scholarly journals Liquid amine–solid carbamic acid phase-separation system for direct capture of CO2 from air

Author(s):  
Soichi Kikkawa ◽  
Kazushi Amamoto ◽  
Yu Fujiki ◽  
Jun Hirayama ◽  
Gen Kato ◽  
...  

The phase separation between a liquid amine and the solid carbamic acid exhibited >99% CO2 removal efficiency under a large-scale gas stream of 400 ppm CO2. Isophorone diamine [IPDA; 3-(aminomethyl)-3,5,5-trimethylcyclohexylamine] reacted with CO2 in the CO2/IPDA molar ratio of ≥ 1 even in H2O as a solvent. The captured CO2 was completely desorbed at 333 K because the disolved carbamate ion releases CO2 at low temperature. The reusability of IPDA under CO2 adsorption-and-desorption cycles without degradation, the >95% efficinecy kept for 100 hours under direct air capture condition, and high CO2 capture rate (214 mmol/h for 1 mol amine) suggest that the phase separation system using IPDA is robust and durable for practical use.

2021 ◽  
Vol 7 (3) ◽  
pp. 58
Author(s):  
Carolina Font-Palma ◽  
David Cann ◽  
Chinonyelum Udemu

Our ever-increasing interest in economic growth is leading the way to the decline of natural resources, the detriment of air quality, and is fostering climate change. One potential solution to reduce carbon dioxide emissions from industrial emitters is the exploitation of carbon capture and storage (CCS). Among the various CO2 separation technologies, cryogenic carbon capture (CCC) could emerge by offering high CO2 recovery rates and purity levels. This review covers the different CCC methods that are being developed, their benefits, and the current challenges deterring their commercialisation. It also offers an appraisal for selected feasible small- and large-scale CCC applications, including blue hydrogen production and direct air capture. This work considers their technological readiness for CCC deployment and acknowledges competing technologies and ends by providing some insights into future directions related to the R&D for CCC systems.


Soft Matter ◽  
2021 ◽  
Author(s):  
Claudio Maggi ◽  
Matteo Paoluzzi ◽  
Andrea Crisanti ◽  
Emanuela Zaccarelli ◽  
Nicoletta Gnan

We perform large-scale computer simulations of an off-lattice two-dimensional model of active particles undergoing a motility-induced phase separation (MIPS) to investigate the systems critical behaviour close to the critical point...


2013 ◽  
Vol 744 ◽  
pp. 392-395 ◽  
Author(s):  
Hao Xian Malcolm Chan ◽  
Eng Hwa Yap ◽  
Jee Hou Ho

Carbon Capture and Storage (CCS) is one of the global leading methods that could potentially retard the speed of climate change. However, CCS on point sources can only slowdown the rate of increase of atmospheric CO2 concentration. In order to mitigate CO2 released by previous emissions, a more proactive alternative is proposed where CO2 is directly extracted and captured from air Direct Air Capture (DAC). This paper presents a technical overview from our current research of a novel DAC concept which features a phase of axial compression to adapt pre-capture atmospheric air to a level suitable for carbon capture. Also detailed in the paper is the feasibility study addressing several key issues: the energy consumption and overall capturing efficiency of the proposed DAC system.


Author(s):  
Eelco J. Rohling

In 2015, the annual mean global atmospheric carbon dioxide (CO2) level surpassed 400 parts per million (ppm; Figure 1.1), and we know very well that this rise is caused by human activities (Figure 1.2). It was the first time in 3 million years that such a level had been reached. Crossing this level has caused widespread concern among climate scientists, and not least among those called pale climatologists, who work on natural climate variability in prehistoric times, before humans. Over the last few decades, researchers have been repeatedly raising the alarm that emissions of CO2, along with those of other greenhouse gases, are getting dangerously out of control and that urgent remedial action is needed. With the crossing of the 400 ppm threshold, this sense of urgency reached a climax: at the Conference of Parties 21 meeting in Paris—also known as COP21 or the 2015 Paris Climate Conference—broad interna¬tional political agreement was reached to limit global warming to a maximum of 2°C, and if at all possible 1.5° C, by the end of this century. If one calculates this through, this implies a commitment for society to operate on zero net carbon emissions well before 2050, along with development and large-scale application of methods for CO2 removal from the climate system. (Scientists focus on carbon (C) emissions when they discuss emissions because it helps in calculating CO2 changes produced by the processing of specific volumes/ masses of fossil fuel hydrocarbons.) Clearly, the challenge is enormous, especially given that even implementing all the pledges made since COP21 would still allow warming to reach about 3°C by 2100. But, regardless, the agreement was ground breaking. It was a marker of hope, optimism, and international motivation to tackle climate change. Moreover, there are concerns about the stated COP21 targets. First, the proposed 2°C or 1.5°C limits to avoid 2 “dangerous” climate impacts may sound good, but there is no specific scientific basis for picking these particular numbers. Second, the implied “end of this century” deadline is an arbitrary moment in time.


Author(s):  
David G. Madden ◽  
Hayley S. Scott ◽  
Amrit Kumar ◽  
Kai-Jie Chen ◽  
Rana Sanii ◽  
...  

Sequestration of CO 2 , either from gas mixtures or directly from air (direct air capture), is a technological goal important to large-scale industrial processes such as gas purification and the mitigation of carbon emissions. Previously, we investigated five porous materials, three porous metal–organic materials (MOMs), a benchmark inorganic material, Zeolite 13X and a chemisorbent, TEPA-SBA-15 , for their ability to adsorb CO 2 directly from air and from simulated flue-gas. In this contribution, a further 10 physisorbent materials that exhibit strong interactions with CO 2 have been evaluated by temperature-programmed desorption for their potential utility in carbon capture applications: four hybrid ultramicroporous materials, SIFSIX-3-Cu , DICRO-3-Ni-i , SIFSIX-2-Cu-i and MOOFOUR-1-Ni ; five microporous MOMs, DMOF-1 , ZIF-8 , MIL-101 , UiO-66 and UiO-66-NH 2 ; an ultramicroporous MOM, Ni-4-PyC . The performance of these MOMs was found to be negatively impacted by moisture. Overall, we demonstrate that the incorporation of strong electrostatics from inorganic moieties combined with ultramicropores offers improved CO 2 capture performance from even moist gas mixtures but not enough to compete with chemisorbents. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.


2005 ◽  
Vol 17 (9) ◽  
pp. 094109 ◽  
Author(s):  
Filomena Califano ◽  
Roberto Mauri ◽  
Reuel Shinnar

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