Influence of External Factors on Amorphous and Nanocrystalline Soft Magnetic Alloys Studied by Mössbauer Spectroscopy

2006 ◽  
Vol 518 ◽  
pp. 195-202 ◽  
Author(s):  
Jarmila Degmová ◽  
J. Sitek ◽  
J. Bednarčík

In this paper, a review of recent 57Fe Mössbauer spectroscopy (MS) studies of external influence on the properties of amorphous and nanocrystalline Fe- and Co-based alloys is submitted. Different types of alloys (FeCuNbZr, FeCuNbSiB, FeCoCuNbB, CoFeZrB and CoFeSiB) in the form of original amorphous and nanocrystalline ribbons were subjected to different external factors: different annealing atmospheres, mechanical stress (for example influence of ball-milling) and tensile stress. It will be shown that the Mössbauer spectrometry is a suitable tool for such studies because the measured spectral parameters are very sensitive to the changes in the vicinity of the probe 57Fe-nuclei and thus, this technique provides a wide variety of information about structural and magnetic behavior of Fe-containing materials.

2011 ◽  
Vol 66 (7) ◽  
pp. 664-670
Author(s):  
◽  
Christian Schwickert ◽  
Thorsten Langer ◽  
Rainer Pöttgen

The ternary stannides RE3Ru4Sn13 (RE = La, Ce, Pr, Nd) were obtained by arc-melting of the elements. The polycrystalline samples were characterized by powder X-ray diffraction. The structures of three compounds were refined from single-crystal diffractometer data: Yb3Rh4Sn13 type, Pm3̄n, a = 977.74(3) pm, wR2 = 0.0379, 280 F2 values for La3Ru4Sn13, a = 971.34(9) pm, wR2 = 0.0333, 274 F2 values for Ce3Ru4Sn13, a = 970.68(8) pm, wR2 = 0.0262, 272 F2 values for Nd3Ru4Sn13 with 13 variables per refinement. The structures consist of three-dimensional networks of condensed RuSn6/2 trigonal prisms with the RE (CN 16) and Sn2 (CN 12) atoms in two different types of cavities of the networks. The two crystallographically independent tin sites have been resolved by 119Sn Mössbauer spectroscopy. Temperature-dependent magnetic susceptibility measurements of Ce3Ru4Sn13 gave a reduced magnetic moment of 2.32 μB per Ce atom, indicating intermediate cerium valence. No magnetic ordering was evident down to 3 K.


2020 ◽  
Vol 22 (46) ◽  
pp. 26876-26886
Author(s):  
Ravi Kumar Yadav ◽  
R. Govindaraj

Changes in the local structure and magnetic properties at Fe sites associated with different types of defects were addressed in a detailed manner in Co2FeAl by 57Fe Mössbauer spectroscopy.


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