scholarly journals Foam Glass Crystalline Granular Material from a Polymineral Raw Mix

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1447
Author(s):  
Olga Miryuk ◽  
Roman Fediuk ◽  
Mugahed Amran

The article is devoted to the development of resource-saving technology of porous granular materials for energy-efficient construction. The relevance of the work for international research is to emphasize expanding the raw material base of porous lightweight concrete aggregates at the expense of technogenic and substandard materials. The work aims to study the processes of porization of glass crystalline granules from polymineral raw materials mixtures. The novelty of the work lies in the establishment of regularities of thermal foaming of glass crystalline granules when using waste of magnetic separation of skarn-magnetite (WMS) ores and lignite clay. Studies of liquid glass mixtures with various mineral fillers revealed the possibility of the formation of a porous structure with the participation of opoka, WMS and lignite clay. This is due to the presence in the materials of substances that exhibit thermal activity with the release of a gas phase. The foaming efficiency of the investigated materials increases when combined with glass breakage. The addition of WMS and lignite clay to the glass mixture increases the pore size in comparison with foam glass. The influence of the composition of raw mixtures on the molding and stability of granules is determined. The addition of sodium carbonate helps to strengthen the raw granules and reduce the softening temperature of the mass. The composition of the molding mixture of glass breakage, liquid glass and a multicomponent additive is developed, which provides an improvement in the molding properties of the glass mass, foaming of granules at a temperature of 750 °C. Foam glass crystalline granules have polymodal porosity, characterized by a density of 330–350 kg/m3, a compressive strength of 3.2–3.7 MPa, and a thermal conductivity of 0.057–0.061 W/(m·°C). Accordingly, the developed granules have a high potential use in structural and heat-insulating concretes.

Author(s):  
А. Х. Аласханов

В работе приводятся возможности расширения сырьевой базы для получения качественных и прочных строительных композитов. Приводится понятие о ресурсном цикле, основанном на природном круговороте веществ (ПКВ) и обеспечивающем безотходный замкнутый цикл производства композитов. Обозначена актуальность и перспективность перехода на энерго- и ресурсосберегающие технологии безотходного производства. The paper presents the possibilities of expanding the raw material base to obtain high-quality and durable building composites. The concept of a resource cycle based on the natural cycle of substances (PCR) and providing a waste-free closed cycle for the production of composites is given. The relevance and prospects of the transition to energy- and resource-saving technologies of waste-free production are indicated.


2020 ◽  
Vol 24 (1) ◽  
pp. 90-102
Author(s):  
M. P. Stepanova ◽  
O. A. Sotnikova

Purpose of research is to study cheaper composite materials for building structures such as cement-free ones without heat treatment, which will undoubtedly allow finding their application in building industry. To achieve this goal it is necessary to identify patterns of structure formation of clinker-free contact condensation hardening composite materials in which portlandite crystals act as a matrix, and the physicochemical active component of natural origin acts as a filler.Methods. In accordance with the purpose set, one of the main tasks of the work was to be solved; it involved study-ing the patterns of structure formation of contact-condensation hardening systems relying on the basic principles of materials science, which include studying the influence of the composition, structure and state of the starting com-ponents on the properties of a composite material. In this work, we studied the role of the physicochemical activity of raw materials and the possibility of ‘combining’ a portlandite matrix with filling mechano-physicochemical active raw materials capable of producing new structures. To form the composite material, a compaction pressing technique at elevated specific pressures was used, which made it possible to implement the mechanisms of contact condensation technology of structure formation. The formation of physicochemical bonds of portlandite and aluminosilicate filler of various types is also possible with certain ratios of their mass fractions and V/I ratios the optimization of which was one of our objectives.Results. The result of this work is to assess the impact of raw material characteristics and technology parameters on the properties of the resulting material, namely, the improvement of the compacting pressure and the amount of filler when getting a compacted composite.Conclusion. The development of a technology of producing clinker-free contact condensation composites based on portlandite with aluminosilicate filler will expand the raw material base of local building materials, reduce their cost and energy consumption, that is, solve key issues of resource saving in the building materials production.


Author(s):  
I. F. Iskakov ◽  
G. A. Kunitsyn ◽  
D. V. Lazarev ◽  
А. А. Red`kin ◽  
S. A. Trubitsyn ◽  
...  

To use effectively internal raw material base, JSC “Ural Steel” accomplished I category major overhaul of the blast furnace No. 2. The main purpose of the overhaul was to design a rational profile which could ensure an ability to operate with a charge containing 95 % of Mikhailovskii GOK (mining and concentrating plant) pellets having basicity of 0.5 by CaO/SiO2. The blast furnace No. 2 having useful volume of 1232 m3, was constructed by design of Danieli Corus, the Netherlands, and was blown in on December 30, 2020. In the process of guarantee tests, step-by-step increase of Mikhailovskii GOK pellets (Fetotal = 60.5 %, CaO/SiO2 = 0.5) content in the charge iron ore part was being accomplished from 55 to 95.1%. Charging of the blend containing pellets in the amount of 55% of iron ore part, was done by charging system 4OOCC + 1COOCC (Ore - Coke) with filling level 1.5 m. Under conditions of pellets part increase in the blend, the charging system was changed to decrease their content at the periphery, to increase it in the ore ridge zone and make it intermediate between periphery and the ore ridge. At the pellets share in the iron ore raw materials 0.75 the charging system was used as the following: 3OOCC + 1COOC + 1COOCC, while at the content 95.1% the following charging system was used: 2COOC + 2COOC + 1COOCC. It was noted that in the period of guarantee tests the furnace running was smooth. The average silicon content in the hot metal was 0.70% at the standard deviation 0.666. Sulfur content in the hot metal did not exceed 0.024%, the blowing and natural gas consumption figures were 2100 m3/min and 11000 m3/min correspondently, oxygen content in the blowing 26.5%, hot blowing and top smoke pressure figures were 226.5 and 109.8 KPa correspondently. The productivity of the furnace was reached as high as 2358 t/day at the specific coke rate 433 kg/t of hot metal. After guarantee tests completion, the pellets content in the iron ore part was decreased gradually from 95 down to 50%. The decreasing was made by 5% in every 6 hours of operation. Application of the mastered technology of the blast furnace No. 2 with the increased share of pellets will enable to stably supply the blast furnaces No. 1, 3 and 4 by iron ore raw materials in the proportion of 30-35% of pellets and 65-70% of sinter.


2021 ◽  
Vol 316 ◽  
pp. 1050-1054
Author(s):  
V.N. Zyryanova ◽  
E.V. Lytkina ◽  
A.P. Ochur-Ool

Increasing water resistance and mechanical strength of hardening magnesian binders’ products can be achieved by introducing microfillings into a hardening dispersed system. It is shown that serpentine provides an increase strength and water resistance in hydration and hardening process, being as a structure-forming component, it intensifies this process. It allows expanding the raw material base for the production of magnesia binders for construction purposes.


2021 ◽  
Vol 9 (16) ◽  
pp. 90-97
Author(s):  
Kateryna Danilova ◽  
◽  
Oksana Zavarzina ◽  

An actual problem of the alcohol industry development is the expansion of the raw material base through the use of new, cheaper types of carbohydrate sources. Recently, glucose-fructose syrup has been of increasing interest to producers of ethanol. Among the producers of craft drinks, in particular rum-based drinks, cane molasses is in increasing demand. The article presents the technological aspects of the fermentation process of nonconventional sugar-containing raw materials on the example of glucose-fructose syrup and cane molasses in ethanol by different yeast strains. It is determined that glucose-fructose syrup and cane molasses are raw materials depleted of nitrogen, phosphorus and growth substances necessary for the yeast activity. To improve the technological properties of raw materials in the molasses, nitrogen, phosphorus nutrition and corn extract as a growth substance shall be added to a mash. Glucose-fructose syrup is of pH 3.68 and of acidity 0.12, which negatively affects the fermentation. It is established that in order to create optimal living conditions for yeast, it is necessary to add substances to the glucose-fructose syrup that will contribute to the safety of development and prevent the pH 3.5. It was determined that the alcohol yield from 1 ton of glucose-fructose syrup is 31.0 dal, from 1 ton of cane molasses is 24.0 dal on the yeast 46ED and 22 dal on the TegaYeast without the use of growth substances and vitamins necessary for the reproduction of yeast biomass. Under conditions of improving the technological properties of the mash from the glucose-fructose syrup and cane molasses by adding biologically active substances promoting the synthesis of yeast biomass, the ethanol content in the fermented mashes increases up to 11.9 12% vol.


2021 ◽  
Vol 9 (A) ◽  
pp. 313-317
Author(s):  
Svetlana Ivasenko ◽  
Ainur Zhumabekova ◽  
Agnieszka Ludwiczuk ◽  
Krystyna Skalicka–Wozniak ◽  
Alexandr Marchenko ◽  
...  

BACKGROUND: A possible reduction in stocks of medicinal plant raw materials of Thymus serpyllum L. and Thymus vulgaris L. leads to the need to expand the raw material base of the official medicinal plants with using of endemic species of the flora of Kazakhstan, in particular, Thymus rasitatus Klokov, and Thymus eremita Klokov. AIM: The aim of the study was to study the possibility of using 70% ethanol extracts of T. rasitatus and T. eremita as antimicrobial agents. MATERIALS AND METHODS: The aerial parts of T. rasitatus and T. eremita were extracted with 70% ethanol using ultrasound assisted extraction. The qualitative and quantitative analyses of the 70% ethanol extracts were determined using the liquid chromatography-detection-ESI-mass spectrometry-(MS)/MS technique. The study of the antimicrobial activity of these extracts was performed for eight strains of Gram-positive bacteria, six strains of Gram-negative bacteria, and four cultures of fungi. RESULTS: Chromatographic analysis of hydroalcoholic extracts of both investigated Thymus species showed very similar phenolic compounds composition. In both cases, the major components are luteolin-7-O-glucoside and rosmarinic acid. About 70% ethanol extracts of T. rasitatus and T. eremita have a broad spectrum of antimicrobial activity, exhibit the bactericidal or bacteriostatic activity against all tested bacteria and fungi at concentration range of 0.0195–20 mg/ml, but differ in their potency against tested strains of microorganisms. CONCLUSION: About 70% ethanol extracts of T. rasitatus and T. eremita, endemic plants in the flora of Kazakhstan, can be considered as potential drugs with a wide spectrum of antimicrobial activity. The results of chromatographic analysis could be used for drug standardization.


2020 ◽  
Author(s):  
P.A. Kozlov ◽  
A.M. Panshin ◽  
L.I. Leontiev

The increasing demand for zinc and a range of zinc-related metals (for example: lead; indium; tin; cadmium; and copper) in the Russian Federation cannot be satisfied by the existing production plants due to the lack of raw materials. At the same time, ferrous and non-ferrous metallurgy and the chemical industry have accumulated hundreds of millions of tons of zinc wastes (falling into the hazard categories 2 to 4), the processing of which could not only make up the raw material base, but also improve the environmental situation. In the world, over 85% of ferrous dust is recycled using the Waelz process. The Waeltz process is used for distilling separation of elements under reducing conditions. In this study, a block diagram for production of the following elements from industrial wastes is proposed: zinc, cadmium and indium in form of massive metals; zinc and indium in the form of fine powders; and clinker as a raw material for cement production. The technical and scientific details of this new process have been patented in the Russian Federation and abroad. For the first time, the following operations have been implemented with the use of large-sized Waelz kilns: vapour-oxidized Waeltz treatment of polymetallic wastes; recycling of heat from gases and solid products with generation of process fumes; and implementation of alternative flux (dolomite) and alternative fuel (petroleum coke). Keywords: Waelz process, industrial wastes, heat recycling, vapour-oxidized Waelz processing


2015 ◽  
Vol 1 (12) ◽  
Author(s):  
Slobodan Majstorović ◽  
Vladimir Malbašić ◽  
Miodrag Čelebić

Curent situation of raw material base and study of limestone like construction stone deposits in the Republic of Serbian were relatively poorly considered during the last decades, and the main problems are the following: low production capacity fragmentation of production, needs for raw materials homogenization and delivering of standard quality, undeveloped market, the recession of the domestic economy and the economies in the region, the relatively low level of exploration by many deposits, especially lack of knowledge of the occurrence legality for certain types and quality of raw materials and lack of complete quality indicators for raw material, which sometimes causes the utilization of only the highest quality deposit parts.This paper provides an overview of active quarries in the Republic Srpska with exploitation of limestone like technical building stone and present an attempt to determine the basic quantitative and qualitative characteristics of the raw material and the current working conditions at these quarries. The purpose of such a review would be in an effort to create a clearer picture about production, market, social and other aspects of the limestone exploitation in the Republika Srpska and the realistic possibilities of maintaining and developing of these mineral resources utilization, which can certainlybe interesting for the development of many other industries in the Republic Srpska.


2019 ◽  
Vol 27 (3) ◽  
pp. 510-519
Author(s):  
M. Syvyj ◽  
B. Gavrychok

This article presents the characteristics of the resource base of building sands within the three Podillya regions, the patterns of sands distribution, and proposals for increasing the extraction of raw materials . The construction sands of Podillya are confined to the Upper Cretaceous, Neogene and Anthropogenicdeposits. The decrease of the thickness of the sandy strata of the Opilsk Neogene suite in the eastern direction was observed with the simultaneous increase in the thickness of the overlapping strata of the rocks. There is no apparent correlation between the thickness of sandy interlayers and the quality of sands. The interdependence of the chemical composition of Neogene sands and the sand size module is established.The genetic predisposition for the distribution of building sands in different parts of the Podillya territory has been established. Four groups of sand deposits of different age have been identified within the Podillya regions, which contrast sharply with single deposits in the neighbouring territories.There is a very uneven distribution of explored reserves of sandy raw materials across the region and accordingly in the provision of construction sands in the different oblasts /regions of Podillya. The areas best provided with sandy raw materials are the central districts of Ternopil region and Slavutsky district of Khmelnytsky region . Sands of the Baltic stage distributed in Vinnytsia region are mostly poor in quality, clogged with clay material and require enrichment. The further development of the mineral raw material base and the prospects for increasing the production of construction sand in the Podillya regions is associated with the increase in production at the prepared deposits, the commissioning of reserve deposits, the conducting of prospecting and exploration work in the proposed potentially exploitable areas and additional exploration of individual deposits that are exploited. The research allows us to evaluate objectively the existing base of sand raw materials for various purposes in the Podillya region and to develop on this basis measures to increase it. The importance of the study is determined by the acute shortage of the raw material in most administrative districts of Khmelnytsky and Vinnytsia regions, by the growth in the volume of construction work (and accordingly the requirements for sandy raw materials) both in Podillya and in the country.


Author(s):  
Yu. V. Lykholat ◽  
N. O. Khromykh ◽  
T. Yu. Lykholat ◽  
M. I. Nedzvetska ◽  
O. A. Lykholat ◽  
...  

The introduction of fruit plants into a culture enriches the diversity of the species composition of the regional flora and at the same time creates an opportunity for expansion of the plant raw material base for the needs of the food industry, inclusion in a full-fledged functional nutrition of the population. Among the fruit plants of the Dniprovsk region, every year, more attention should be paid to introduced low-frequency non-traditional fruit species, in which the fruits, leaves, stems and other parts have high nutritional value and are the source of physiologically active compounds that have anti-cancer, antibacterial and anti-inflammatory properties, carry cardio protective, antihypertensive, anti-diabetic effects, stimulate the central nervous system, etc., and can contribute to the prevention and treatment of many diseases.   Antioxidants additives in the raw materials and finished products ensures their prevention damage, reduce losses, increase shelf life and production of high quality products which keep for a long time characteristics inherent fresh, complete products. Preservation, restoration and introduction to the culture of any species depends primarily on its ability to multiply seed and vegetative methods. A comparative analysis of the fruit and seed ability of Berberis L. representatives grown in the botanical garden of Oles Gonchar’  Dniprovsky National University was carried out. The use of integrated research methods made it possible to carry out an integrated assessment of the regenerative capacity of the investigated representatives of the Berberis L. and to establish their biological ability to seed propagation depending on the seed quality of the seeds. The seeds length varied from 4.5 mm (B. canadensis) to 5.2 mm (B. declinata, B. amurensis), width was from 1.8 mm (B. amurensis, B. vulgares) to 2.1 mm ( B. coreana). The weight of 1000 seeds, which, depending on their size and completeness, amounted to an average of 10.16 grams. Largest weight 1000 pcs. seed is marked in B. coreana. As a result of the total antioxidant ability of the fruits, the species examined can be arranged in the following order:  B. koreana > B. x declinata > B. vulgaris > B. amurensis > B. canadensis. When comparing total antioxidant capacity level of the plants, the highest indices were characteristic for B. koreana and B. x declinata fruits, which exceeded the values of other species in 1.7-1.9 times. The relatively low antioxidants concentration in B. amurensis fruits is offset by a greater weight of the fruits of this species.  In order to enrich the range of ornamental and fruit plants, it is expedient to introduce into production of new crops and to expand the species diversity of Berberis L. representatives. Barberry reproduction process depends on many factors related to the environment. All investigated representatives of the Berberis L. are promising for further use in the planting system and as fruit plants that can be included in the functional nutrition of the population and use in the food industry in the conditions of the Steppe Prydniprovya.


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