Effect of morphology on adsorption kinetics of magnesium oxide for the removal of methyl orange

2017 ◽  
Vol 98 ◽  
pp. 325-335
Author(s):  
Yong Liu ◽  
Ming Huang ◽  
Yaohui You ◽  
Donghai Zhu ◽  
Xiaojing Fu ◽  
...  
2021 ◽  
Vol 10 (2) ◽  
pp. 16-25
Author(s):  
Thang Bui Van ◽  
Dep Huynh Thi Thanh ◽  
Mai Tran Thi Xuan ◽  
Thao Nguyen Minh

The MnO2-modified diatomite was obtained by wet chemical methods. The specific structure of the material has been determined by modern physicochemical methods. The results showed that the surface of diatomite was coated by the manganese oxide nanoparticles. The prepared MnO2-diatomite material is a good adsorbent for the removal methyl orange (MO) in water. The adsorption kinetics of MO on modulation materials are consistent with the pseudo-second-order kinetics model. Therefore, MnO2-modified diatomite materials could be promising sorbents for removing MO.


2012 ◽  
Vol 581-582 ◽  
pp. 273-276 ◽  
Author(s):  
Yu Hong Chen ◽  
Si Qian Hu

Ethylenediamine-modified chitosan magnetic nano-adsorbent (EMCN) was prepared and used for the sorption of methyl orange(MO). The kinetics of the sorption fitted well with the pseudo-second-order kinetics model. The activation energy of sorption (Ea) was determined to be 16.47 kJ.mol-1. Adsorption isotherms showed that the sorption process was consistent with both Langmuir and Freundlich isotherm, and the thermodynamic parameters were calculated and indicated that the sorption process was spontaneous and exothermic. The saturated sorption capacity is 247.66, 227.58, 214.19 mg.g-1 at 5°C, 25°C, 45°C(pH=5.6),respectively.


2019 ◽  
Author(s):  
Chem Int

The kinetics of oxidation of methyl orange by vanadium(V) {V(V)} has been investigated in the pH range 2.3-3.79. In this pH range V(V) exists both in the form of decavanadates and VO2+. The kinetic results are distinctly different from the results obtained for the same reaction in highly acidic solution (pH < 1) where V(V) exists only in the form of VO2+. The reaction obeys first order kinetics with respect to methyl orange but the rate has very little dependence on total vanadium concentration. The reaction is accelerated by H+ ion but the dependence of rate on [H+] is less than that corresponding to first order dependence. The equilibrium between decavanadates and VO2+ explains the different kinetic pattern observed in this pH range. The reaction is markedly accelerated by Triton X-100 micelles. The rate-[surfactant] profile shows a limiting behavior indicative of a unimolecular pathway in the micellar pseudophase.


1998 ◽  
Vol 31 (26) ◽  
pp. 9281-9294 ◽  
Author(s):  
H. D. Bijsterbosch ◽  
M. A. Cohen Stuart ◽  
G. J. Fleer

Author(s):  
Zahia Benredjem ◽  
Karima Barbari ◽  
Imene Chaabna ◽  
Samia Saaidia ◽  
Abdelhak Djemel ◽  
...  

Abstract The Advanced Oxidation Processes (AOPs) are promising environmentally friendly technologies for the treatment of wastewater containing organic pollutants in general and particularly dyes. The aim of this work is to determine which of the AOP processes based on the Fenton reaction is more effective in degrading the methyl orange (MO) dye. The comparative study of the Fenton, photo-Fenton (PF) and electro-Fenton (EF) processes has shown that electro-Fenton is the most efficient method for oxidizing Methyl Orange. The evolution of organic matter degradation was followed by absorbance (discoloration) and COD (mineralization) measurements. The kinetics of the MO degradation by the electro-Fenton process is very rapid and the OM degradation rate reached 90.87% after 5 min. The influence of some parameters such as the concentration of the catalyst (Fe (II)), the concentration of MO, the current density, the nature and the concentration of supporting electrolyte was investigated. The results showed that the degradation rate increases with the increase in the applied current density and the concentration of the supporting electrolyte. The study of the concentration effect on the rate degradation revealed optimal values for the concentrations 2.10−5 M and 75 mg L−1 of Fe (II) and MO respectively.


Langmuir ◽  
1997 ◽  
Vol 13 (12) ◽  
pp. 3191-3197 ◽  
Author(s):  
Ruey-Yug Tsay ◽  
Shi-Yow Lin ◽  
Lung-Wei Lin ◽  
Shou-I Chen

Sign in / Sign up

Export Citation Format

Share Document