scholarly journals Zn-Co-CeO2 vs. Zn-Co Coatings: Effect of CeO2 Sol in the Enhancement of the Corrosion Performance of Electrodeposited Composite Coatings

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 704
Author(s):  
Marija Riđošić ◽  
Nebojša D. Nikolić ◽  
Asier Salicio-Paz ◽  
Eva García-Lecina ◽  
Ljiljana S. Živković ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Healing Rate ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Self Healing ◽  
Kelvin Probe ◽  
Artificial Defect ◽  
Volta Potential ◽  
Superior Corrosion Resistance ◽  
The Stability

Electrodeposition and characterization of novel ceria-doped Zn-Co composite coatings was the main goal of this research. Electrodeposited composite coatings were compared to pure Zn-Co coatings obtained under the same conditions. The effect of two ceria sources, powder and home-made sol, on the morphology and corrosion resistance of the composite coatings was determined. During the electrodeposition process the plating solution was successfully agitated in an ultrasound bath. The source of the particles was found to influence the stability and dispersity of plating solutions. The application of ceria sol resulted in an increase of the ceria content in the resulting coating and favored the refinement from cauliflower-like morphology (Zn-Co) to uniform and compact coral-like structure (Zn-Co-CeO2 sol). The corrosion resistance of the composite coatings was enhanced compared to bare Zn-Co as evidenced by electrochemical impedance spectroscopy and scanning Kelvin probe results. Zn-Co doped with ceria particles originating from ceria sol exhibited superior corrosion resistance compared to Zn-Co-CeO2 (powder) coatings. The self-healing rate of artificial defect was calculated based on measured Volta potential difference for which Zn-Co-CeO2 (sol) coatings exhibited a self-healing rate of 73.28% in a chloride-rich environment.

scholarly journals Cellulose microfibers (CMFs) reinforced smart self-healing polymeric composite coatings for corrosion protection of steel

2020 ◽  
Author(s):  
Muddasir Nawaz ◽  
Sehrish Habib ◽  
Adnan Khan ◽  
Abdul Shakoor ◽  
Ramazan Kahraman
Keyword(s):  
Corrosion Resistance ◽  
Immersion Time ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Polymeric Composite ◽  
Protective Film ◽  
Self Healing ◽  
Ph Change ◽  
Smart Coatings ◽  
Cellulose Microfibers

The use of organic coating for the metals has been widely being used to protect the surface against corrosion. Polymeric coating incorporated with Nanocontainers loaded with inhibitor and self-healing provides better corrosion resistance. Cellulose microfibers (CMFs) used as smart carriers were synthesized and loaded with dodecylamine (DOC)-inhibitor and polyethyleneimine (PEI)-both inhibitor and self-healing agents. Smart polymeric coatings were developed by mixing CMF/DOC and CMFs/PEI into the epoxy matrix. Reference coatings (that has only CMFs) were also prepared for a compersion. Scanning electron microscope (SEM), X-ray diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FTIR) and thermal gravitational analysis (TGA) were used to confirm the loading of DOC and PEI onto the CMFs. UV-vis analysis indicates that the self-release of inhibitor from CMFs is sensitive to pH of the solution and the immersion time. Recovery of controlled surface damage confirms the decent self-healing ability of the prepared smart coatings is due to the efficient release of inhibitor (DOC) and self-healing agent (PEI) in the damaged area leading to the formation of a protective film. Electrochemical impedance spectroscopy (EIS) results demonstrate that corrosion resistance of the smart coating increases with an increase in immersion time which is due to the progressive release of inhibitors from CMFs in response to the pH change. Therefore, smart coatings demonstrate superior properties as compared to the reference coatings. The study reveals the polymeric composite coatings have potential to inhibit the corrosion of steel for oil and gas industry.

Improved Corrosion Resistance and Increased Hardness of Copper Substrates from Cu-Ni/Ni-P Composite Coatings

MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2129-2137 ◽  
Author(s):  
Wenwen Dou ◽  
Wen Li ◽  
Yuchen Cai ◽  
Mengyao Dong ◽  
Xiaojing Wang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Copper Substrate ◽  
Electrolytic Deposition ◽  
Deposition Method ◽  
Nacl Solution ◽  
Current Densities ◽  
Superior Corrosion Resistance ◽  
Deposition Conditions

ABSTRACTTo improve the corrosion resistance and to increase the hardness of copper substrate in marine environment, the Cu-Ni/Ni-P composite coatings were prepared on the copper substrate using the galvanostatic electrolytic deposition method. The deposition current densities were explored to find the optimized deposition conditions for forming the composite coatings. Corrosion resistance properties were analyzed using the polarization curves and electrochemical impedance spectroscopy (EIS). Considering the corrosion resistance and hardness, the −20 mA/cm2 was selected to deposit Cu-Ni coatings on copper substrate and the −30 mA/cm2 was selected to deposit Ni-P coating on the Cu-Ni layer. The Cu-Ni/Ni-P composite coatings not only exhibited superior corrosion resistance compared to single Cu-Ni coating in 3.5 wt.% NaCl solution, but also showed much better mechanical properties than single Cu-Ni coating.

scholarly journals High Performance Anti-Corrosion Coatings of Poly (Vinyl Butyral) Composites with Poly N-(vinyl)pyrrole and Carbon Black Nanoparticles

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2307 ◽  
Author(s):  
Lu Hao ◽  
Guowei Lv ◽  
Yaqian Zhou ◽  
Kaiming Zhu ◽  
Mochen Dong ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Carbon Black ◽  
High Performance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Corrosion Property ◽  
Corrosion Properties ◽  
The Matrix ◽  
Superior Corrosion Resistance ◽  
Vinyl Butyral

Zinc is widely used in battery negative electrodes and steel coatings for automotive industries. The anti-corrosion property of zinc is the most important factor determining the performance and lifetime of the products. In this paper, both size-controlled poly N-(vinyl)pyrrole (PNVPY) nanoparticles and carbon black (CB) nanoparticles were compounded with poly (vinyl butyral) (PVB) binder developing a series of composite coatings covered on the zinc substrates using a spin-coating technique. The morphologies of the surface and cross section of the PNVPY/CB/PVB coatings indicate that the PNVPY and CB nanoparticles are uniformly distributed in the matrix. The corrosion resistance of the composite coatings was tested by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization in a 3.5% NaCl solution. It is found that the coating with 1.9 wt.% PNVPY and 2.3 wt.% CB nanoparticles shows a remarkably high resistance value (Rc) and corrosion protection efficiency (99.99%). Meanwhile, the immersion results also reveal its superior corrosion resistance. It is considered that the nanoscale dispersion of PNVPY and carbon in PVB matrix and the strong interface action between the nanoparticles and PVB result in the uniform microstructure of the composites which endues the superior corrosion properties of the coatings.

A review on the corrosion resistance of electroless Ni-P based composite coatings and electrochemical corrosion testing methods

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Imtiaz Ahmed Shozib ◽  
Azlan Ahmad ◽  
Ahmad Majdi Abdul-Rani ◽  
Mohammadali Beheshti ◽  
Abdul’Azeez Abdu Aliyu
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Electrochemical Corrosion ◽  
Kelvin Probe ◽  
Corrosive Media ◽  
Measuring Techniques ◽  
Electroless Ni ◽  
The Impact ◽  
Electrode Technique

Abstract This paper aims to review the impact of different factors influencing the corrosion resistance of electroless Ni-P based coatings. Emphasis has been given onto the impact of phosphorus content, incorporation of alloying elements, addition of particles and heat treatment which have been discussed in detail and critically reviewed. The effect of corrosive media and coating process parameters on corrosion resistance are studied concisely. Furthermore, the role of the incorporation of various elements and particles’ contents on the corrosion resistance of electroless Ni-P coating are studied systematically. This paper also presents an overview of the latest electrochemical corrosion measuring techniques. The following approaches deserve special attention in the analysis: localized electrochemical impedance spectroscopy (LEIS), scanning vibrating electrode technique (SVET), scanning ion-selective electrode technique (SIET), scanning droplet cell (SDC), scanning electrochemical microscopy (SECM), scanning Kelvin probe (SKP) and novel contactless technique (NCT).

Electrodeposition of MgO/Calcium Phosphate Composite Coatings on Titanium for Biomedical Applications

2013 ◽  
Vol 785-786 ◽  
pp. 872-876
Author(s):  
Yong Huang ◽  
Shu Guang Han ◽  
Ya Jing Yan ◽  
Xiao Feng Pang
Keyword(s):  
Corrosion Resistance ◽  
Phase Composition ◽  
Calcium Phosphate ◽  
Biomedical Applications ◽  
Lower Layer ◽  
Composite Coatings ◽  
Polarization Test ◽  
Coated Surface ◽  
Bare Titanium ◽  
Superior Corrosion Resistance

This work elucidated corrosion resistance of the electrodeposited MgO/calcium phosphate (Ca-P/MgO) films on titanium (Ti). The microstructure, phase composition, and corrosion resistance of the films were studied. Results revealed that The Ca-P/MgO composite coatings were rough and inhomogeneous, the upper layer was floral-like crystals or flakes agglomerates morphology, and the lower layer was needle-like crystals which were mutually cross linked. The coating was very dense, and the content of Mg was about 0.3 wt%. Potentiodynamic polarization test manifested that the Ca-P/MgO-coated surface exhibited superior corrosion resistance than the bare titanium.

Role of chromium in anomalous behaviour of the passive layer in Ni-Cr-Mo alloys in 1M HCl solution

CORROSION ◽  
10.5006/3767 ◽  
2022 ◽  
Author(s):  
Malvika Karri ◽  
Amit Verma ◽  
J.B. Singh ◽  
Sunil Kumar Bonagani ◽  
U.K. Goutam
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Underlying Mechanism ◽  
Passive Layer ◽  
X Ray ◽  
Superior Corrosion Resistance ◽  
Hcl Solution ◽  
Cr2o3 Layer

This work seeks to understand the underlying mechanism involved in passivity of Ni-Cr-Mo alloys in a less concentrated HCl solution (1M) by systematically varying contents of Cr and Mo solutes in model Ni-Cr-Mo alloys. Corrosion behaviour was evaluated based on potentiodynamic polarisation tests carried out in conjunction with electrochemical impedance and x-ray photoelectron spectroscopies of passive films that formed on alloys during their exposure to the HCl solution. Results have shown that an increase in Mo alone is not sufficient to improve the corrosion resistance of the alloys at lower concentrations of HCl. Optimum concentrations of Cr and Mo solutes have been found to be in the vicinity of ~17 wt.% Cr and ~19 wt.% Mo for superior corrosion resistance of the alloys. This was attributed to the protection of the Cr2O3 layer as a consequence of the enrichment of Mo6+ ions in the passive film in 1M HCl solution.

MICROSTRUCTURE AND ELECTROCHEMICAL PROPERTIES OF Ni–B/GO ULTRASONIC-ASSISTED COMPOSITE COATINGS

2019 ◽  
Vol 26 (10) ◽  
pp. 1950080
Author(s):  
JIBO JIANG ◽  
HAOTIAN CHEN ◽  
LIYING ZHU ◽  
YAOXIN SUN ◽  
WEI QIAN ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Photoelectron Spectroscopy ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Ultrasonic Field ◽  
Protective Material ◽  
X Ray ◽  
Electrochemical Tests ◽  
Ultrasonic Assisted ◽  
Corrosive Environments

Graphene oxide (GO) sheet and ultrasonic field (UF) were successfully employed to produce Ni–B/GO and UF–Ni–B/GO composite coatings on Q235 mild steel by electroless plating. The composite coatings’ structure and surface morphology were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Results showed that GO was successfully co-deposited in the Ni–B alloy. Moreover, UF–Ni–B/GO composite coatings have smoother surface and thicker cross-section than others. The microhardness and corrosion resistance of the sample coatings were determined using Vickers hardness tests, Tafel electrochemical tests and electrochemical impedance measurements (EIS) in 3.5[Formula: see text]wt.% NaCl solution to receive the effect of GO and ultrasonic. The findings indicated that UF–Ni–B/GO exhibited optimum hardness (856[Formula: see text]HV) and enhanced corrosion resistance (6.38 [Formula: see text][Formula: see text] over the Ni–B and Ni–B/GO coatings. Due to these interesting properties of the coating, it could be used as a protective material in the automotive and aerospace industries for parts of machines that were manipulated in high temperature and corrosive environments.

Electrodeposition and Hardness and Corrosion Resistance Propertie of Ni/Nano-B4C Composite Coatings

2011 ◽  
Vol 399-401 ◽  
pp. 2055-2060
Author(s):  
Ji Bo Jiang ◽  
Wei Dong Liu ◽  
Lei Zhang ◽  
Qing Dong Zhong ◽  
Yi Wang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Corrosion Property ◽  
Pure Nickel ◽  
Plating Bath ◽  
Tafel Polarization ◽  
Nickel Coatings ◽  
Eis Measurements ◽  
Steel Substrates

Ni–B4C composite coatings on carbon steel substrates with various contents of B4C nano-particulates were prepared by electrodeposition in Ni plating bath containing B4C nano-particulates. Microhardness, Scanning Electron Microscopy (SEM), Tafel polarization and Electrochemical Impedance Spectroscopy (EIS) measurements were used to compare pure nickel coatings and Ni–B4C composite coatings. Pure Ni coating microhardness is lower than that of Ni–B4C coatings and the microhardness of the composite coatings increases with the increase of the content of B4C nano-particulates. The effects of various contents of B4C nano-particulates on the corrosion resistance were investigated and it was found that the best anti–corrosion property of Ni–B4C composite coatings is at 6 g/L B4C in the bath formulation.

Corrosion protective properties of coatings doped with inhibitors

2014 ◽  
Vol 61 (6) ◽  
pp. 416-422 ◽  
Author(s):  
Mansoureh Parsa ◽  
Seyed Mohammad Ali Hosseini ◽  
Zahra Hassani ◽  
Effat Jamalizadeh
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Titania Nanoparticles ◽  
Self Healing ◽  
Properties Of Coatings ◽  
Ethylene Imine ◽  
Protective Properties ◽  
Content Type

Purpose – The purpose of this paper was to study the corrosion resistance of water-based sol-gel coatings containing titania nanoparticles doped with organic inhibitors for corrosion protection of AA2024 alloy. Design/methodology/approach – The coatings were obtained using tetraethylorthosilicate, 3-glycidoxypropyltrimethoxysilane, titanium (IV) tetrapropoxide and poly(ethylene imine) polymer as cross-linking agents. As corrosions inhibitors, 2-mercaptobenzoxazole and salicylaldoxime were incorporated into the sol-gel for the improvement of the corrosion resistance. The corrosion protection performance of coatings was studied using the potentiodynamic scan and the electrochemical impedance spectroscopy (EIS) methods. Atomic force microscopy was used to investigate surface morphology of the coatings. Findings – The results indicated that doping the sol-gel coatings with inhibitors leads to improvement of the corrosion protection. The comparison of doped coatings confirmed that corrosion protection performance of the sol-gel coatings doped with 2-mercaptobenzoxazole was better than for the sol-gel coatings doped with salicylaldoxime. Also the EIS results verified self-healing effects for the sol-gel coatings doped with 2-mercaptobenzoxazole. Originality/value – This paper indicates 2-mercaptobenzoxazole and salicylaldoxime can be added as corrosion inhibitors to sol-gel coatings to improve their corrosion protective properties for AA2024 alloy.

HIGH CORROSION RESISTANCE OF NI-P/NANO-SIO2 ELECTROLESS COMPOSITE COATINGS

2012 ◽  
Vol 05 ◽  
pp. 810-816 ◽  
Author(s):  
S.R. Allahkaram ◽  
T. Rabizadeh
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Carbon Steels ◽  
Nano Particles ◽  
Chemical Compositions ◽  
High Corrosion Resistance ◽  
Coating Type ◽  
Corrosion Behaviors ◽  
Electroless Ni

The process of electroless plating Ni - P and Ni - P /nano- SiO 2 on API-5L X65 carbon steels was improved. The Ni - P /nano- SiO 2 composite coatings were prepared from the bathes containing different concentrations of nano- SiO 2 particles. The coatings surface and morphologies were observed via scanning electron microscopy (SEM). The chemical compositions were analyzed by EDAX. The corrosion behaviors were evaluated by electrochemical impedance spectroscopy tests. The experimental results indicated that SiO 2 nano-particles co-deposited but some agglomeration occurred. Micro-hardness of electroless Ni - P - SiO 2 composite coatings increased due to the existence of nano-particles. Corrosion tests showed that both electroless Ni - P and Ni - P /nano- SiO 2 composite coatings demonstrated significant improvement of corrosion resistance of substrate in salty atmosphere and latter coating type appeared to offer a better corrosion protection.

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