽  
H. S. Patel ◽  
...  

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