Photocatalytic Degradation of Methyl Orange Dye with Synthesized Chitosan/Fe2O3Nanocomposite and its Isotherm Studies.

2020 ◽  
Vol 16 ◽  
Author(s):  
Nimisha Jadon ◽  
Gulzar Ahmad Bhat ◽  
Manoharmayum Vishwanath Sharma ◽  
Harendra Kumar Sharma
Keyword(s):  
Methyl Orange ◽  
Dye Degradation ◽  
Dose Effect ◽  
X Ray Diffraction ◽  
Methyl Orange Degradation ◽  
Transmission Electron ◽  
Fourier Transformation Infrared Spectroscopy ◽  
Vis Spectroscopy ◽  
Methyl Orange Dye ◽  
Degradation Of Methyl Orange

Background: The study focuses on the synthesis of chitosan/ Fe2O3 nanocomposite, its characterization and application in methyl orange dye degradation. Methods: The synthesized chitosan/ Fe2O3 nanocomposite was characterized with Powder X-Ray Diffraction, Fourier Transformation Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and UV-Vis Spectroscopy. Results: The characterization showed that the Fe2O3nanoparticles were embedded in the polymer matrix of chitosan. The size of the Fe2O3nanoparticles were less than 10nm and the crystallite size was 1.22 nm.The synthesized chitosan/ Fe2O3nanocomposite was tested for methyl orange degradation using different parameters such as effect of contact time, effect of dose, effect of concentration and effect of pH for the degradation of methyl orange dye in aqueous solution.The Fruendlich, Langmuir and Temkin isotherm studies were also conducted for adsoption of methyl orange on Chitosan/ Fe2O3nanocomposite. Conclusion: The study indicated that the synthesized chitosan/Fe2O3 nanocomposite had the potential of degrading methyl orange dye up to 75.04% under the set condition in this experiment which indicate that Chitosan/ Fe2O3 nanocomposite is a viable option that can be used for the degradation of methyl orange dye.

scholarly journals Synthesis and Characterization of Chitosan-Polyaniline-Manganese Dioxide Nanocomposite for Removal of Methyl Orange Dye

2021 ◽  
Vol 33 (3) ◽  
pp. 671-676
Author(s):  
B.R.S. Rathore ◽  
N.P.S. Chauhan ◽  
M.K. Rawal ◽  
S.C. Ameta ◽  
R. Ameta
Keyword(s):  
Electron Microscopy ◽  
Methyl Orange ◽  
Manganese Dioxide ◽  
Oxygen Demand ◽  
Batch Adsorption ◽  
Significant Shift ◽  
X Ray Diffraction ◽  
Adsorption Method ◽  
Transmission Electron ◽  
Methyl Orange Dye

An ecofriendly polymer composite based on chitosan, polyaniline and manganese dioxide has been prepared using batch adsorption method and analyzed by Fourier transform infrared (FTIR), UV-vis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). FTIR results suggested the presence of functional groups like hydroxyl and amino groups and also shown a significant shift in IR bands in CS-PANI-MnO2 composite. The surface of composite was quite rough within the folds of pleated regions as observed from the SEM and TEM morphologies. The prepared composite was also utilized as an adsorbent for the treatment of methyl orange from the aqueous solution and achieved a reasonably good adsorption capacity of 96.2%. The biochemical oxygen demand (BOD) and chemical oxygen demand (COD) tests also suggested their suitability for the adsorption of methyl orange dye.

scholarly journals Synthesis and Characterization of Erbium Trioxide Nanoparticles as Photo-Catalytic for Degradation of Methyl Orange Dye

2019 ◽  
Author(s):  
Rifat Mohammed Dakhil ◽  
Tayser Sumer Gaaz ◽  
Ahmed Al-Amiery ◽  
Mohd S. Takriff ◽  
Abdul Amir H. Kadhum
Keyword(s):  
Catalytic Activity ◽  
Methyl Orange ◽  
Synthesis And Characterization ◽  
Photo Degradation ◽  
Photo Catalytic Activity ◽  
Xrd Diffraction ◽  
Vis Spectroscopy ◽  
Methyl Orange Dye ◽  
Degradation Of Methyl Orange

Abstract. The present work focuses on the photo-catalytic degradation of methyl orange (MO) on Erbium trioxide nanoparticles Er2O3 NPs. In this study, Er2O3 nanoparticles were synthesized and fully characterized via various techniques including; XRD diffraction, UV-Vis spectroscopy and SEM techniques. The results revealed that, the photo-catalytic activity of the prepared Er2O3 NPs towards methyl orange (MB) photo-degradation was manifested. The optimum efficiency obtained was 16 %.

Preparation and Photocatalytic Activity Research of Hollow Cubic TiO2 Particles

2011 ◽  
Vol 356-360 ◽  
pp. 558-564
Author(s):  
Xiao Wei Yuan ◽  
Xue Guo ◽  
Dan Dan Yang ◽  
Li Juan Wang ◽  
Mei Ling Cheng ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Photocatalytic Property ◽  
Methyl Orange Solution ◽  
Tetrabutyl Titanate ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Orange Solution

Hollow cubic TiO2particles were synthesized using cubic Cu2O particles as hard templates, and the hydrolysis of tetrabutyl titanate (TBOT). The products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and UV-Vis spectrometer, respectively. The results show that the prepared TiO2is composed of anatase TiO2, and has a stronger absorption in the range of 300-400nm wavelengths in its UV-Vis spectroscopy. Experiments were carried out using a methyl orange solution as a model to evaluate the photocatalytic activity of hollow cubic TiO2particles. The effects of catalyst dosage, initial concentration and pH of methyl orange solution on the degree of photodegradation have been investigated. It’s found that the hollow cubic TiO2particles have a good photocatalytic property. And the degradation rate of the methyl orange, after methyl orange solution (5mg/L) containing hollow cubic TiO2particles (0.5g/L) is irradiated by 125W ultraviolet light for 120 minutes, is 95%.

scholarly journals Synthesis and characterization of erbium trioxide nanoparticles as photocatalyzers for degradation of methyl orange dye

2019 ◽  
Vol 12 (1) ◽  
pp. 15-21 ◽  
Author(s):  
Rifat Mohammed Dakhil ◽  
Tayser Sumer Gaaz ◽  
Ahmed Al-Amiery ◽  
Mohd S. Takriff ◽  
Abdul Amir H. Kadhum
Keyword(s):  
Methyl Orange ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Visible Spectroscopy ◽  
X Ray ◽  
Uv Visible ◽  
Methyl Orange Dye ◽  
Microscopy Techniques ◽  
Degradation Of Methyl Orange

Abstract. The present work focuses on the photocatalytic degradation of methyl orange (MO) on erbium trioxide nanoparticles (Er2O3 NPs). In this study, Er2O3 nanoparticles were synthesized and fully characterized via various techniques, including X-ray diffraction, UV–visible spectroscopy and scanning electron microscopy techniques. The results revealed that the photocatalytic activity of the prepared Er2O3 NPs was manifested in MO photodegradation. The optimum efficiency obtained was 16 %.

A Novel CuO-TiO2 Composite Photocatalyst and its Degradation of Methyl Orange under UV Irradiation

2011 ◽  
Vol 295-297 ◽  
pp. 1129-1132 ◽  
Author(s):  
Shi De Wu ◽  
You Qi Zhu ◽  
Chao Li ◽  
Ying Liang Wei
Keyword(s):  
Electron Microscopy ◽  
Methyl Orange ◽  
Uv Light ◽  
Sol Gel ◽  
High Catalytic Activity ◽  
X Ray Diffraction ◽  
Composite Photocatalyst ◽  
Uv Light Irradiation ◽  
Transmission Electron ◽  
Degradation Of Methyl Orange

A novel CuO-TiO2 composite photocatalyst was prepared by a redox process coupling with sol-gel method. The morphology and structure of the as-prepared samples were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Photocatalytic activity of the CuO-TiO2 composite photocatalyst was evaluated in terms of the degradation of Methyl orange (MO) in aqueous solution under UV light irradiation. The results show that the as-prepared composite consisted of monoclinic-phase CuO-nanotubes and TiO2 nanoparticles, in which TiO2 nanoparticles were dramatically decorated on the CuO-nanotubes, exhibits a high catalytic activity to decolorize MO. According to the experimental results, 1.27wt % was the optimal loading for CuO-doped TiO2 photocatalyst.

Synthesis of Active MFe2O4/γ-Fe2O3 Nanocomposites (Metal = Ni or Co) for Reduction of Nitro-Containing Pollutants and Methyl Orange Degradation

NANO ◽  
2019 ◽  
Vol 14 (10) ◽  
pp. 1950125 ◽  
Author(s):  
G. M. El-Subruiti ◽  
A. S. Eltaweil ◽  
S. A. Sallam
Keyword(s):  
Methyl Orange ◽  
Specific Activity ◽  
Metal Salt ◽  
X Ray Diffraction ◽  
Activity Parameter ◽  
Methyl Orange Degradation ◽  
Highly Active ◽  
Transmission Electron ◽  
Ferrite Composites ◽  
Co Precipitation

Metal-ferrite/maghemite nanocomposites (NiFe2O4/***[Formula: see text]-Fe2O3 and CoFe2O4/[Formula: see text]-Fe2O[Formula: see text] were synthesized via doping maghemite with metal salt (NiCl2 or CoCl[Formula: see text] followed by reduction of metal ions using NaBH4. The synthesized metal-ferrite/maghemite nanocomposites were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), Fourier transform infrared (FTIR) and the amounts of the dopant-metal (Ni/Co) were determined using ICP-OES technique. Results showed that this synthetic route produced nanocomposites with highly active ferrite phases MFe2O4. The synthesized nanocomposites exhibited exceptional catalytic activities for the reduction of 4-nitrophenol and 2-nitroaniline as well as the catalytic degradation of methyl orange. Specific activity parameter of NiFe2O4/[Formula: see text]-Fe2O3 and CoFe2O4/[Formula: see text]-Fe2O3 toward reduction of 4-NP reached 993.9 and 929.8[Formula: see text]s[Formula: see text][Formula: see text]g[Formula: see text], respectively. These high values of specific activities are higher than most reported metal-ferrite composites prepared via traditional co-precipitation methods. Besides, strong magnetic properties of the prepared metal-ferrite/maghemites facilitates easy separation process for several reuses.

Effect of Univalent Cations Fluoride in F-Sb Codoped SnO2 Electrode on Electro-Catalytic Degradation of Methyl Orange

2012 ◽  
Vol 465 ◽  
pp. 192-197 ◽  
Author(s):  
Lu Sheng Chen ◽  
Yan Yan Liu ◽  
Huai Xiang Li ◽  
Chao Liu ◽  
Kang Wu
Keyword(s):  
Methyl Orange ◽  
Sol Gel ◽  
Catalytic Degradation ◽  
Anode Surface ◽  
Univalent Cations ◽  
X Ray Diffraction ◽  
Methyl Orange Degradation ◽  
X Ray ◽  
Degradation Rates ◽  
Degradation Of Methyl Orange

In this work, F-Sb codoped SnO2film electrode material has been prepared and used as an anode on titanium (Ti) substrate for degradation of methyl orange. The emphasis is laid on the effect of univalent cations fluoride doped during preparation of F-Sn codoped SnO2composites by sol gel method. The facts show that univalent cations fluoride could affects the electro-catalytic degradation rate of methyl orange by F-Sb codoped composite film on the Ti electrode. A promotion to the degradation rates of methyl orange could be observed when KF or NH4F was used as codopant but other fluoride codopant such as LiF, NaF or HF could slow the methyl orange degradation. X-ray diffraction (XRD) and x-ray photo-electron spectroscopy (XPS) were used to study structures and composition of the anode surface.

Preparation of Polyaniline-Modified TiO2 Nanoparticles by In Situ Chemical Oxidative Polymerization and their Photocatalytic Activity for the Degradation of Methyl Orange under Natural Light

2013 ◽  
Vol 669 ◽  
pp. 24-29
Author(s):  
Zhao Pin He ◽  
Yuan Chang Shi ◽  
Li Bo Sun ◽  
Bo Li ◽  
Hong Jiao Nie
Keyword(s):  
Photocatalytic Activity ◽  
Electron Microscope ◽  
Methyl Orange ◽  
Oxidative Polymerization ◽  
Natural Light ◽  
X Ray Diffraction ◽  
Chemical Oxidative Polymerization ◽  
Transmission Electron ◽  
Degradation Of Methyl Orange

Polyaniline-modified nanocrystalline TiO2 composites were successfully prepared by in situ chemical oxidative polymerization and used as an efficient photocatalyst for the degradation of methyl orange under natural light. The nanocomposites were characterized by Transmission electron microscope (TEM), Scanning electron microscope (SEM), Fourier transform infrared spectra (FT-IR), X-ray diffraction and UV-Vis spectra. Results show that polyaniline-modified nanocrystalline TiO2 composites exhibit significantly higher photocatalytic activity than that of neat TiO2 on degradation of methyl orange under natural light. In addition, the conductivity of polyaniline-modified TiO2 nanoparticles was also investigated and has reached 2.65 × 10-1 S cm-1 at room temperature.

Photocatalytic Properties of TiO2-Coatings Mounted on CaAl2O4:Eu2+, Nd3+ without Light Source

2009 ◽  
Vol 620-622 ◽  
pp. 671-674
Author(s):  
Hui Hui Li ◽  
Yu Hua Wang
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Methyl Orange ◽  
Light Source ◽  
Sol Gel ◽  
Photocatalytic Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Degradation Of Methyl Orange

This paper aims at the investigation of photocatalytic properties of titanium dioxide coatings covering on the surfaces of long blue-emitting afterglow CaAl2O4:Eu2+, Nd3+ elaborated by a sol-gel method. Morphologies and microstructures of the coatings were observed mainly by transmission electron microscopy (TEM) and analyzed by X-ray diffraction (XRD). The photocatalytic behavior of the TiO2-base surfaces was evaluated by the degradation of methyl orange (MO) solution. It suggested that a layer of TiO2 film mounted on the phosphor particles successfully. Also, the TiO2 coatings had remained its photocatalytic role on the as-prepared sample even after the light source was removed. The inner long blue-emitting afterglow had released blue afterglow after removing light source and allowed for reactive TiO2 surfaces to be held for the removal of methyl orange.

scholarly journals Synthesis of CdIn2S4Microsphere and Its Photocatalytic Activity for Azo Dye Degradation

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Jianhui Huang ◽  
Wei Lin ◽  
Jianqin Chen
Keyword(s):  
Electron Microscopy ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Diffuse Reflectance Spectroscopy ◽  
Dye Degradation ◽  
Ultrasonic Spray Pyrolysis ◽  
Mesoporous Structure ◽  
X Ray Diffraction ◽  
Ultrasonic Spray ◽  
Transmission Electron

CdIn2S4was prepared by ultrasonic spray pyrolysis. The prepared CdIn2S4was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FSEM), transmission electron microscopy (TEM), UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), and N2-sorption techniques. Aqueous photocatalytic activity was evaluated by the decomposition of methyl orange under visible light irradiation. The results indicate that the prepared CdIn2S4has spherical morphology with mesoporous structure which can efficiently degrade methyl orange in water. The sample prepared at 500°C exhibits the optimized photocatalytic activity.

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