scholarly journals Health-Promoting Properties of Borage Seed Oil Fractionated by Supercritical Carbon Dioxide Extraction

Foods ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 2471
Author(s):  
Lourdes Casas-Cardoso ◽  
Casimiro Mantell ◽  
Sara Obregón ◽  
Cristina Cejudo-Bastante ◽  
Ángeles Alonso-Moraga ◽  
...  

Borage (Borago officinalis L.) seed oil is an important source of γ–linolenic acid, which is normally used as a treatment against different pathologies. Since the fractionation of this interesting seed oil has many environmental, economic and biological benefits, two borage fractionation techniques after extraction with CO2 under supercritical conditions have been studied: precipitation in two cyclone separators and countercurrent extraction column. Both techniques have successfully collected free fatty acids in one fraction: (i) two separators set up in series obtained the highest concentration of free fatty acids in separator 2 at 90 bar/40 °C; (ii) when countercurrent extraction column was used, the acidity index of the raffinate stream was independent from the operating conditions (2.6 ± 0.5%). Furthermore, the composition of the fatty acids, as well as their antioxidant and cytotoxic activities, were determined. The profile of the fatty acids obtained by either of these two methods remained unaltered, so that the crude oil exhibited improved antioxidant and cytotoxic properties. All the extracts obtained in the two cyclone separators at the same pressure/temperature conditions displayed high tumouricidal activity against HL 60 promyelocytic leukaemia cells, even if the extracts at 50% concentration from separator 2 presented a lower inhibitory activity (IC50). The extracts from separator 2 at 90 bar/40 °C exhibited the highest anti-proliferative activity at low doses (IC50 of 0.3 μL/mL for the trypan blue exclusion test). To reach the lethal dose—IC50—with the product obtained through countercurrent column fractionation, a concentration of 2 μL/mL of crude borage oil raffinate was required.

1989 ◽  
Vol 44 (9-10) ◽  
pp. 739-742 ◽  
Author(s):  
Heidrun Dresen ◽  
R. B. N. Prasad ◽  
Paul-Gerhard Gülz

Abstract The lipid composition of Piqui (Caryocar coriaceum) seed oil and pulp oil was analyzed and found to contain triacylglycerols (95.1/95.3%) as major components followed by free fatty acids (1.7/1.6%), diacylglycerols (1.6/1.5%), squalene (0.3/0.3%) and monoacylglycerols (0.1/0.1%). Phospholipids were found only in seed oil (0.2%). They were identified as phosphatidylethanolamine and phosphatidylinositol. The sterol fraction (0.1/0.1%) contained stigmasterol and β-sito-sterol. In seed oil triacylglycerols the C-53 molecular species were dominated (52.8%) follow ed by C-55 (37.7%), C-57 (6.9%) and C-51 (2.6%) in minor quantities. In pulp oil triacylglycerols C-55 (51.7%) was predominant followed by C-53 (30.6%) and C-57 (17.7%). Palmitic (16:0) and oleic (18:1) acids were always the major fatty acids in both oils. In seed oil their quantities were nearly the same, whereas in pulp oil oleic acid was predominant. Composition of Lipids of Piqui (Caryocar coriaceum Wittm.)


Fuel ◽  
2006 ◽  
Vol 85 (17-18) ◽  
pp. 2671-2675 ◽  
Author(s):  
V VELJKOVIC ◽  
S LAKICEVIC ◽  
O STAMENKOVIC ◽  
Z TODOROVIC ◽  
M LAZIC

Author(s):  
Eman H. Ahmed ◽  
Azhari H. Nour ◽  
Omer A. Omer Ishag ◽  
Abdurahman H. Nour

The need of energy never comes to an end so; the challenge is to procure power source sufficient to offer for our energy needs. Besides, this energy source must be dependable, renewable, recurring and non-contributing to climate change. Aims: This study was aimed to produce biodiesel from Roselle seed oil and to investigate its quality.  Methodology: The Roselle seeds were clean from dirt, milled to proper size and the oil was extracted using soxhlet with n-hexane as solvent. The extracted oil was subjected to physiochemical analysis tests and then transesterified using methanol and potassium hydroxide as catalyst; with ratio of oil to alcohol 1:8 at 65°C. The quality of produced biodiesel was investigated and compared to international standards. The fatty acid composition of the produced biodiesel was determined by GC-MS. Results: Based on the experimental results, the yellow with characteristic odor oil was obtained from the seeds had the following physicochemical properties: yield, 12.65%; refractive index (25°C), 1.467 m ; free fatty acids, 5.5%; saponification value, 252 mg KOH/g of oil; density, 0.915 g/mL and ester value, 241 mgKOH/g. Also the biodiesel yield achieved was 96%, with density, 0.80 g/mL; API, 44.63; Kinematics viscosity @ 40˚C, 0.742; Pour point, < -51˚C; and Micro Carbon Residual (MCR), 0.65%; which conformed to the range of ASTM D6751 and EN 14214 standard specifications. However, the GC-MS analysis result revealed that the biodiesel produced was methyl ester and free other undesired products such as linoleic acid (33%), elaidic acid (29%) and palmitic acid (17%) and other biomolecules. Conclusion: Based on the obtained results, Roselle seed oil had potential for biodiesel production due to its high contains of free fatty acids. Therefore, in the future, more investigations in alcohol: oil ratio and the concentration of catalyst may be warranted to increase the yield much more.


2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Rosana Chirinos ◽  
Daniela Zorrilla ◽  
Ana Aguilar-Galvez ◽  
Romina Pedreschi ◽  
David Campos

The effect of roasting ofPlukenetia huayllabambanaseeds on the fatty acids, tocopherols, phytosterols, and phenolic compounds was evaluated. Additionally, the oxidative stability of the seed during roasting was evaluated through free fatty acids, peroxide, andp-anisidine values in the seed oil. Roasting conditions corresponded to 100, 120, 140, and 160°C for 10, 20, and 30 min, respectively. Results indicate that roasting temperatures higher than 120°C significantly affect the content of the studied components. The values of acidity, peroxide, andp-anisidine in the sacha inchi oil from roasted seeds increased during roasting. The treatment of 100°C for 10 min successfully maintained the evaluated bioactive compounds in the seed and quality of the oil, while guaranteeing a higher extraction yield. Our results indicate thatP. huayllabambanaseed should be roasted at temperatures not higher than 100°C for 10 min to obtain snacks with high levels of bioactive compounds and with high oxidative stability.


2020 ◽  
Vol 71 (3) ◽  
pp. 367
Author(s):  
A. Al-Farga ◽  
M. Baeshen ◽  
F. M. Aqlan ◽  
A. Siddeeg ◽  
M. Afifi ◽  
...  

This study investigated the effects of blending alhydwan seed oil and peanut oil as a way of enhancing the stability and chemical characteristics of plant seed oils and to discover more innovative foods of high nutraceutical value which can be used in other food production systems. Alhydwan seed oil and peanut oil blended at proportions of 10:90, 20:80, 30:70, 40:60 and 50:50 (v/v) were evaluated according to their physi­cochemical properties, including refractive index, relative density, saponification value, peroxide value, iodine value, free fatty acids, oxidative stability index, and tocopherol contents using various standard and published methods. At room temperature, all of the oil blends were in the liquid state. The physicochemical profiles of the blended oils showed significant decreases (p < 0.05) in peroxide value (6.97–6.02 meq O2/kg oil), refractive index at 25 °C (1.462–1.446), free fatty acids (2.29–1.71%), and saponification value (186.44–183.77 mg KOH/g), and increases in iodine value and relative density at 25 °C (98.10–102.89 and 0.89–0.91, respectively), especially with an analhydwan seed oil to peanut oil ratio of 10:90. Among the fatty acids, oleic and linoleic acids were most abundant in the 50:50 and 10:90 alhydwan seed oil to peanut oil blends, respectively. Oxidative stability increased as the proportion of alhydwan oil increased. In terms of tocopherol contents (γ, δ, and α), γ-tocopherol had the highest values across all of the blended proportions, followed by δ-tocopherol. The overall acceptability was good for all blends. The incorporation of alhydwan seed oil into peanut oil resulted in inexpensive, high-quality blended oil that may be useful in health food products and pharmaceuticals without compromising sensory characteristics.


1956 ◽  
Vol 34 (4) ◽  
pp. 459-464 ◽  
Author(s):  
Mary J. Chisholm ◽  
C. Y. Hopkins

The fatty oil of delphinium seed (Delphinium hybridum (Hort.)) was examined. Fresh seed gave an oil composed mainly of glycerides but having 2.8% of free fatty acids. The oil from older seed contained about 50% of free fatty acids, apparently as a result of lipase action in the seed. The total fatty acids were found to include cis-11-eicosenoic acid (18%) and eicosadienoic acid (1%), the latter identified as tetrahydroxyeicosanoic acid. Other acids that were identified and the estimated percentages were: 9-hexadecenoic <1, palmitic 4, linoleic 16, oleic 53, and stearic 1. Spectroscopic analysis indicated a content of 2.5% of octadecatrienoic acid. Eicosoic acids have not been observed previously in the seed oils of this plant family (Ranunculaceae).


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