scholarly journals Bio-Based Alternatives to Phenol and Formaldehyde for the Production of Resins

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.

2017 ◽  
Vol 13 (1) ◽  
pp. 69-79 ◽  
Author(s):  
Tibor L. Alpár ◽  
Gábor Markó

AbstractMedium density fiberboards are widely produced and used in Europe. The main raw materials used in Hungary are beech (Fagus sylvatica), hornbeam (Carpinus betulus), poplar (Populus spp.) and pine (Pinus spp.). Governmental subsidizing of biomass for power plants has created economic pressure and a shortage of wood prompting a major producer of energy grass to initialize a project to examine the possibility for the production of MDF from energy grass “Szarvasi-1” (Elymus elongatus (Agropyron elongatum) cv. Szarvasi-1). Prior to this, no research results on the experimental production of MDF from energy grass had been published. In our research study, energy grass was defibrated and MDF boards were produced with the use of different adhesives. Standard tests were completed to evaluate the suitability of this alternate raw material in MDF production. The best result was achieved with phenol formaldehyde (PF) adhesive.


Cerâmica ◽  
2013 ◽  
Vol 59 (351) ◽  
pp. 473-480 ◽  
Author(s):  
K. C. P. Faria ◽  
J. N. F. Holanda

The sugarcane industry generates huge amounts of sugarcane bagasse ashes (SCBA). This work investigates the incorporation of a SCBA waste as an alternative raw material into a clay body, replacing natural clay material by up to 20 wt.%. Clay ceramic pieces were produced by uniaxial pressing and fired at temperatures varying from 700 to 1100 ºC. The technological properties of the clay ceramic pieces (linear shrinkage, apparent density, water absorption, and tensile strength) as function of the firing temperature and waste addition are investigated. The phase evolution during firing was followed by X-ray diffraction. The results showed that the SCBA waste could be incorporated into red ceramics (bricks and roofing tiles) in partial replacement for natural clay material. These results confirm the feasibility of valorisation of SCBA waste to produce red ceramic. This use of SCBA can also contribute greatly to reducing the environmental problems of the sugarcane industry, and also save the sources of natural raw materials used in the ceramic industry.


2020 ◽  
Vol 14 (2) ◽  
Author(s):  
N. Pritulska ◽  
I. Motuzka ◽  
A. Koshelnyk ◽  
M. Jarossová ◽  
A. Lacková

A recent tendency in Ukraine is the changes in the structure of food consumption, which are caused by the reduced consumption of some product groups and by their decreasing quality. A persisting problem is that affordable and easy-to-consume food products made with due consideration of the needs of patients with certain categories of diseases can hardly be found on the domestic market. The products present on the domestic market are all imported, available in a limited assortment, very expensive, and not customised to suit all the specific needs of human metabolism. Approaches to the nutrition of patients with certain types of nutrition-dependent and non-infectious diseases have been analysed. It has been established that аn effective component in the diet of patients with non-infectious diseases can be plant-based milk analogues. It has been determined how important it is to use domestic raw materials: it will contribute to expanding domestic production, will help the gross domestic product growth, and will reduce the product’s costs, thus reducing the costs of diagnostic and treatment procedures. It has been established that the assortment of plant-based milk analogues is constantly expanding. The vegetable raw material conventionally used to make this product group has been analysed. It has been shown that fenugreek seeds can be most effectively used to make special food products (in particular, plant-based milk analogues) for the nutritional support of patients with non-infectious diseases. This is feasible due to the availability of the raw material, simple cultivating conditions, the chemical composition of the product (e. g. a wide range of biologically active substances), low costs of the product when it is made from domestic raw materials, and the simple production technology. It is expected that manufacture of milk analogues from fenugreek seeds will widen the assortment of this product group, and satisfy the target consumers’ needs of safe and high quality products that offer an alternative to imports.


Author(s):  
В. В. Поздняков ◽  
Ю. В. Харченко ◽  
Л. Я. Харченко ◽  
О. В. Анцыферова

Гибриды сахарной и сверхсахарной кукурузы являются хорошим сырьем для производства функциональных пищевых продуктов, в том числе диетического и детского питания. Важными показателями высокого качества этих продуктов являются повышенное содержание белка и ценного масла, незначительное количество плохо усвояемого кукурузного крахмала и высокое содержание антиоксидантов, а также отменные вкусовые качества. В работе представлены данные по оценке антиоксидантной активности большой группы новых перспективных гибридов сверхсахарной кукурузы среднеспелой группы, созданных с целью получения ценных источников сырья для консервной промышленности. Значения показателя общей антиоксидантной активности варьировали в широком интервале значений (от 31,8 % до 60,4 %, 568,4–1008 мкг/г семян), что указывает на перспективность использования этого важного биохимического параметра в селекции сверхсахарной кукурузы на качество. Hybrids of excess sugar maize are good raw material for the production of functional food products, including baby food and diet. Important indicators of high quality of these products are high protein content and a valuable oil, a small amount of poorly digestible maize starch and a high content of antioxidants, and also excellent taste qualities. The paper presents data on the evaluation of the antioxidant activity of a large group of promising new hybrids of excess sugar maize of mid-group created in order to obtain valuable raw materials for the canning industry. Index value of total antioxidant activity varied over a wide range (from 31,8 % to 60,4 %, 568,4–1,008 mg/g of seed), which indicates on promising use of this important parameter in the breeding of biochemical excess sugar maize on quality.


Author(s):  
Patrick Degryse ◽  
Dennis Braekmans

Petrography has developed into an indispensable tool for ceramic fabric analysis, specifically studying the mineralogical and textural composition of ceramic objects. Petrography is a technique commonly used in geology to describe and classify rocks. Ceramic petrography studies clay-based archaeological or historical materials. Using a polarizing light microscope (PLM) in ceramic studies, the different raw materials used to make a ceramic object can be identified, ranging from clays and other minerals to rock fragments and inorganic or organic temper. The technique moreover feeds into the study of raw material provenance and origin, and is able to discern the different technological procedures followed to make the ceramic object (from shaping to firing), next to providing clues on the function of the object. This information not only helps reconstruct trade and exchange of raw materials and ceramics, but aids in reconstructing society behind the pot.


2020 ◽  
Vol 992 ◽  
pp. 253-258
Author(s):  
M.P. Lebedev ◽  
V.N. Tagrov ◽  
E.S. Lukin

The article deals with the manufacture of modern structural ceramic materials from clay and loam deposits of the Republic of Sakha (Yakutia). The importance and relevance of the development of the production of building materials from local raw materials is emphasized, since this will certainly affect the effectiveness of the construction complex as a whole. The successful development of the construction complex is capable of not only stimulating growth in all sectors of the economy, but also contributes to solving the most pressing social problems. Today, Yakutia has huge reserves of mineral raw materials for the production of a wide range of building materials and products. Of practical interest are wall materials made from clay soils. Given the features of the region’s raw material base, this work focuses on additional processing of traditional material. Controlling the complex physicochemical and structural-mechanical transformations that occur during heat treatment, a methodology has been developed for creating a composite material that will allow competitive innovative materials with enhanced strength properties to be produced with a reinforcing element with a glassy phase matrix of mullite crystals. The fabricated samples have a wide range of physical and mechanical properties and allow using it as a high-quality structural building ceramics, as well as industrial floor technical tile.


2018 ◽  
Vol 22 (3) ◽  
pp. 318-341 ◽  
Author(s):  
Michael J Lynch ◽  
Paul B Stretesky ◽  
Michael A Long

During the development of green criminology, little attention has been paid to how Indigenous/Native Peoples (INP) are victimized by green crime and how they employ environmental activism to resist externally imposed ecological destruction. In the past decade, news services and environmental interest groups have reported on the killing of INP environmental activists who have resisted ecological destruction across the world. Here, we begin to develop a green criminological view of INP victimization and resistance to ecological destruction within the context of the global capitalist treadmill of production, while drawing upon concepts of colonization, imperialism, genocide and ecocide. Our analysis suggests that in the contemporary capitalist world system, expansion of the treadmill of production’s ecological withdrawal process (i.e. the withdrawal of raw materials used in production) not only accelerates ecological disorganization in developing/underdeveloped nations, but may be harmful in nations where INP are dependent on access to nature for survival.


Membranes ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 105 ◽  
Author(s):  
Amanmyrat Abdullayev ◽  
Maged Bekheet ◽  
Dorian Hanaor ◽  
Aleksander Gurlo

In water treatment applications, the use of ceramic membranes is associated with numerous advantages relative to polymer-based filtration systems. High-temperature stability, fouling resistance, and low maintenance requirements contribute to lower lifecycle costs in such systems. However, the high production costs of most commercially available ceramic membranes, stemming from raw materials and processing, are uneconomical for such systems in most water treatment applications. For this reason, there is a growing demand for new ceramic membranes based on low-cost raw materials and processes. The use of unrefined mineral feedstocks, clays, cement, sands, and ash as the basis for the fabrication of ceramic membranes offers a promising pathway towards the obtainment of effective filtration systems that can be economically implemented in large volumes. The design of effective ceramic filtration membranes based on low-cost raw materials and energy-efficient processes requires a balance of pore structure, mass flow, and robustness, all of which are highly dependent on the composition of materials used, the inclusion of various pore-forming and binding additives, and the thermal treatments to which membranes are subjected. In this review, we present recent developments in materials and processes for the fabrication of low-cost membranes from unrefined raw materials, including clays, zeolites, apatite, waste products, including fly ash and rice husk ash, and cement. We examine multiple aspects of materials design and address the challenges relating to their further development.


2020 ◽  
Vol 1 (3) ◽  
pp. 256-274
Author(s):  
H. N. Cheng ◽  
Zhongqi He ◽  
Catrina Ford ◽  
Wade Wyckoff ◽  
Qinglin Wu

There has been increasing interest in recent years in the use of agro-based raw materials for the production of bio-friendly and sustainable products. Plant-based proteins are among the popular materials being studied. In particular, cottonseed protein (a byproduct of cotton fiber production) is widely available and has useful properties. Although not as well-known as soy protein, cottonseed protein has been shown to be a potentially valuable raw material for numerous applications. In this review, the latest developments in isolation, composition and molecular weight, chemical and enzymatic modifications, and non-food applications are delineated. Among these applications, films and coatings, interfacial and emulsifying applications, adhesives, and bioplastics seem to attract the most attention. A particular effort has been made to cover the literature on these topics in the past 10 years.


Author(s):  
Magdalena Śmiglak-Krajewska

The main purpose of this paper was to identify the factors affecting the selection of raw materials used by feed operators in feed production. An attempt was also made to indicate the barriers to increasing the use of native protein plants by feed operators in feed production. Today, many EU countries (including Poland) primarily rely on vegetable protein derived from genetically modified soya bean meal (mainly imported from South America and the U.S.) in addressing their needs for protein raw material used in animal feed. For many years now, Poland has taken steps to increase the production and use of native protein raw material to partially replace soya bean meal imports. The use of mixes of diverse domestic protein sources derived from grain legumes (peas, field beans, lupine) can provide an advantageous alternative to compound feeding stuff based on imported post-extraction soya bean meal. To meet the objective defined above, this paper relied on the results of a 2018 survey conducted with a sample of 29 feed operators located across the country. More than half (55%) of the enterprises surveyed did not use legumes in feed production; the use of legumes was above 10% in only 3% of respondents. When asked about the key factors affecting the selection of raw materials used in production processes, the respondents declared to be interested in buying large batches of homogeneous raw materials that meet specific quality parameters (33% replied “rather yes” and 67% replied “definitely yes”). The protein content of plant seeds used in feed production was identified as another aspect of extreme importance (55% replied “rather yes” and 24% replied “definitely yes”).


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