The Relation between Drift, Entropy Distribution and Kirkendall Plane Position during Diffusion
Keyword(s):
The Kirkendall effect appears due to the unbalanced diffusion fluxes causing the vacancy flux. There are several numerical methods that allow to predict the position of Kirkendall plane after the diffusion couple annealing. In this work for the first time the entropy density distribution is used to estimate the trajectory of the Kirkendall plane. The entropy density distribution is calculated with use of the bi-velocity method, which combines: (1) the volume continuity, (2) the conservation of mass, (3) momentum and (4) entropy-density. The method is applied to simulate the diffusion in Ni-Pd diffusion couple.