scholarly journals Properties of Calcium Sulfoaluminate Cement Mortar Modified by Hydroxyethyl Methyl Celluloses with Different Degrees of Substitution

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2136
Author(s):  
Shaokang Zhang ◽  
Ru Wang ◽  
Linglin Xu ◽  
Andreas Hecker ◽  
Horst-Michael Ludwig ◽  
...  

This paper studies the influence of hydroxyethyl methyl cellulose (HEMC) on the properties of calcium sulfoaluminate (CSA) cement mortar. In order to explore the applicability of different HEMCs in CSA cement mortars, HEMCs with higher and lower molar substitution (MS)/degree of substitution (DS) and polyacrylamide (PAAm) modification were used. At the same time, two kinds of CSA cements with different contents of ye’elimite were selected. Properties of cement mortar in fresh and hardened states were investigated, including the fluidity, consistency and water-retention rate of fresh mortar and the compressive strength, flexural strength, tensile bond strength and dry shrinkage rate of hardened mortar. The porosity and pore size distribution were also analyzed by mercury intrusion porosimetry (MIP). Results show that HEMCs improve the fresh state properties and tensile bond strength of both types of CSA cement mortars. However, the compressive strength of CSA cement mortars is greatly decreased by the addition of HEMCs, and the flexural strength is decreased slightly. The MIP measurement shows that HEMCs increase the amount of micron-level pores and the porosity. The HEMCs with different MS/DS have different effects on the improvement of tensile bond strength in different CSA cement mortars. PAAm modification can improve the tensile bond strength of HEMC-modified CSA cement mortar.

Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 113 ◽  
Author(s):  
Hongfang Sun ◽  
Li Ling ◽  
Zhili Ren ◽  
Shazim Ali Memon ◽  
Feng Xing

This paper evaluated the effect of graphene oxide/graphene (GO/GR) hybrid on mechanical properties of cement mortar. The underlying mechanism was also investigated. In the GO/GR hybrid, GO was expected to act as a dispersant for GR while GR was used as reinforcement in mortar due to its excellent mechanical properties. For the mortar specimen, flexural and compressive strength were measured at varied GO to GR ratios of 1:0, 3:1, 1:1, 1:3, and 0:1 by keeping the total amount of GO and GR constant. The underlying mechanism was investigated through the dispersibility of GR, heat releasing characteristics during hydration, and porosity of mortar. The results showed that GO/GR hybrid significantly enhanced the flexural and compressive strength of cement mortars. The flexural strength reached maximum at GO:GR = 1:1, where the enhancement level was up to 23.04% (28 days) when compared to mortar prepared with only GO, and up to 15.63% (7 days) when compared to mortar prepared with only GR. In terms of compressive strength, the enhancement level for GO:GR = 3:1 was up to 21.10% (3 days) when compared with that of mortar incorporating GO only. The enhancement in compressive strength with mortar at GO:GR = 1:1 was up to 14.69% (7-day) when compared with mortar incorporating GR only. In addition to dispersibility, the compressive strength was also influenced by other factors, such as the degree of hydration, porosity, and pore size distribution of mortar, which made the mortars perform best at different ages.


2013 ◽  
Vol 539 ◽  
pp. 244-248
Author(s):  
De Zhi Wang ◽  
Yin Yan Zhang ◽  
Yun Fang Meng

Water requirement of normal consistency, setting time and soundness of cement pastes mixed with SiO2 and CaCO3 nanoparticle and the flexural strength and compressive strength of cement mortars mixed with SiO2 and CaCO3 nanoparticles were experimentally studied. Results indicated that the added nano-SiO2 and nano-CaCO3 with a mass account of 4.0 wt. % decreased the setting time and increased the water requirement of normal consistency, flexural strength and compressive strength. And these nanoscaled mineral admixtures did not have a negative impact on cement soundness. The optimal replacement levels of cement by SiO2 and CaCO3 nanoparticles for producing cement mortar with improved strength were 2.0 and 4.0 wt.% respectively.


2010 ◽  
Vol 168-170 ◽  
pp. 1886-1890 ◽  
Author(s):  
Zheng Mao Ye ◽  
Wen Chen ◽  
Xin Cheng

The impermeability and other performance of sulphoaluminate cement were studied, which mixed with redispersible polymer powders. With the help of SEM and mercury intrusion apparatus, the morphology of the hydrates and the pore structure of the cement mortars were observed. The impermeability mechanism of redispersible polymer powders in sulphoaluminate cement mortar was analyzed. The results show that sulphoaluminate cement mortar could be modified by adding redispersible polymer powders. The flexural strength of sulphoaluminate cement mortar could be increased by adding redispersible polymer powders, and compressive strength of sulphoaluminate cement mortar could also be increased to a certain extent. When the mass fraction of redispersible polymer powders was 0.9%, the flexural strength and compressive strength reached 9.2 MPa and 52.5 MPa. When small amount of redispersible polymer powders was added, the impermeability of modified sulphoaluminate cement mortar was improved significantly. When the mass fraction of redispersible polymer powders exceeded 0.9%, impermeability of Sulphoaluminate cement mortar would not be improved significantly. Due to redispersible powders gap filling and film forming, the interface of cement and aggregate is more closed, total porosity decreased and unharmful porosity increased when redispersible polymer powders is added.


2010 ◽  
Vol 168-170 ◽  
pp. 190-194 ◽  
Author(s):  
Zhen Jun Wang ◽  
Rui Wang ◽  
Yu Bin Cheng

In this paper, styrene-butadiene polymer emulsion SD622S was adopted to modify cement mortar; mechanical properties of cement mortars were studied and microstructures was analyzed by means of Scanning Electron Microscope (SEM) and Specific Surface Area & Pore Distribution Analyzer. The results show that in contrast to ordinary cement mortar, if water to cement ratio (W/C) is constant, compressive strength of modified cement mortar can decrease, while flexural strength and toughness, ratio of compressive strength to flexural strength, increase with the increase of polymer to cement ratio in mass (P/C) at 7 and 28 curing days. With the increase of P/C, net structure made from polymer and cement hydration products is developed and pore whose size is smaller than 200Å begins to increase, which indicates pore diameters in modified cement mortar change to be finer. So microstructures of modified cement mortar become denser and display higher toughness.


2014 ◽  
Vol 1033-1034 ◽  
pp. 1189-1193
Author(s):  
Lin Yang ◽  
Ya Ming Liu ◽  
Jian Zuo ◽  
Bin Zhang ◽  
Jian Xin Cao

Cement, phosphorus slag, silica sand, fly ash and water reducing agent were well-mixed, and then stirred with polypropylene fiber and water for preparation of phosphorus slag mortar. Performance of the mortar was tested according to relevant standards. The results showed that polypropylene fiber can improve flexural strength and tensile bond strength of the mortar. However the polypropylene fiber has little contribution to the compressive strength of the mortar. Fluidity of phosphorus slag mortar reduces with length of the fiber increasing. Polypropylene fibers distributed evenly in the phosphorus slag mortar can obstruct generation and propagation of micro cracks, thus crack-control property of mortar can be improved. When polypropylene fiber’s length and content are 10 mm and 4 g (by weight) respectively, the properties of phosphorus slag mortar are as follow: fluidity 209 mm, tensile bond strength 0.71 MPa, flexural strength 4.32 MPa, Compressive strength 10.83 MPa, and ratio of compressive strength to flexural strength 2.51 on 28 days.


2011 ◽  
Vol 306-307 ◽  
pp. 758-761
Author(s):  
Shui Zhang ◽  
Guo Zhong Li ◽  
Hai Yan Yuan

This work aims to evaluate the effect of Kevlar fibers with chemical treatment on the flexural strength, compressive strength and impact resistance of cement mortar. The experimental results exhibit that Kevlar fiber with a larger percentage can increase the flexural strength and improve the impact resistance of cement mortar, and the reinforcement effect of Kevlar fiber with chemical treatment is more obvious. The surface morphology of Kevlar fiber and the fracture surface of cement mortar reinforced with Kevlar fiber were observed by SEM, and the reinforcement mechanism of the Kevlar fiber on cement mortar was discussed.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


2021 ◽  
Vol 13 (8) ◽  
pp. 4546
Author(s):  
Kaiyue Zhao ◽  
Peng Zhang ◽  
Bing Wang ◽  
Yupeng Tian ◽  
Shanbin Xue ◽  
...  

Cement-based materials prepared with activated water induced by a magnetic field or electric field represent a possible solution to environmental issues caused by the worldwide utilization of chemical admixtures. In this contribution, electric- and magnetic-activated water have been produced. The workability and mechanical properties of cement mortar prepared with this activated water have been investigated. The results indicate that the pH and absorbance (Abs) values of the water varied as the electric and magnetic field changed, and their values increased significantly, exhibiting improved activity compared with that of the untreated water. In addition, activated water still retains activity within 30 min of the resting time. The fluidity of the cement paste prepared with electric-activated water was significantly larger than that of the untreated paste. However, the level of improvement differed with the worst performance resulting from cement paste prepared with alternating voltage activated water. In terms of mechanical properties, both compressive strength and flexural strength obtained its maximum values at 280 mT with two processing cycles. The compressive strength increased 26% as the curing time increased from 7 days to 28 days and flexural strength increased by 31%. In addition, through the introduction of magnetic-activated water into cement mortar, the mechanical strength can be maintained without losing its workability when the amount of cement is reduced.


2013 ◽  
Vol 795 ◽  
pp. 684-691 ◽  
Author(s):  
Wail N. Al-Rifaie ◽  
Omar Mohanad Mahdi ◽  
Waleed Khalil Ahmed

The present research examined the compressive and flexural strength of nanocement mortar by using micro cement, micro sand, nanosilica and nanoclay in developing a nanocement mortar which can lead to improvements in ferrocement construction. The measured results demonstrate the increase in compressive and flexural strength of mortars at early stages of hardening. In addition, the influence of heating on compressive strength of cement mortar. General expressions to predict the compressive strength, modulus of rupture for the developed nanocement mortar in the present work are proposed.


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