Concentrated Landfill Leachate Treatment by Electro-Ozonation

Author(s):  
Amin Mojiri ◽  
Lou Ziyang ◽  
Wang Hui ◽  
Ali Gholami

Municipal solid waste has continued to be a major problem in many nations of the world. The primary methods of treating landfill leachate include physical-chemical and biological treatment processes. Pressure-driven membrane processes, such as microfiltration, ultrafiltration, nanofiltration, and reverse osmosis (RO), are among the utmost promising and capable ways for treating landfill leachate. The concentrated leachate created from pressure-driven membrane processes typically represents 13%–30% of total incoming landfill leachate. Concentrated leachate is a dark brown solution with high levels of pollutants. Treating concentrated leachate is extremely difficult, and thus, a combined treatment system is suggested. In the present study, concentrated landfill leachate was treated using a combined treatment technique that included electro-ozonation. The removal efficacies of chemical oxygen demand (COD), color, and nickel were monitored at original pH (7.3) as well as current and voltage of 4 A and 9 V, respectively.

1995 ◽  
Vol 32 (3) ◽  
pp. 119-128 ◽  
Author(s):  
Craig D. Martin ◽  
Keith D. Johnson

Recently in the USA, the Solid Waste Industry has undergone specific changes in landfill regulations. The Federal Resource Conservation and Recovery Acts (RCRA); and EPA subtitle D regulations, as well as stringent State regulations, impose minimum criteria for municipal solid waste facilities in the areas of location, operation, groundwater monitoring, and leachate management. In conjunction with these State and Federal mandates the University of West Florida developed a leachate treatment technique utilizing extended aeration and surface-flow constructed wetlands. Sampling of water quality has occurred monthly since February 1992. Parameters examined include: Nitrogen (NH3,), Total Suspended Solids (TSS), Total Phosphate (TPO4), Total Organic Carbon (TOC), pH, Alkalinity, and Chlorides. Chemical Oxygen Demand (COD), Total and Fecal Coliforms, Priority Pollutant Metals, and limited organic analytes are sampled on a less frequent basis. Samples are collected at a raw leachate site (L0), primary aerated lagoon (L1), and 6 stations within the 1.1 hectare constructed wetland complex (S1; W1; W3; W5; W7; W9) and one sandfilter (SF) location. Results thus far indicate removal percentages of the tested analytes average between 64% and 99%. This data suggests various physical, microbiological and chemical processes occurring within the aerated lagoon and constructed wetlands can provide an effective alternative to standard techniques for landfill leachate treatment and disposal. The methods as described have proven to be ideal for the circumstances occurring at the Perdido Landfill.


2016 ◽  
Vol 18 (2) ◽  
pp. 360-370

<div> <p>The main objective of this study was to investigate the differences between the main pollutants in young and intermediate age landfill leachate in terms of molecular weight distribution (MWD). Parameters of chemical oxygen demand (COD), five day - biochemical oxygen demand (BOD<sub>5</sub>), ultraviolet-visible spectrophotometry (UV-VIS spectrum), total kjehldahl nitrogen (TKN), ammonia nitrogen (NH<sub>4</sub>-N) and colour were fractioned by membranes with the nominal pore size of 1&micro;m, 0.05 &micro;m, 100 kDa, 50 kDa, 10 kDa, 1 kDa and 0.5 kDa. According to the MWD results appropriate treatment technology could be choosen easily. According to the MWD results the ratio of soluble fractions (&lt; 0.5 kDa) to total COD was 34% in young leachate (YL), whereas low molecular weight (MW) fractions were dominant in intermediate leachate (IL) having this ratio of 71%. Presence of lower MW compounds in IL was also confirmed with UV-VIS absorbance spectra and its spectrum was higher than the YL. According to the specific ultraviolet absorption (SUVA) values, the organic contents of all of these processes were hydrophilic. TKN and NH<sub>4</sub>-N analysis showed that in IL all the nitrogen present is in ammoniacal form, instead in YL there is still the presence of organic nitrogen. Furthermore more than half of the TKN was less than 0.5 kDa while 6 % and 16 % TKN found in wastewater from IL and YL was higher than 1 &micro;m respectively. The observations of this study may provide useful criteria to choose a suitable landfill leachate treatment processes.</p> </div> <p>&nbsp;</p>


2020 ◽  
Vol 10 (28) ◽  
Author(s):  
Hamri Zineb ◽  
Mouhir Latifa ◽  
Souabi Salah ◽  
Saafadi Laila

Background. Landfill leachate is a source of environmental pollution and a major concern for human health because it contains high concentrations of organic and inorganic contaminants. Objectives. The objective of the present study is to validate the efficiency of the forced aeration treatment technique, which consists of intensively injecting a continuous oxygen flow of 16.75 kg/m3/h for 30 days using a bubble air diffuser in a relatively small volume of 1 m3. The principle of the technique is essentially based on acceleration of the degradation of the effluent as well as reduction of the organic and nitrogenous matter contents. Methods. Forced aeration technology was used for the treatment of leachate from the Mohammedia-Benslimane landfill. The sample was treated by injecting a flow of oxygen to accelerate the biodegradability of the pollutants by the microorganisms. Results. The physicochemical characterization of the raw leachate at the inlet of the aeration tank showed high values for chemical oxygen demand (COD) (38,600 mg O2/l), biological oxygen demand (BOD5) (24,000 mg O2/l), and total Kjeldahl nitrogen (TKN) (5,932.45 mg/L). The proposed treatment technique allowed relatively high purification yields to be achieved, with abatement rates for the major elements COD, BOD5 and TKN of 73%, 98%, and 85%, respectively. Conclusions. The treatment of leachate by intensive aeration technology reduces considerably the pollutant load and achieves a high purification yield. Competing Interests. The authors declare no competing financial interests.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 946
Author(s):  
Chunlian Wang ◽  
Xiaojie Sun ◽  
Huijun Shan ◽  
Hongxia Zhang ◽  
Beidou Xi

This study explored the performance of TiO2 nanoparticles in combination with aged waste reactors to treat landfill leachate. The optimum conditions for synthesis of TiO2 were determined by a series of characterizations and removal rates of methyl orange. The effect of the ultraviolet irradiation time, amount of the catalyst, and pH on the removal efficiency for the chemical oxygen demand (COD) and color in the leachate was explored to determine the optimal process conditions, which were 500 min, 4 g/L and 8.88, respectively. The removal rates for COD and chroma under three optimal conditions were obtained by the single factor control method: 89% and 70%; 95.56% and 70%; and 85% and 87.5%, respectively. Under optimal process conditions, the overall average removal rates for ammonium nitrogen (NH4+–N) and COD in the leachate for the combination of TiO2 nanoparticles and an aged waste reactor were 98.8% and 32.5%, respectively, and the nitrate (NO3−–N) and nitrite nitrogen (NO2–N) concentrations were maintained at 7–9 and 0.01–0.017 mg/L, respectively. TiO2 nanoparticles before and after the photocatalytic reaction were characterized by emission scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, and Fourier transform infrared spectrometry. In addition, TiO2 nanoparticles have excellent recyclability, showing the potential of the photocatalytic/biological combined treatment of landfill leachate. This simulation of photocatalysis-landfilling could be a baseline study for the implementation of technology at the pilot scale.


2018 ◽  
Vol 47 (2) ◽  
pp. 297-305 ◽  
Author(s):  
Mehdi Zolfaghari ◽  
Oumar Dia ◽  
Nouha Klai ◽  
Patrick Drogui ◽  
Satinder Kaur Brar ◽  
...  

Author(s):  
Siti Nor Farhana Zakaria

Landfill leachate is a hazardous pollutant generated from a landfill site. Discharge of landfill leachate has caused a major contamination to the environment and detrimental to human health. This chapter introduces an alternative method to treat recalcitrant pollutant in leachate by using ozonation with catalyst. The production of hydroxyl radical in ozonation was not enough to oxidize complex molecular structure in the leachate. Theoretically, the addition of catalyst enhances the capacity of radical and accelerates the chemical reaction. The effectiveness of ozonation with Fenton (O3/Fenton), hydrogen peroxide (O3/H2O2), and zirconium tetrachloride (O3/ZrCl4) in removing pollutant such as chemical oxygen demand (COD), color, and improvement of biodegradability by using this process were also discussed in this chapter. Comparison in term of treatment cost and benefits of the application of chemical as catalyst are briefly elaborated at the end of this chapter.


2020 ◽  
pp. 204-220
Author(s):  
Zawawi Daud ◽  
Halizah Awang

In this chapter, the performance of combined treatment of municipal landfill leachate is reviewed. Although individual physico-chemical treatments are suitable for the removal of heavy metals and hydrolyzation of some organic compounds, a combination of two physico-chemical treatments or physico-chemical and biological is required for optimum treatment of stabilized landfill leachate. A combination of two physico-chemical treatments can give optimum results in removal of recalcitrant organic compounds from stabilized leachate, as reflected by a significant decrease of the COD values after treatment. On the other hand, a combination of physico-chemical and biological treatments is required to achieve effective removal of NH3-N and COD with a substantial amount of biodegradable organic matter. In many cases, physico-chemical treatments are suitable for pre-treatment of stabilized leachate. The objective of this paper is to highlight various types of integrated leachate treatments as it has been difficult to get optimum efficiency from single approached treatment.


Author(s):  
Amin Mojiri ◽  
Siti Fatihah Binti Ramli ◽  
Wan Izatul Saadiah Binti Wan Kamar

Leachate is created while water penetrates through the waste in a landfill, carrying some forms of pollutants. The goal of this chapter is the introduction to leachate treatment. Biological, physical, and chemical treatments of leachate are the most common methods. The biological techniques in leachate treatment are studied. The physical-chemical ways for landfill leachate treatment like chemical precipitation, chemical oxidation, coagulation–flocculation, membrane filtration, ion exchange, adsorption and electrochemical treatment are studied. The landfill leachate properties, technical applicability and constraints, effluent discharge alternatives, cost-effectiveness, regulatory requirements and environmental impact are important factors for selection of the most suitable treatment technique for landfill leachate treatment.


2019 ◽  
Vol 80 (3) ◽  
pp. 458-465 ◽  
Author(s):  
Ahmed Samir Naje ◽  
Mohammed A. Ajeel ◽  
Isam Mohamad Ali ◽  
Hussein A. M. Al-Zubaidi ◽  
Peter Adeniyi Alaba

Abstract In this work, landfill leachate treatment by electrocoagulation process with a novel rotating anode reactor was studied. The influence of rotating anode speed on the removal efficiency of chemical oxygen demand (COD), total dissolved solids (TDS), and total suspended solids (TSS) of raw landfill leachate was investigated. The influence of operating parameters like leachate pH, leachate temperature, current, and inter-distance between the cathode rings and anode impellers on the electrocoagulation performance were also investigated. The results revealed the optimum rotating speed is 150 rpm and increasing the rotating speed above this value led to reducing process performance. The leachate electrocoagulation treatment process favors the neutral medium and the treatment performance increases with increasing current intensity. Furthermore, the electrocoagulation treatment performance improves with increasing leachate temperature. However, the performance reduces with increasing inter-electrode distance.


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