scholarly journals Ozone formation under low solar radiation in eastern China

2019 ◽  
Author(s):  
Xuexi Tie ◽  
Xin Long ◽  
Guohui Li ◽  
Shuyu Zhao ◽  
Jianming Xu
Keyword(s):  
Solar Radiation ◽  
Eastern China ◽  
Threshold Level ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Oh Radicals ◽  
Chemical Production ◽  
The Past ◽  
Photochemical Production ◽  
Steady State Model

Abstract. PM2.5, a particulate matter with a diameter of 2.5 micrometers or less, is one of the major components of the air pollution in eastern China. In the past few years, China's government made strong efforts to reduce the PM2.5 pollutions. However, another important pollutant (ozone) becomes an important problem in eastern China. Ozone (O3) is produced by photochemistry, which requires solar radiation for the formation of O3. Under heavy PM2.5 pollution, the solar radiation is often depressed, and the photochemical production of O3 is prohibited. This study shows that during fall in eastern China, under heavy PM2.5 pollutions, there were often strong O3 photochemical productions, causing a co-occurrence of high PM2.5 and O3 concentrations. This co-occurrence of high PM2.5 and O3 is un-usual and is the main focus of this study. Recent measurements show that there were often high HONO surface concentrations in major Chinese mega cities, especially during daytime, with maximum concentrations ranging from 0.5 to 2 ppbv. It is also interesting to note that the high HONO concentrations were occurred during high aerosol concentration periods, suggesting that there were additional HONO surface sources in eastern China. Under the high daytime HONO concentrations, HONO can be photo-dissociated to be OH radicals, which enhance the photochemical production of O3. In order to study the above scientific issues, a radiative transfer model (TUV; Tropospheric Ultraviolet-Visible) is used in this study, and a chemical steady state model is established to calculate OH radical concentrations. The calculations show that by including the OH production of the photo-dissociated of HONO, the calculated OH concentrations are significantly higher than the values without including this production. For example, by including HONO production, the maximum of OH concentration under the high aerosol condition (AOD = 2.5) is similar to the value under low aerosol condition (AOD = 0.25) in the no-HONO case. This result suggests that even under the high aerosol condition, the chemical oxidizing process for O3 production can occurred, which explain the co-occurrence of high PM2.5 and high O3 in fall season in eastern China. However, the O3 concentrations were not significantly affected by the appearance of HONO in winter. This study shows that the seasonal variation of solar radiation plays important roles for controlling the OH production in winter. When the solar radiation is in a very low level in winter, it reaches the threshold level to prevent the OH chemical production, even by including the HONO production of OH. This study provides some important scientific highlights to better understand the O3 pollutions in eastern China.

scholarly journals Ozone enhancement due to the photodissociation of nitrous acid in eastern China

2019 ◽  
Vol 19 (17) ◽  
pp. 11267-11278 ◽  
Author(s):  
Xuexi Tie ◽  
Xin Long ◽  
Guohui Li ◽  
Shuyu Zhao ◽  
Junji Cao ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Eastern China ◽  
Late Spring ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Oh Radicals ◽  
Production Term ◽  
Photochemical Production ◽  
Steady State Model ◽  
Early Fall

Abstract. PM2.5, particulate matter with a diameter of 2.5 µm or less, is one of the major components of air pollution in eastern China. In the past few years, China's government has made strong efforts to reduce PM2.5 pollution. However, another important pollutant (ozone) is becoming a problem in eastern China. Ozone (O3) is produced by photochemistry, which requires solar radiation for the formation of O3. Under heavy PM2.5 pollution, solar radiation is often depressed, and the photochemical production of O3 is prohibited. This study shows that during late spring and early fall in eastern China, under heavy PM2.5 pollution, there was often strong O3 photochemical production, causing a co-occurrence of high PM2.5 and O3 concentrations. This co-occurrence of high PM2.5 and O3 is unusual and is the main focus of this study. Recent measurements show that there were often high HONO surface concentrations in major Chinese megacities, especially during daytime, with maximum concentrations ranging from 0.5 to 2 ppbv. It is also interesting to note that high HONO concentrations occurred during high aerosol concentration periods, suggesting that there were additional HONO surface sources in eastern China. Under high daytime HONO concentrations, HONO can be photodissociated to OH radicals, which enhance the photochemical production of O3. In order to study the above scientific issues, a radiative transfer model (TUV; tropospheric ultraviolet–visible) is used in this study, and a chemical steady-state model is established to calculate OH radical concentrations. The calculations show that by including the OH production of photodissociated HONO, the calculated OH concentrations are significantly higher than the values without including this production. For example, by including HONO production, the maximum OH concentration under high aerosol conditions (AOD = 2.5) is similar to the value under low aerosol conditions (AOD = 0.25) in the no-HONO case. This result suggests that even under high aerosol conditions, the chemical oxidizing process for O3 production can occur, which explains the co-occurrence of high PM2.5 and high O3 in late spring and early fall in eastern China. However, the O3 concentrations were not significantly affected by the appearance of HONO in winter. This study shows that the seasonal variation of solar radiation plays important roles for controlling the OH production in winter. Because solar radiation is at a very low level in winter, adding the photolysis of HONO has a smaller effect in winter than in other seasons, and OH remains at low values by including the HONO production term. This study provides some important scientific insight to better understand O3 pollution in eastern China.

scholarly journals On the Computation of Apparent Direct Solar Radiation

2019 ◽  
Vol 76 (9) ◽  
pp. 2761-2780 ◽  
Author(s):  
Petri Räisänen ◽  
Anders V. Lindfors
Keyword(s):  
Monte Carlo ◽  
Solar Radiation ◽  
Optical Depth ◽  
Scattered Radiation ◽  
Fine Tuning ◽  
Direct Solar Radiation ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Scaling Factors ◽  
Ice Clouds

Abstract Near-forward-scattered radiation coming from the vicinity of the sun’s direction impacts the interpretation of measurements of direct solar radiation by pyrheliometers and sun photometers, and it is also relevant for concentrating solar technology applications. Here, a Monte Carlo radiative transfer model is employed to study the apparent direct solar transmittance t(α), that is, the transmittance measured by an instrument that receives the radiation within a half-field-of-view (half-FOV) angle α from the center of the solar disk, for various ice cloud, water cloud, and aerosol cases. The contribution of scattered radiation to t(α) increases with increasing particle size, and it also depends strongly on ice crystal morphology. The Monte Carlo calculations are compared with a simple approach, in which t(α) is estimated through Beer’s law, using a scaled optical depth that excludes the part of the phase function corresponding to scattering angles smaller than α. Overall, this optical depth scaling approach works very well, although with some degradation of the performance for ice clouds for very small half-FOV angles (α < 0.5°–1°), and in optically thick cases. The errors can be reduced by fine-tuning the optical depth scaling factors based on the Monte Carlo results. Parameterizations are provided for computing the optical depth scaling factors for water clouds, ice clouds, aerosols, and for completeness, Rayleigh scattering to allow for a simple calculation of t(α). It is also shown that the optical depth scaling used in delta-two-stream approximations is inappropriate for simulating the direct solar radiation received by pyrheliometers.

scholarly journals Cloud sensitivity studies for stratospheric and lower mesospheric ozone profile retrievals from measurements of limb-scattered solar radiation

2009 ◽  
Vol 2 (2) ◽  
pp. 653-678 ◽  
Author(s):  
T. Sonkaew ◽  
V. V. Rozanov ◽  
C. von Savigny ◽  
A. Rozanov ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Relative Error ◽  
Optical Thickness ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Absorption Bands ◽  
Ozone Profile ◽  
Mesospheric Ozone ◽  
Cloud Optical Thickness ◽  
The Impact

Abstract. Clouds in the atmosphere play an important role in reflection, absorption and transmission of solar radiation and thus affect trace gas retrievals. The main goal of this paper is to examine the sensitivity of stratospheric and lower mesospheric ozone retrievals from limb-scattered radiance measurements to clouds using the SCIATRAN radiative transfer model and retrieval package. The retrieval approach employed is optimal estimation, and the considered clouds are vertically and horizontally homogeneous. Assuming an aerosol-free atmosphere and Mie phase functions for cloud particles, we compute the relative error of ozone profile retrievals in a cloudy atmosphere if clouds are neglected in the retrieval. To access altitudes from the lower stratosphere up to the lower mesosphere, we combine the retrievals in the Chappuis and Hartley ozone absorption bands. We find significant cloud sensitivity of the limb ozone retrievals in the Chappuis bands at lower stratospheric altitudes. The relative error in the retrieved ozone concentrations gradually decreases with increasing altitude and becomes negligible above approximately 40 km. The parameters with the largest impact on the ozone retrievals are cloud optical thickness, ground albedo and solar zenith angle. Clouds with different geometrical thicknesses or different cloud altitudes have a similar impact on the ozone retrievals for a given cloud optical thickness value, if the clouds are outside the field of view of the instrument. The effective radius of water droplets has a small influence on the error, i.e., less than 0.5% at altitudes above the cloud top height. Furthermore, the impact of clouds on the ozone profile retrievals was found to have a rather small dependence on the solar azimuth angle (less than 1% for all possible azimuth angles). For the most frequent cloud types, the total error is below 6% above 15 km altitude, if clouds are completely neglected in the retrieval. Neglecting clouds in the ozone profile retrievals generally leads to a low bias for a low ground albedo and to a high bias for a high ground albedo, assuming that the ground albedo is well known.

scholarly journals Local Tilt Optimization of Photovoltaic Solar Panels for Maximum Radiation Absorption

2019 ◽  
Vol 2019 ◽  
pp. 1-10
Author(s):  
Mauro Masili ◽  
Liliane Ventura
Keyword(s):  
Solar Radiation ◽  
Tilt Angle ◽  
Spectral Response ◽  
Solar Spectrum ◽  
Weather Conditions ◽  
Solar Irradiation ◽  
Radiation Absorption ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Solar Panels

Incident solar radiation on photovoltaic (PV) solar panels is not constant throughout the year. Besides dependence on the season, solar radiation is reliant on the location and weather conditions. For a given location on Earth, the best-fixed orientation of a PV panel can be determined by achieving the maximum incident solar irradiance throughout the year or for a predetermined period. In this paper, we use a sophisticated atmospheric radiative transfer model to calculate the direct and diffuse solar irradiation (radiant exposure) for the solar spectrum incident on PV solar panels to determine the best tilt angle of the panel in order to maximize absorption of solar radiation for selected periods. We used the Regula-Falsi numerical method to obtain the tilt angle at which the derivative of solar irradiation (concerning the tilt angle) approaches zero. Moreover, the spectral response of typical silicon cells is taken into account. These calculations were carried out in São Carlos (SP), a town in the southeast of Brazil. The best tilt angle was obtained for three selected periods. Additionally, we provide results for Southern latitudes ranging from 0° to −55° in steps of −5° for the meteorological seasons. We have shown that for each period, there is an increase in solar radiation absorption compared to the traditional installation angle based exclusively on the local latitude. These calculations can be extended to any location.

scholarly journals A fast visible-wavelength 3D radiative transfer model for numerical weather prediction visualization and forward modeling

2020 ◽  
Vol 13 (6) ◽  
pp. 3235-3261
Author(s):  
Steven Albers ◽  
Stephen M. Saleeby ◽  
Sonia Kreidenweis ◽  
Qijing Bian ◽  
Peng Xian ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Radiative Transfer ◽  
Numerical Weather Prediction ◽  
Land Surface ◽  
Weather Prediction ◽  
Lower Boundary ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Numerical Weather ◽  
Visible Wavelength

Abstract. Solar radiation is the ultimate source of energy flowing through the atmosphere; it fuels all atmospheric motions. The visible-wavelength range of solar radiation represents a significant contribution to the earth's energy budget, and visible light is a vital indicator for the composition and thermodynamic processes of the atmosphere from the smallest weather scales to the largest climate scales. The accurate and fast description of light propagation in the atmosphere and its lower-boundary environment is therefore of critical importance for the simulation and prediction of weather and climate. Simulated Weather Imagery (SWIm) is a new, fast, and physically based visible-wavelength three-dimensional radiative transfer model. Given the location and intensity of the sources of light (natural or artificial) and the composition (e.g., clear or turbid air with aerosols, liquid or ice clouds, precipitating rain, snow, and ice hydrometeors) of the atmosphere, it describes the propagation of light and produces visually and physically realistic hemispheric or 360∘ spherical panoramic color images of the atmosphere and the underlying terrain from any specified vantage point either on or above the earth's surface. Applications of SWIm include the visualization of atmospheric and land surface conditions simulated or forecast by numerical weather or climate analysis and prediction systems for either scientific or lay audiences. Simulated SWIm imagery can also be generated for and compared with observed camera images to (i) assess the fidelity and (ii) improve the performance of numerical atmospheric and land surface models. Through the use of the latter in a data assimilation scheme, it can also (iii) improve the estimate of the state of atmospheric and land surface initial conditions for situational awareness and numerical weather prediction forecast initialization purposes.

scholarly journals On the ability of RegCM4 regional climate model to simulate surface solar radiation patterns over Europe: an assessment using satellite-based observations

2015 ◽  
Vol 15 (22) ◽  
pp. 13195-13216 ◽  
Author(s):  
G. Alexandri ◽  
A. K. Georgoulias ◽  
P. Zanis ◽  
E. Katragkou ◽  
A. Tsikerdekis ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Regional Climate Model ◽  
Climate Model ◽  
Regional Climate ◽  
Radiative Transfer Model ◽  
Asymmetry Factor ◽  
Transfer Model ◽  
Potential Contribution ◽  
Absolute Deviation ◽  
Surface Solar Radiation

Abstract. In this work, we assess the ability of RegCM4 regional climate model to simulate surface solar radiation (SSR) patterns over Europe. A decadal RegCM4 run (2000–2009) was implemented and evaluated against satellite-based observations from the Satellite Application Facility on Climate Monitoring (CM SAF), showing that the model simulates adequately the SSR patterns over the region. The SSR bias between RegCM4 and CM SAF is +1.5 % for MFG (Meteosat First Generation) and +3.3 % for MSG (Meteosat Second Generation) observations. The relative contribution of parameters that determine the transmission of solar radiation within the atmosphere to the deviation appearing between RegCM4 and CM SAF SSR is also examined. Cloud macrophysical and microphysical properties such as cloud fractional cover (CFC), cloud optical thickness (COT) and cloud effective radius (Re) from RegCM4 are evaluated against data from CM SAF. Generally, RegCM4 underestimates CFC by 24.3 % and Re for liquid/ice clouds by 36.1 %/28.3 % and overestimates COT by 4.3 %. The same procedure is repeated for aerosol optical properties such as aerosol optical depth (AOD), asymmetry factor (ASY) and single-scattering albedo (SSA), as well as other parameters, including surface broadband albedo (ALB) and water vapor amount (WV), using data from MACv1 aerosol climatology, from CERES satellite sensors and from ERA-Interim reanalysis. It is shown here that the good agreement between RegCM4 and satellite-based SSR observations can be partially attributed to counteracting effects among the above mentioned parameters. The potential contribution of each parameter to the RegCM4–CM SAF SSR deviations is estimated with the combined use of the aforementioned data and a radiative transfer model (SBDART). CFC, COT and AOD are the major determinants of these deviations on a monthly basis; however, the other parameters also play an important role for specific regions and seasons. Overall, for the European domain, CFC, COT and AOD are the most important factors, since their underestimations and overestimations by RegCM4 cause an annual RegCM4–CM SAF SSR absolute deviation of 8.4, 3.8 and 4.5 %, respectively.

scholarly journals Analysis of Long-Term Solar Resource Variability Using NSRDB Version 3

2021 ◽  
Author(s):  
Manajit Sengupta ◽  
Aron Habte
Keyword(s):  
Solar Radiation ◽  
Spatial Variability ◽  
Temporal Variability ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Spatial And Temporal Variability ◽  
Cloud Optical Depth ◽  
Resource Variability ◽  
Solar Resource

<p>Understanding long-term solar resource variability is essential for planning and deployment of solar energy systems. These variabilities occur due to deterministic effects such as sun cycle and nondeterministic such as complex weather patterns. The NREL’s National Solar Radiation Database (NSRDB) provides long term solar resource data covering 1998- 2019 containing more than 2 million pixels over the Americas and gets updated on an annual basis. This dataset is satellite-based and uses a two-step physical model for it’s development. In the first step we retrieve cloud properties such as cloud mask, cloud type, cloud optical depth and effective radius. The second step uses a fast radiative transfer model to compute solar radiation.  This dataset is ideal for studying solar resource variability. For this study, NSRDB version 3 which contains data from 1998-2017 on a half hourly and 4x4 km temporal and spatial resolution was used. The study analyzed the spatial and temporal trend of solar resource of global horizontal irradiance (GHI) and direct normal irradiance (DNI) using long-term 20-years NSRDB data. The coefficient of variation (COV) was used to analyze the spatio-temporal interannual and seasonal variabilities. The spatial variability was analyzed by comparing the center pixel to neighboring pixels. The spatial variability result showed higher COV as the number of neighboring pixels increased. Similarly, the temporal variability for the NSRDB domain ranges on average from ±10% for GHI and ±20% for DNI. Furthermore, the long-term variabilities were also analyzed using the Köppen-Geiger climate classification. This assisted in the interpretation of the result by reducing the originally large number of pixels into a smaller number of groups. This presentation will provided a unique look at long-term spatial and temporal variability of solar radiation using high-resolution satellite-based datasets.</p>

Sign in / Sign up

Export Citation Format

Share Document