Toughening of Polypropylene-Ethylene Copolymer with Nanosized CaCO3 and Styrene-Butadiene-Styrene

2007 ◽  
Vol 121-123 ◽  
pp. 1451-1454
Author(s):  
Jian Feng Chen ◽  
Guo Quan Wang ◽  
Xiao Fei Zeng ◽  
Hong Ying Zhao
Keyword(s):  
Average Particle Size ◽  
Average Particle ◽  
Single Screw Extruder ◽  
Roll Mill ◽  
The Matrix ◽  
Ethylene Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
The Impact ◽  
Butadiene Styrene

Nanocomposites of nanosized-CaCO3/polypropylene-ethylene copolymer (PPE) and nanosized CaCO3/ PPE/ styrene-butadiene-styrene (SBS) were prepared by using two-roll mill and single screw extruder. The average particle size of nanosized CaCO3 was determined to be about 30 nm. By adding nanosized CaCO3 into PPE matrix, the toughness of the matrix improves significantly. At nanosized CaCO3 content of 12 phr (parts per hundred PPE resin by weight), the impact strength of CaCO3/PPE at room temperature reaches 61.6 KJ/m2, which is 3.02 times that of unfilled PPE matrix. In addition, the synergistic toughening effect of nanosized CaCO3 and SBS particles on PPE matrix was investigated.

Toughening of polypropylene-ethylene copolymer with nanosized CaCO3 and styrene-butadiene-styrene

2004 ◽  
Vol 94 (2) ◽  
pp. 796-802 ◽  
Author(s):  
Jianfeng Chen ◽  
Guoquan Wang ◽  
Xiaofei Zeng ◽  
Hongying Zhao ◽  
Dapeng Cao ◽  
...  
Keyword(s):  
Ethylene Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

scholarly journals EVALUATION OF SELECTED TECHNICAL PROPERTIES OF BITUMEN BINDERS MODIFIED WITH SBS COPOLYMER AND CRUMB RUBBER

2020 ◽  
Vol 12 (1) ◽  
pp. 12-19
Author(s):  
RAMAN PAKHOLAK ◽  
ANDRZEJ PLEWA ◽  
RAMAN HATALSKI
Keyword(s):  
Strain Energy ◽  
Crumb Rubber ◽  
Test Results ◽  
Styrene Butadiene Styrene ◽  
Technical Properties ◽  
Styrene Butadiene ◽  
Penetration Tests ◽  
The Impact ◽  
Bitumen Modification ◽  
Butadiene Styrene

Good quality bitumen used in the production of bitumen-aggregate mixtures is a binder with high stiffness and elasticity at high operating temperatures occurring in summer and adequate flexibility during exposure to sub-zero temperatures. Currently, one of the best technological solutions to improve the viscoelasticity of bitumen and the resistance to ageing is their modification with various types of additives. The paper presents the results of penetration tests as a function of temperature, softening point (ring and ball method) and strain energy at various temperatures of road bitumen modified with SBS (styrene-butadiene-styrene) copolymer, crumb rubber and simultaneous bitumen modification with SBS copolymer and crumb rubber. The obtained results allowed to assess temperature sensitivity, resistance to changes in selected technical properties of the tested binders as a result of technological ageing process with RTFOT (Roler Thin Film Oven Tester) method and to evaluate changes in their technical properties in relation to the 50/70 base bitumen. Multivariate analysis of variance (MANOVA) was used to analyse the impact of the modification type on the test results of technical properties (significance of the impact of the considered factors on the level of technical properties).

scholarly journals Marshall Performance and Volumetric Properties of Styrene-Butadiene-Styrene Modified Asphalt Mixtures

2021 ◽  
Vol 7 (6) ◽  
pp. 1050-1059
Author(s):  
Sameer Abbas Jasim ◽  
Mohammed Qadir Ismael
Keyword(s):  
Asphalt Binder ◽  
Asphalt Mixtures ◽  
Traffic Load ◽  
Asphalt Content ◽  
Styrene Butadiene Styrene ◽  
And Performance ◽  
The Stability ◽  
Styrene Butadiene ◽  
The Impact ◽  
Butadiene Styrene

The durability of asphalt pavement is associated with the properties and performance of the binder. This work-study intended to understand the impact of blending Styrene-Butadiene-Styrene (SBS) to conventional asphalt concrete mixtures and calculating the Optimum Asphalt Content (OAC) for conventional mixture also; compare the performance between SBS modified with the conventional mixture. Two different kinds of asphalt penetration grades, A.C. (40-50) and A.C. (60-70), were improved with 2.5 and 3.5% SBS polymer, respectively. Marshall properties were determined in this work. Optimum Asphalt Content (OAC) was 4.93 and 5.1% by weight of mixture for A.C. (40-50) and (60-70), respectively. Marshall properties results show an increasement in the stability value by 8.65 and 20.19% for A.C. (40-50) with 2.5 and 3.5% of SBS, respectively. And an increasement by 9.32 and 20.61% for AC (60-70) with 2.5 and 3.5% of SBS respectively. Furthermore, the results indicate a decrease in Marshall flow by 14.7 and 26.47% for A.C. (40-50) with 2.5 and 3.5% SBS respectively and a decrease by 10.46 and 21.21% for A.C. (60-70) with 2.5 and 3.5% SBS respectively. Other Marshall properties were also calculated. Moreover, Blending SBS polymers to conventional asphalt mixtures produces a better performance to asphalt binder and better Marshall properties, which provides a great solution to Iraqi road problems affected by temperature and high traffic load, including less maintenance. Doi: 10.28991/cej-2021-03091709 Full Text: PDF

Influence of temperature and humidity on the angle of repose of wood bulk materials

2016 ◽  
Author(s):  
И.В. Бачериков ◽  
Б.М. Локштанов
Keyword(s):  
Field Experiments ◽  
Bulk Material ◽  
Average Particle Size ◽  
Operating Conditions ◽  
Angle Of Repose ◽  
Wood Dust ◽  
Average Particle ◽  
Bulk Materials ◽  
Technical Literature ◽  
The Impact

При проектировании открытых и закрытых хранилищ измельченных сыпучих материалов древесных материалов, таких как щепа и опилки, большое значение имеет угол естественного откоса (статический и динамический) этих материалов. В технической литературе приводятся противоречивые сведения о величине этих углов, что приводит к ошибкам при проектировании складов. В справочных данных не учитываются условия, в которых эксплуатируются емкости для хранения сыпучих материалов, свойства и состояние этих сыпучих материалов. В свою очередь, ошибки при проектировании приводят к проблемам (зависание, сводообразование, «затопление» и т. д.) и авариям при эксплуатации бункеров и силосов на производстве. В статье представлены сведения, посвященные влиянию влажности и температуры на угол естественного откоса сыпучих материалов. На основании лабораторных и натурных экспериментов, проведенных с помощью специально разработанных методик и установок, была скорректирована формула для определения углов естественного откоса (статического и динамического) для измельченных древесных материалов в зависимости от их фракционного и породного состава, влажности (абсолютной и относительной) и температуры. При помощи скорректированной формулы можно определить угол естественного откоса древесных сыпучих материалов со среднегеометрическим размером частицы от 0,5 мм до 15 мм (от древесной пыли до технологической щепы) в различных производственных условиях. Статья может быть полезна проектировщикам при расчете угла наклона граней выпускающей воронки бункеров и силосов предприятий лесной отрасли и целлюлозо-бумажной промышленности. In the design of open and closed storage warehouses chopped wood materials for bulk materials such as wood chips and sawdust, great importance has an angle of repose (static and dynamic) of these materials. In the technical literature are conflicting reports about the magnitude of these angles, which leads to errors in the design of warehouses. In the referencesdoes not take into account the conditions under which operated capacities for storage of bulk materials, and properties and condition of the bulk material. The design errors lead to problems (hanging, arching, «flooding», etc.) and accidents in the operation of hoppers and silos at the mills. The article provides information on the impact of humidity and temperature on the angle of repose of granular materials. On the basis of laboratory and field experiments, conducted with the help of specially developed techniques and facilities has been adjusted formula for determining the angle of repose (static and dynamic) for the shredded wood materials depending on their fractional and species composition, humidity (absolute and relative) and temperature. It is possible, by using the corrected formula, to determine the angle of repose of loose wood materials with average particle size of from 0.5 mm to 15 mm (wood dust to pulpchips) in various operating conditions. The article can be helpful to designers in the calculation of the angle of inclination of the funnel faces produces bunkers and silos forest industries and pulp and paper industry.

TUNING PROPERTIES AND MORPHOLOGY IN HIGH VINYL CONTENT SBS BLOCK COPOLYMER, A THERMOPLASTIC ELASTOMER VIA THIOL-ENE MODIFICATION

2017 ◽  
Vol 90 (3) ◽  
pp. 550-561 ◽  
Author(s):  
Prithwiraj Mandal ◽  
Siva Ponnupandian ◽  
Soumyadip Choudhury ◽  
Nikhil K. Singha
Keyword(s):  
Block Copolymer ◽  
Thermoplastic Elastomer ◽  
Atomic Force Microscopy Analysis ◽  
Ene Reaction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Microscopy Analysis ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

ABSTRACT Thiol-ene modification of high vinyl content thermoplastic elastomeric styrene butadiene styrene (SBS) block copolymer (BCP) was carried out using different thiolating agents in toluene at 70 °C. 1H NMR analysis confirmed the participation of vinyl double bond in the thiol-ene modification reaction of SBS. Surface morphology of the block copolymers evaluated by atomic force microscopy analysis showed higher roughness after the thiol-ene reaction. The thiol-modified SBS block copolymer showed better adhesion strength and oil resistance properties than the pristine SBS.

scholarly journals Evaluation of Properties and Micro-Characteristics of Waste Polyurethane/Styrene-Butadiene-Styrene Composite Modified Asphalt

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng
Keyword(s):  
Low Temperature ◽  
Performance Test ◽  
Permanent Deformation ◽  
Modified Asphalt ◽  
Basic Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
And Storage ◽  
Butadiene Styrene

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.

Thermo‐responsive shape memory properties based on polylactic acid and styrene‐butadiene‐styrene block copolymer

2021 ◽  
pp. 51000
Author(s):  
Fathin Hani Azizul Rahim ◽  
Abdul Aziz Saleh ◽  
Raa Khimi Shuib ◽  
Ku Marsilla Ku Ishak ◽  
Zuratul Ain Abdul Hamid ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Shape Memory ◽  
Polylactic Acid ◽  
Shape Memory Properties ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene
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