scholarly journals The Ubiquitous Imprint of Radiative Acceleration in the Mean Absorption Spectrum of Quasar Outflows

2019 ◽  
Vol 886 (2) ◽  
pp. 151 ◽  
Author(s):  
Lluís Mas-Ribas ◽  
Renate Mauland

When two solutions are mixed the absorption spectrum of the new solution will be the mean of those of the separate solutions provided that no chemical interaction occures. The mere fact of a departure from additivity does not, however, necessarily denote the formation of true chemical compounds. The solute or solutes may undergo solvation, loosely bound aggregates may occur, and even when marked deviations from the simple law of mixtures are observed it is rarely possible to prove the quantitative formation of a given chemical compound from spectroscopic data alone. The above considerations apply with some force to the problem of the absorption spectra of halogens and inter-halogen compounds in an inert solvent. The three elements show perfectly characteristic absorption bands, they are known to interact with the formation of some quite stable compounds, some relatively stable compounds, and some apparently very unstable compounds.


Clay Minerals ◽  
1984 ◽  
Vol 19 (1) ◽  
pp. 107-111 ◽  
Author(s):  
A. Julg ◽  
O. Julg

The spectrum of Ni-substituted lizardite, (Mg,Ni)3Si2O5(OH)4, has been discussed by many authors, who have successively given contradictory interpretations concerning the symmetry of the Ni-sites. Lakshman & Reddy (1973) affirmed that in garnierites Ni is in a tetrahedral site. Faye (1974) rejected this conclusion and showed that Ni2+ occupies an octahedral site. However, the Ni … O distance of 2·01 Å which he deduced from the intensity of the crystal field is unacceptable. Recently, using a completely different approach to the interpretation of the spectrum, Cervelle & Maquet (1982) claimed that Ni2+ occupies a six-coordinated site of C3v symmetry, and concluded that the mean Ni … O distance is 2·06 Å.The aim of this note is to show that it is possible to interpret the spectrum of Ni-lizardite as arising from a predominantly octahedral field with a weak C2v component which provokes a small increase in width of the absorption bands.


In 1874 it was shown by Roscoe and Schuster that channelled absorption spectra can be obtained with the vapours of the alkali elements sodium and potassium, and later on these spectra were investigated in some detail by Liveing and Dewar. It was also shown in 1896 by Weidemann and Schmidt that the vapours of these same metals emitted a radiation possessing characteristics of a fluorescence spectrum when they were traversed by white light. Since 1903 exhaustive studies have been made of both the fluorescence and the channelled absorption spectrum of sodium by R. W. Wood, together with a number of collaborators, Including J. H. Moore and F. E. Hackett. In these investigation it was shown that the channelled absorption spectrum of sodium was made up of a number of series of absorption bands, one set of series being on the red wave-length side of the D lines, and another lying in the visible blue-green region. In addition, series of absorption bands were found by them with approximately regular spacing in the neighbourhood of λ = 3303 A, the second member of the doublet series of this element. As regards the fluorescence spectrum of sodium, they found that, by stimulation of the vapour with approximately monochromatic light, there resulted an emission of light, the spectrum of which consisted of a number of bright but narrow bands of varying intensity, more or less regularly spaced both above and below the mean wave-length of the exciting light. They observed, too, that the slightest change in the wave-length of the exciting light resulted in the disappearance of one set of lines and in the appearance of another of different wave-lengths. In the various florescence spectra obtained by R. W. Wood when stimulating sodium vapour by monochromatic light from different sources, it was noted that there was a remarkable recurrence of the interval, ∆ λ = 52·3 A. in the spacing of the fluorescence bands.


1994 ◽  
Vol 348 ◽  
Author(s):  
S. Cangopadhyay ◽  
N. Barashkov ◽  
L. Liu ◽  
C. Palsule ◽  
W. Borst ◽  
...  

ABSTRACTWe have produced fast wavelength shifters using mixtures of various Coumarin dyes with DCM in epoxy-polymers (DGEBA+HHPA) and measured the properties of these wavelength shifters. The particular mixtures were chosen because there is a substantial overlap between the emission spectrum of Coumarin and the absorption spectrum of DCM. The continuous wave and time-resolved fluorescence spectra have been studied as a function of component concentration to optimize the decay times, emission peaks and quantum yields. The mean decay times of these mixtures are in the range of 2.5-4.5 ns. The mean decay time increases with an increase in Coumarin concentration at a fixed DCM concentration or with a decrease in DCM concentration at a fixed Coumarin concentration. This indicates that the energy transfer is radiative at lower relative DCM concentrations and becomes non-radiative at higher DCM concentrations.


1960 ◽  
Vol 13 (2) ◽  
pp. 222 ◽  
Author(s):  
GJ Sutton

A study has been made of the bis(2-picolylamine) copper(II) complex in association with various anions. Of the salts investigated, the chloride bromide, and nitrate are blue, the iodide is green, and the perchlorate and tetraiodomercurate are purple. Blue solutions are obtained in water, and the molecular absorption spectra are identical and are characteristic of bispicolylamine copper(II) ion. However, conductance measurements in methanol and nitromethane show that there is some metal halogen bonding for the iodide, and this is also indicated by a slight shift in the absorption spectrum to longer wavelengths in the same solvents. The mean magnetic moment of the copper atom in the complexes was found to be 1.93 B.M.


1962 ◽  
Vol 40 (2) ◽  
pp. 163-178 ◽  
Author(s):  
J. D. Poll ◽  
J. Van Kranendonk

The effect of the lattice vibrations on the infrared absorption spectrum of solid hydrogen is investigated theoretically. General expressions are derived for the integrated intensities of the phonon branches in the rotational and vibrational spectrum of solid parahydrogen. It is shown that the intensities of the pure rotational and vibrational absorption features are not appreciably affected by the lattice vibrations. A general criterion is derived for the vanishing of the contribution of instantaneous phonon processes to the integrated intensities of the phonon branches. The integrated intensities are expressed in terms of the mean square displacements of the molecules from their equilibrium positions. Explicit calculations are presented, based on the Einstein and Debye models for the lattice vibrations, and the results are compared with the available experimental data.


2017 ◽  
Vol 846 (1) ◽  
pp. 4 ◽  
Author(s):  
Lluís Mas-Ribas ◽  
Jordi Miralda-Escudé ◽  
Ignasi Pérez-Ràfols ◽  
Andreu Arinyo-i-Prats ◽  
Pasquier Noterdaeme ◽  
...  

1966 ◽  
Vol 24 ◽  
pp. 170-180
Author(s):  
D. L. Crawford

Early in the 1950's Strömgren (1, 2, 3, 4, 5) introduced medium to narrow-band interference filter photometry at the McDonald Observatory. He used six interference filters to obtain two parameters of astrophysical interest. These parameters he calledlandc, for line and continuum hydrogen absorption. The first measured empirically the absorption line strength of Hβby means of a filter of half width 35Å centered on Hβand compared to the mean of two filters situated in the continuum near Hβ. The second index measured empirically the Balmer discontinuity by means of a filter situated below the Balmer discontinuity and two above it. He showed that these two indices could accurately predict the spectral type and luminosity of both B stars and A and F stars. He later derived (6) an indexmfrom the same filters. This index was a measure of the relative line blanketing near 4100Å compared to two filters above 4500Å. These three indices confirmed earlier work by many people, including Lindblad and Becker. References to this earlier work and to the systems discussed today can be found in Strömgren's article inBasic Astronomical Data(7).


1966 ◽  
Vol 25 ◽  
pp. 46-48 ◽  
Author(s):  
M. Lecar

“Dynamical mixing”, i.e. relaxation of a stellar phase space distribution through interaction with the mean gravitational field, is numerically investigated for a one-dimensional self-gravitating stellar gas. Qualitative results are presented in the form of a motion picture of the flow of phase points (representing homogeneous slabs of stars) in two-dimensional phase space.


1966 ◽  
Vol 25 ◽  
pp. 373
Author(s):  
Y. Kozai

The motion of an artificial satellite around the Moon is much more complicated than that around the Earth, since the shape of the Moon is a triaxial ellipsoid and the effect of the Earth on the motion is very important even for a very close satellite.The differential equations of motion of the satellite are written in canonical form of three degrees of freedom with time depending Hamiltonian. By eliminating short-periodic terms depending on the mean longitude of the satellite and by assuming that the Earth is moving on the lunar equator, however, the equations are reduced to those of two degrees of freedom with an energy integral.Since the mean motion of the Earth around the Moon is more rapid than the secular motion of the argument of pericentre of the satellite by a factor of one order, the terms depending on the longitude of the Earth can be eliminated, and the degree of freedom is reduced to one.Then the motion can be discussed by drawing equi-energy curves in two-dimensional space. According to these figures satellites with high inclination have large possibilities of falling down to the lunar surface even if the initial eccentricities are very small.The principal properties of the motion are not changed even if plausible values ofJ3andJ4of the Moon are included.This paper has been published in Publ. astr. Soc.Japan15, 301, 1963.


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