scholarly journals Retention of the Antibiotic Cefuroxime onto Agricultural and Forest Soils

2021 ◽  
Vol 11 (10) ◽  
pp. 4663
Author(s):  
Raquel Cela-Dablanca ◽  
Carolina Nebot ◽  
Lucia Rodríguez López ◽  
David Ferández-Calviño ◽  
Manuel Arias-Estévez ◽  
...  

Antibiotics in wastewater, sewage sludge, manures, and slurries constitute a risk for the environment when spread on soils. This work studies the adsorption and desorption of the antibiotic cefuroxime (CFX) in 23 agricultural and forest soils, using batch-type experiments. Our results show that the adsorption values were between 40.75 and 99.57% in the agricultural soils, while the range was lower (from 74.57 to 93.46%) in forest soils. Among the Freundlich, Langmuir, and Linear models, the Freundlich equation shows the best fit for the adsorption results. In addition, agricultural soils with higher pH are the ones that present the highest adsorption. Further confirmation of the influence of pH on adsorption is given by the fact that Freundlich’s KF parameter and the Linear model Kd parameter shows a positive correlation with pH and with the exchangeable Ca and Mg values, which are known to affect the charges of the soil colloids and the formation of cationic bridges between adsorbents and adsorbate. In addition, Freundlich’s n parameter shows a positive and significant correlation with the organic matter content, related to the high adsorption taking place on forest soils despite their pH < 5. Regarding desorption, in most cases, it is lower than 1%, which indicates that CFX is adsorbed in a rather irreversible way onto these soils. Overall, these results can be considered relevant regarding their potential impact on environmental quality and public health.

2018 ◽  
Vol 42 (4) ◽  
pp. 420-430
Author(s):  
Judith Prieto Méndez ◽  
Francisco Prieto García ◽  
Nallely Trejo González ◽  
Yolanda Marmolejo Santillán ◽  
Otilio Arturo Acevedo Sandoval

ABSTRACT The accumulation of salts in the soil profile produces conditions that affect the growth of crops. The effects of these conditions on crops and the intensity of these effects depend on the quantity and type of salts that predominate and are also influenced by soil characteristics and climate, among other aspects. The salinization of agricultural soils is a serious problem facing agriculture today. The use of organic amendments has increased in recent years, acting on the texture of the soil, correcting compaction or granularity problems, and influencing chemical and/or biological reactions. The objectives of this work were to analyze the use of compost and vermicompost using different analysis techniques to determine the influence of conditions on the remediation of a saline soil. In saturation extracts of soil, compost, and vermicompost, a Zeta potential value 2.34-2.44 times more negative (more-stable colloids) than that in the soil colloids was observed in the amendments. The values of electrophoretic mobility were more negative in the organic amendments compared with the soil. This is the first time that these parameters have been reported for these purposes and for a saline soil. In this study, the soil has low organic matter content (1.65%), so these amendments are expected to improve soil quality and texture, achieving the recovery of saline soils.


1961 ◽  
Vol 9 (1) ◽  
pp. 36-40
Author(s):  
J.J. Reynders

Analyses of limestone soils under shifting cultivation, involving the growing of sweet potatoes and laros (Colocasia escalenta) for 6-8 months and a natural regeneration period of 15-20 years followed by burning of the secondary forest, showed this system to be sound. The organic-matter content of the A1 horizon shows little variation during cultivation and regeneration, and the acidity of the top soil is directly related to exchangeable-Ca levels. (Abstract retrieved from CAB Abstracts by CABI’s permission)


1998 ◽  
Vol 131 (4) ◽  
pp. 455-464 ◽  
Author(s):  
B. J. CHAMBERS ◽  
T. W. D. GARWOOD

Lime loss rates were determined for 11 agricultural soils across England (1987–92) under arable cropping (six sites) and grassland management (five sites), receiving commercial rates of fertilizer inputs. Lime additions in the range 0–1500 kg ha−1 CaCO3 (250 kg ha−1 CaCO3 increments) were made annually to the sites. Soil pH (water and 0·01 m CaCl2) and exchangeable calcium concentrations were measured annually. The annual lime loss rates were calculated as the amount of lime needed to maintain the initial site pH or exchangeable Ca concentrations.Lime loss rates based on soil water pH varied between 40 and 1270 kg ha−1 CaCO3, on the basis of CaCl2 pH between 0 and 1370 kg ha−1 CaCO3, and exchangeable Ca between 0 and 1540 kg ha−1 CaCO3. There was a positive relationship between the lime loss rate (based on water pH) and initial soil pH value (r=0·75; P<0·01), and a negative relationship with soil organic matter content (r=0·63; P<0·05) was based on soil pH, organic matter content and nitrogen (N) fertilizer input. Lime loss rates were approximately double those predicted by previous models developed in the 1970s, reflecting the greater quantities of inorganic N fertilizer now being applied to agricultural land.


Soil Research ◽  
1980 ◽  
Vol 18 (2) ◽  
pp. 163 ◽  
Author(s):  
EL Greacen ◽  
R Sands

The problem of soil compaction in forestry differs from that in agriculture because of differences in the nature of the crop, in particular the weight and size of the plant members and the length of time that they persist. The roots compact the soil as they increase in size, but they also transmit the weight of the tree and forces generated by the wind onto the soil. There are important differences in management practices; in forestry modern harvesting machines apply heavy loads and, for reasons of cost, tend to be kept in operation throughout the year. As a consequence the structure of the soil suffers some damage, often manifested as compaction. Compaction arising from such sources may reduce the growth of the current trees or trees subsequently planted on the site. But it is difficult to predict the extent of such reduction, if any, because of the complex of interactions involved. Important factors concerned, namely, the soil water regime and the organic matter content, are emphasized. A conceptual model is proposed as a predictive tool. The mechanics of soil compaction, the effects of compaction on the physical properties of the soil, and techniques for the prevention and amelioration of compaction of forest soils, are discussed.


Soil Research ◽  
2012 ◽  
Vol 50 (1) ◽  
pp. 7 ◽  
Author(s):  
Thomas Keller ◽  
Anthony R. Dexter

The plastic limits (lower plastic limit, PL; and liquid limit, LL) are important soil properties that can yield information on soil mechanical behaviour. The objective of this paper is to study the plastic limits of agricultural soils as functions of soil texture and organic matter (OM) content. The plastic limits were highly related to the clay content. The LL was more strongly correlated with clay than was PL, but the reasons are unclear. Interestingly, PL was virtually unaffected by clay content for soils with clay contents below ~35%. The OM had a strong effect on the plastic limits. This effect was clearly demonstrated when analysing soils of similar texture with a range of OM. We present equations (pedotransfer functions) for estimation of PL, LL, and plasticity index (PI) from soil texture and OM. Finally, we predict that the clay content must be ≥10% for soils without OM to be plastic; however, soils with <10% clay can be plastic if OM is present. More research is needed to investigate OM effects on soil consistency.


2021 ◽  
Author(s):  
Vito Abbruzzese

In many farm systems, both inorganic and organic fertilisers, including manure and slurry, are applied to the soil to replenish nutrient offtake in agricultural products and additional nutrient losses to soil as well as surface water and groundwater. With respect to sole reliance on inorganic fertilisers, the use of manure/slurry as a nutrient resource offers important benefits, including the reuse and recycling of nitrogen (N) and phosphorus (P) within farming systems as well as a reduction in the reliance on agricultural production on finite inorganic fertiliser reserves. There is increasing interest in the extent to which additives can enhance the nutrient value of slurry/manure. However, little is known about the impacts of these amended slurries/manures on the quantity and composition of N and P within agricultural and pasture soils. We report data from incubation experiments in which soils received a range of treatments, including the application of livestock slurry that had received a mixture of commercial additives. Our experiments were designed to understand how slurry that has received additives ultimately affects nutrient availability in organic, clay-loam and sandy-loam grassland soils. The addition of the additives to slurry resulted in a slight increase or no difference in total solids, pH, total N, ammonium-N, total P, total potassium, total magnesium and total sodium compared to the untreated counterpart. We considered the effects of our treatments on a range of agronomically important soil parameters, including Olsen-P, mineral-N, available-K, pH and organic matter content. This experiment aimed to understand the extent to which soil fertility could be enhanced through the application of slurries/manures that have received additives. The application of both amended and unamended slurry treatments on soil led to higher values of NH4-N, available-K, available Mg and pH than the addition of inorganic fertiliser. In addition, no substantial differences were observed between the treatment of the three soils with unamended and amended slurry.


Author(s):  
Д.А. Данилов ◽  
А.В. Жигунов ◽  
Б.Н. Рябинин ◽  
А.А. Вайман

Используя потенциальное плодородие посагрогенных почв, можно выращивать целевые древесные насаждения и получать балансовую и товарную древесину в более короткие сроки, чем на землях лесного фонда. Проблематика данного вопроса мало исследована и в настоящее время необходимо оценить перспективность выращивания насаждений высокой продуктивности на постагрогенных. Целью проведённого исследования было сравнение лесных и постагрогенных почв по таким параметрам, как содержание углерода органического вещества и общего азота, для прогнозирования перспективности организации хозяйства с ускоренным выращиванием продуктивных древесных насаждений на залежных землях. На постагрогенных и лесопокрытых землях были подобраны площади со сходными условиями почвообразования под спелыми древостоями, относящихся к типам леса: черничник, кисличник и дубравнотравный и почвенными комплексами постагрогенных залежных земель. Проводилась оценка ряда физико-химических показателей почв по общепринятым в почвоведении методикам: определялся гранулометрический состав, плотность сложения и мощность генетических почвенных горизонтов. Плотность сложения всех горизонтов оценивалась по Качинскому; определение углерода проводилось сухим озолением, общего азота по Кьельдалю, рН солевой вытяжки потенциометрическим методом.Анализ запасов углерода органического вещества (Сорг) и азота (Nобщ) в генетических горизонтах почв черничного, кисличного и дубравнотравного типов леса показывает увеличение содержания органического вещества и общего азота от черничного к дубравнотравному типу леса. Происходит снижение содержания органического углерода от гумусового горизонта к оподзоленному: в дубравнотравных типах леса – в 2,8; кисличных – в 7,6; в черничных – в 8,5 раз. Возобновление на постагрогенных землях носит куртинный характер или происходит по микро понижениям бывших борозд. Содержание органического вещества в пахотном горизонте данных участков постагрогенных земель находится на уровне кисличного типа леса. Содержание общего азота в данных почвах высокое от 5 до 7,4 т/га – на уровне дубравнотравного типа леса. Отношение С:N, которое характеризует обогащенность гумуса азотом, для большинства гумусовых горизонтов почв составляет 8–10, что отвечает высокой и средней степени обеспеченности этим элементом. По содержанию Сорг и Nобщ в верхнем горизонте почвы образуют следующий убывающий ряд: травяно-дубравный тип леса > залежные земли > кисличный тип леса > черничный тип леса > пашня. Проведённый сравнительный анализ физического и агрохимического состояния постагрогенных и лесных почв показал, что несмотря на предшествующее антропогенное воздействие, агрозёмный горизонт сохраняет высокое содержание органического вещества и общего азота. Ухудшение свойств постагрогенных почв на исследуемых участках не происходит и трансформации в сторону природных лесных почв региона не наблюдается, несмотря на длительный период залежности (свыше 30 лет). Соотношение углерода и азота в постагрогенных почвах по почвенному профилю показывает более высокое плодородие, чем в лесных почвах, где показатель С:N оптимален только части горизонта А1. Оценивая пригодность обследованных участков залежных земель на предмет ускоренного выращивания различных древесных пород для получения биомассы, можно констатировать, что уровень содержания органического вещества и общего азота превышает или соответствует условиям произрастания по IA –I классу бонитета для региона исследования. Using potential fertility mosagrogen soil you can grow of target woody plants and to balance and marketable timber in a shorter time than in the lands of the forest Fund. The problem of this issue is little investigated and now it is necessary to assess the prospects of growing high productivity plantations on postagrogenic. The aim of the study was to compare forest and postagrogenic soils in such parameters as the carbon content of organic matter and total nitrogen, to predict the prospects for the organization of the economy with the accelerated cultivation of productive tree plantations on fallow lands. In postagrogenic and wooded land were selected in the area with similar conditions of soil formation under ripe forest stands belonging to the forest types: myrtillus, oxalis and quercus-herbosa and postagrogenic soil complexes of fallow lands. Conducted assessment of some physico-chemical parameters of soil common in soil science methods: determined particle size distribution, the density of the composition and power of the genetic soil horizons. The density of addition of all horizons was estimated by Kaczynski; determination of carbon was carried out by dry ashing, total Kjeldahl nitrogen, pH salt extraction by the potentiometric method. Analysis of carbon stocks of organic matter (С) and nitrogen (N) in the genetic horizons of soils of blueberry, acidic and oak-grass forest types shows an increase in the content of organic matter and total nitrogen from blueberry to oak-grass forest type. There is a decrease in the content of organic carbon from the humus horizon to the ashed one: in quercus-herbosa forest types – 2.8, acidic – 7.6, myrtillus – 8.5 times. The postagrogenic restoration to the land is curtains character or occurs at the micro depressions of the former furrows. The organic matter content in the arable horizon of postagrogenic parcel of land be at the level of parents type of the wood. The content of total nitrogen in these soils is high from 5 to 7.4 t/ha – at the level of oak-grass forest type. The ratio C: N, which characterizes the enrichment of humus nitrogen, for most humus horizons of soils is 8-10, which corresponds to a high and medium degree of security with this element. According to the content of weeds and Communities in the upper horizon of the soil form the following decreasing series: quercus-herbosa type forest > lands >forest oxalis type > myrtillus type forest > arable land. Comparative analysis of physical and agrochemical condition of postagrogenic and forest soils showed that, in spite of previous anthropogenic impact, agronomy horizon maintains a high organic matter content and total nitrogen. Deterioration of the properties of postagrogenic soils in the study areas does not occur and transformation in the direction of natural forest soils of the region is not observed, despite the long period of occurrence (over 30 years). The ratio of carbon and nitrogen in postagrogenic soils by soil profile shows a higher fertility than in forest soils, where the indicator C:N is optimal only part of the horizon A1. Assessing the suitability of the surveyed areas of fallow lands for the accelerated cultivation of different species of wood to produce biomass, it can be stated that the level of organic matter and total nitrogen exceeds or corresponds to the conditions of growth in Ia –I class of bonitet for the region of the study.


2019 ◽  

<p>Application of municipal sewage sludge (MSS) to agricultural soils is a current practice in EU. European legislation permits its use in agriculture when concentrations of metals in soil do not exceed the maximum permissible limits. In order to study the influence of MSS on cotton yield and soil properties, a filed experiment was conducted in a soil classified as Typic Xerochrepts located in Lamia area, central Greece, for two consecutive years. The experimental design was complete randomized blocks with four treatments: Control (C ), inorganic fertilization (IF), application of 6000 dry kg ha-1 MSS, and 10000 dry SS kg ha-1, each replicated 4 times. The results showed that MSS application in both rates, increased significantly cotton yield compared to control equally to inorganic fertilization. Soil properties, at the end of the second year of MSS application, were significantly affected by MSS application in a positive way i.e. pH decreased slightly, but organic matter content, available phosphorus, total nitrogen concentrations exchangeable potassium and available zinc and copper increased significantly. The potentially toxic elements lead, chromium, and nickel were not significantly affected by MSS application in both application rates compared to control.</p>


2018 ◽  
Vol 7 (5) ◽  
pp. 386-395 ◽  
Author(s):  
Abdellah El Boukili ◽  
Nidae Loudiyi ◽  
Ahmed El Bazaoui ◽  
Abderrahim El Hourch ◽  
M'Hamed Taibi ◽  
...  

The present study was conducted in order to investigate the adsorption and desorption behavior of Mefenpyr-diethyl (MFD) using the batch equilibration technique in four soils, with different ranges of organic matter content, from different regions of Morocco orders of Benimellal (Soil 1), Settat (Soil 2), Sidi Bettach (Soil 3) and EL Hajeb (Soil 4). The adsorption isotherm models Langmuir, linear and Freundlich were used to compare the adsorption capacity of the soils. The results indicated that the Freundlich equation provided the best fit for all adsorption data. The values of KF and Kd ranged from 4.45 to 15.9 and 4.30 to 18.30 L.kg-1 , respectively. The calculated total percentage of desorption values from the Soil 1, Soil 2, Soil 3 and Soil 4 after the four desorption process were 59 %; 55,6 %; 37,5 % and 52,5%, respectively. Highest adsorption and desorption were observed in soil 1, and the lowest was in soil 3. According to the adsorption and desorption results, organic matter and clay seemed to be the most important factors influencing the adsorption capacity of MFD.


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