scholarly journals Biodegradable Flame Retardants for Biodegradable Polymer

Biomolecules ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1038
Author(s):  
Muhammad Maqsood ◽  
Gunnar Seide
Keyword(s):  
Renewable Resources ◽  
Flame Retardants ◽  
Fire Risk ◽  
Polymeric Materials ◽  
Good Choice ◽  
Airborne Particle ◽  
Short Term ◽  
Renewable Materials ◽  
Long Time ◽  
Significant Attention

To improve sustainability of polymers and to reduce carbon footprint, polymers from renewable resources are given significant attention due to the developing concern over environmental protection. The renewable materials are progressively used in many technical applications instead of short-term-use products. However, among other applications, the flame retardancy of such polymers needs to be improved for technical applications due to potential fire risk and their involvement in our daily life. To overcome this potential risk, various flame retardants (FRs) compounds based on conventional and non-conventional approaches such as inorganic FRs, nitrogen-based FRs, halogenated FRs and nanofillers were synthesized. However, most of the conventional FRs are non-biodegradable and if disposed in the landfill, microorganisms in the soil or water cannot degrade them. Hence, they remain in the environment for long time and may find their way not only in the food chain but can also easily attach to any airborne particle and can travel distances and may end up in freshwater, food products, ecosystems, or even can be inhaled if they are present in the air. Furthermore, it is not a good choice to use non-biodegradable FRs in biodegradable polymers such as polylactic acid (PLA). Therefore, the goal of this review paper is to promote the use of biodegradable and bio-based compounds for flame retardants used in polymeric materials.

scholarly journals Soy-Based Polyols and Polyurethanes

KIMIKA ◽  
2017 ◽  
Vol 28 (1) ◽  
pp. 1-19 ◽  
Author(s):  
Arnold A. Lubguban ◽  
Rosal Jane G. Ruda ◽  
Rae Homer Aquiatan ◽  
Shierlyn Paclijan ◽  
Kriztine O. Magadan ◽  
...  
Keyword(s):  
Renewable Resources ◽  
Unsaturated Fatty Acids ◽  
Review Paper ◽  
Polymeric Materials ◽  
Plant Oils ◽  
Equivalent Weight ◽  
Research Fields ◽  
Significant Attention ◽  
Effective Reaction ◽  
Reaction Routes

Polymers derived from plant oils have attracted major commercial interest and significant attention in scientific research because of the availability, biodegradability, and unique properties of triglycerides. Triglycerides rich in unsaturated fatty acids, such as soybean oil (SBO), are particularly susceptible to chemical modification for desired polymeric materials. Soy-based polyols are important industrial prepolymeric materials that use renewable resources; and can be produced or derived through different processing routes. This review paper discusses previous and recent researches about chemical and biochemical polymerization processes to produce soy-based polyols as prepolymers for the production of polyurethane materials in the form of foams (rigid or flexible) and elastomers. The central goal of these research fields is to find effective reaction routes to increase both equivalent weight and hydroxyl functionality of soy-based polyols while taking into consideration the simplicity and economics of these processes.

Time Window from Visual Images to Visual Short-Term Memory: Consolidation or Integration?

2004 ◽  
Vol 51 (1) ◽  
pp. 45-51 ◽  
Author(s):  
Yuhong Jiang
Keyword(s):  
Short Term Memory ◽  
Time Window ◽  
Short Interval ◽  
Visual Images ◽  
Short Term ◽  
Temporal Window ◽  
Term Memory ◽  
Visual Short Term Memory ◽  
Probe Task ◽  
Long Time

Abstract. When two dot arrays are briefly presented, separated by a short interval of time, visual short-term memory of the first array is disrupted if the interval between arrays is shorter than 1300-1500 ms ( Brockmole, Wang, & Irwin, 2002 ). Here we investigated whether such a time window was triggered by the necessity to integrate arrays. Using a probe task we removed the need for integration but retained the requirement to represent the images. We found that a long time window was needed for performance to reach asymptote even when integration across images was not required. Furthermore, such window was lengthened if subjects had to remember the locations of the second array, but not if they only conducted a visual search among it. We suggest that a temporal window is required for consolidation of the first array, which is vulnerable to disruption by subsequent images that also need to be memorized.

scholarly journals Subway Gearbox Fault Diagnosis Algorithm Based on Adaptive Spline Impact Suppression

Entropy ◽  
2021 ◽  
Vol 23 (6) ◽  
pp. 660
Author(s):  
Zhongshuo Hu ◽  
Jianwei Yang ◽  
Dechen Yao ◽  
Jinhai Wang ◽  
Yongliang Bai
Keyword(s):  
Fault Diagnosis ◽  
Spline Interpolation ◽  
Reference Value ◽  
High Amplitude ◽  
Engineering Practice ◽  
Negative Effects ◽  
Short Term ◽  
Time Domain Signal ◽  
Gearbox Vibration ◽  
Long Time

In the signal processing of real subway vehicles, impacts between wheelsets and rail joint gaps have significant negative effects on the spectrum. This introduces great difficulties for the fault diagnosis of gearboxes. To solve this problem, this paper proposes an adaptive time-domain signal segmentation method that envelopes the original signal using a cubic spline interpolation. The peak values of the rail joint gap impacts are extracted to realize the adaptive segmentation of gearbox fault signals when the vehicle was moving at a uniform speed. A long-time and unsteady signal affected by wheel–rail impacts is segmented into multiple short-term, steady-state signals, which can suppress the high amplitude of the shock response signal. Finally, on this basis, multiple short-term sample signals are analyzed by time- and frequency-domain analyses and compared with the nonfaulty results. The results showed that the method can efficiently suppress the high-amplitude components of subway gearbox vibration signals and effectively extract the characteristics of weak faults due to uniform wear of the gearbox in the time and frequency domains. This provides reference value for the gearbox fault diagnosis in engineering practice.

scholarly journals Fire-Safe Polymer Composites: Flame-Retardant Effect of Nanofillers

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 540
Author(s):  
Yukyung Kim ◽  
Sanghyuck Lee ◽  
Hyeonseok Yoon
Keyword(s):  
Organic Matter ◽  
High Temperature ◽  
Flame Retardant ◽  
Flame Retardants ◽  
Combustion Process ◽  
Polymeric Materials ◽  
Fire Performance ◽  
Gaseous Species ◽  
Advantages And Disadvantages ◽  
Temperature Conditions

Currently, polymers are competing with metals and ceramics to realize various material characteristics, including mechanical and electrical properties. However, most polymers consist of organic matter, making them vulnerable to flames and high-temperature conditions. In addition, the combustion of polymers consisting of different types of organic matter results in various gaseous hazards. Therefore, to minimize the fire damage, there has been a significant demand for developing polymers that are fire resistant or flame retardant. From this viewpoint, it is crucial to design and synthesize thermally stable polymers that are less likely to decompose into combustible gaseous species under high-temperature conditions. Flame retardants can also be introduced to further reinforce the fire performance of polymers. In this review, the combustion process of organic matter, types of flame retardants, and common flammability testing methods are reviewed. Furthermore, the latest research trends in the use of versatile nanofillers to enhance the fire performance of polymeric materials are discussed with an emphasis on their underlying action, advantages, and disadvantages.

scholarly journals Physical Properties of Thermoplastic Starch Derived from Natural Resources and Its Blends: A Review

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1396
Author(s):  
Z. N. Diyana ◽  
R. Jumaidin ◽  
Mohd Zulkefli Selamat ◽  
Ihwan Ghazali ◽  
Norliza Julmohammad ◽  
...  
Keyword(s):  
Thermoplastic Starch ◽  
Natural Fibre ◽  
Polymer Materials ◽  
Secondary Pollution ◽  
Wide Range ◽  
Potential Applications ◽  
Long Time ◽  
To Come ◽  
Main Component ◽  
Significant Attention

Thermoplastic starch composites have attracted significant attention due to the rise of environmental pollutions induced by the use of synthetic petroleum-based polymer materials. The degradation of traditional plastics requires an unusually long time, which may lead to high cost and secondary pollution. To solve these difficulties, more petroleum-based plastics should be substituted with sustainable bio-based plastics. Renewable and natural materials that are abundant in nature are potential candidates for a wide range of polymers, which can be used to replace their synthetic counterparts. This paper focuses on some aspects of biopolymers and their classes, providing a description of starch as a main component of biopolymers, composites, and potential applications of thermoplastics starch-based in packaging application. Currently, biopolymer composites blended with other components have exhibited several enhanced qualities. The same behavior is also observed when natural fibre is incorporated with biopolymers. However, it should be noted that the degree of compatibility between starch and other biopolymers extensively varies depending on the specific biopolymer. Although their efficacy is yet to reach the level of their fossil fuel counterparts, biopolymers have made a distinguishing mark, which will continue to inspire the creation of novel substances for many years to come.

scholarly journals Post-Wildfire Logging Hinders Regeneration and Increases Fire Risk

Science ◽  
2006 ◽  
Vol 311 (5759) ◽  
pp. 352-352 ◽  
Author(s):  
D. C. Donato ◽  
J. B. Fontaine ◽  
J. L. Campbell ◽  
W. D. Robinson ◽  
J. B. Kauffman ◽  
...  
Keyword(s):  
Fire Risk ◽  
Fuel Reduction ◽  
Short Term ◽  
High Severity ◽  
Fuel Loads ◽  
Conifer Regeneration ◽  
Biscuit Fire ◽  
Additional Reduction

We present data from a study of early conifer regeneration and fuel loads after the 2002 Biscuit Fire, Oregon, USA, with and without postfire logging. Natural conifer regeneration was abundant after the high-severity fire. Postfire logging reduced median regeneration density by 71%, significantly increased downed woody fuels, and thus increased short-term fire risk. Additional reduction of fuels is necessary for effective mitigation of fire risk. Postfire logging can be counterproductive to the goals of forest regenration and fuel reduction.

scholarly journals Methods of long-term and short-term adaptation for biometric image of keystroke dynamics

2021 ◽  
Vol 7 (3D) ◽  
pp. 450-457
Author(s):  
Dmitry V. Pashchenko ◽  
Dmitry A. Trokoz ◽  
Alexey I. Martyshkin ◽  
Elena A. Balzannikova
Keyword(s):  
Working Capacity ◽  
Keystroke Dynamics ◽  
Short Term ◽  
User Identification ◽  
New Device ◽  
Short Term Adaptation ◽  
Long Time

This article discusses one of the main problems of user identification by keyboard handwriting - short-term changes in the keystroke dynamics of users in connection with its psychophysical state, as well as changes over a long time associated with the formation of keystroke dynamics by a new user or when switching to a new device. A method for determining the phase of working capacity by the time characteristics of the keystroke dynamics is proposed.

Short-term fire risk: foliage moisture content estimation from satellite data

1999 ◽  
pp. 17-38 ◽  
Author(s):  
Emilio Chuvieco ◽  
Michel Deshayes ◽  
Nicholas Stach ◽  
David Cocero ◽  
David Riaño
Keyword(s):  
Moisture Content ◽  
Satellite Data ◽  
Fire Risk ◽  
Short Term

scholarly journals Planting and harvesting innovation - an analysis of Samsung Electronics

2019 ◽  
Vol 5 (1) ◽  
Author(s):  
Seung Hoon Jang ◽  
Sang M. Lee ◽  
Taewan Kim ◽  
Donghyun Choi
Keyword(s):  
Early Stage ◽  
New Products ◽  
Limited Resources ◽  
High Tech ◽  
Short Term ◽  
Entire Life ◽  
Entire Life Cycle ◽  
Time Period ◽  
Innovation Projects ◽  
Long Time

Abstract This study explores how firms manage the entire life cycle of innovation projects based on the framework of harvesting and planting innovation. While harvesting innovation seeks new products in the expectation of financial performance in the short term, planting innovation pursues creating value over a long time period. Without proper management of the process of planting and harvesting innovation, firms with limited resources may not be successful in launching innovative new products to seize a momentum in high tech industries. To examine this issue, the case of Samsung Electronics (SE), now an electronics giant originated from a former developing country, is analyzed. SE has shown to effectively utilize co-innovation to maintain numerous planting and harvesting innovation projects. Both researchers and practitioners would be interested in learning about how SE shared risks of innovation investment with external partners at the early stage of innovation cycles.

scholarly journals Cyclodextrins and Cyclodextrin Derivatives as Green Char Promoters in Flame Retardants Formulations for Polymeric Materials. A Review

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 664 ◽  
Author(s):  
Maria Paola Luda ◽  
Marco Zanetti
Keyword(s):  
Flame Retardants ◽  
Environmental Concern ◽  
Fire Retardant ◽  
Polymeric Materials ◽  
Poly Lactic Acid ◽  
Mechanical Resistance ◽  
Self Healing ◽  
Cyclodextrin Derivatives ◽  
The Matrix ◽  
Fire Retardance

Polymers are intrinsically flammable materials; hence, fire retardance (FR) is required in their most common applications (i.e., electronic and construction, to mention some). Recently, it has been reported that cyclodextrin (CD) and cyclodextrin derivatives are beginning to be introduced into Intumescent Fire Retardant (IFR) formulations in place of pentaerythritol, which is used in IFRs that are currently on the market. Since IFRs are of less environmental concern than their hazardous halogen containing counterparts, the use of natural origin compounds in IFRs provides a way to comply with green chemistry issues. BCD and BCD derivatives presence in IFR mixtures promotes a higher yield of blowing gases and char when polymeric materials undergo combustion. Both processes play important roles in intumescence. The key rule to obtain in insulating compact char is the good dispersion of the nanoparticles in the matrix, which can be achieved by functionalizing nanoparticles with BCD derivatives. Moreover, CD derivatives are attractive because of their nanosized structure and their ability to form inclusion complexes with many compounds used as FR components, reducing their release to the environment during their shelf life of FR items. Often, fire retardance performed by BCD and BCD derivatives accompanies other relevant properties, such as improved mechanical resistance, washability resistance, self healing ability, thermal conductivity, etc. The application of CD fire retardant additives in many polymers, such as poly(lactic acid), poly(propylene), poly(vinyl acetate), poly(methyl methacrylate), linear low density poly(ethylene), polyamides, and polyesters are comprehensively reviewed here.

Sign in / Sign up

Export Citation Format

Share Document