scholarly journals Cloud sensitivity studies for stratospheric and lower mesospheric ozone profile retrievals from measurements of limb-scattered solar radiation

2009 ◽  
Vol 2 (2) ◽  
pp. 653-678 ◽  
Author(s):  
T. Sonkaew ◽  
V. V. Rozanov ◽  
C. von Savigny ◽  
A. Rozanov ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Relative Error ◽  
Optical Thickness ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Absorption Bands ◽  
Ozone Profile ◽  
Mesospheric Ozone ◽  
Cloud Optical Thickness ◽  
The Impact

Abstract. Clouds in the atmosphere play an important role in reflection, absorption and transmission of solar radiation and thus affect trace gas retrievals. The main goal of this paper is to examine the sensitivity of stratospheric and lower mesospheric ozone retrievals from limb-scattered radiance measurements to clouds using the SCIATRAN radiative transfer model and retrieval package. The retrieval approach employed is optimal estimation, and the considered clouds are vertically and horizontally homogeneous. Assuming an aerosol-free atmosphere and Mie phase functions for cloud particles, we compute the relative error of ozone profile retrievals in a cloudy atmosphere if clouds are neglected in the retrieval. To access altitudes from the lower stratosphere up to the lower mesosphere, we combine the retrievals in the Chappuis and Hartley ozone absorption bands. We find significant cloud sensitivity of the limb ozone retrievals in the Chappuis bands at lower stratospheric altitudes. The relative error in the retrieved ozone concentrations gradually decreases with increasing altitude and becomes negligible above approximately 40 km. The parameters with the largest impact on the ozone retrievals are cloud optical thickness, ground albedo and solar zenith angle. Clouds with different geometrical thicknesses or different cloud altitudes have a similar impact on the ozone retrievals for a given cloud optical thickness value, if the clouds are outside the field of view of the instrument. The effective radius of water droplets has a small influence on the error, i.e., less than 0.5% at altitudes above the cloud top height. Furthermore, the impact of clouds on the ozone profile retrievals was found to have a rather small dependence on the solar azimuth angle (less than 1% for all possible azimuth angles). For the most frequent cloud types, the total error is below 6% above 15 km altitude, if clouds are completely neglected in the retrieval. Neglecting clouds in the ozone profile retrievals generally leads to a low bias for a low ground albedo and to a high bias for a high ground albedo, assuming that the ground albedo is well known.

scholarly journals Cloud sensitivity studies for stratospheric and lower mesospheric ozone profile retrievals from measurements of limb scattered solar radiation

2009 ◽  
Vol 2 (1) ◽  
pp. 379-438 ◽  
Author(s):  
T. Sonkaew ◽  
V. V. Rozanov ◽  
C. von Savigny ◽  
A. Rozanov ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Relative Error ◽  
Optical Thickness ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Absorption Bands ◽  
Ozone Profile ◽  
Mesospheric Ozone ◽  
Cloud Optical Thickness ◽  
The Impact

Abstract. Clouds in the atmosphere play an important role in reflection, absorption and transmission of solar radiation affecting trace gas retrievals. The main goal of this paper is to examine the sensitivity of stratospheric and lower mesospheric ozone retrievals from limb-scattered radiance measurements to clouds using the SCIATRAN radiative transfer model and retrieval package. Assuming an aerosol-free atmosphere and Mie phase functions for cloud particles, we compute the relative error of ozone profile retrievals in a cloudy atmosphere if clouds are neglected in the retrieval. To access altitudes from the lower stratosphere up to lower mesosphere, we combine the retrievals in the Chappuis and Hartley ozone absorption bands. We find significant cloud sensitivity of the limb ozone retrievals in the Chappuis bands at lower stratospheric altitudes. The relative error in the retrieved ozone concentrations gradually decreases with increasing altitude and becomes negligible above about 40 km. The parameters with the largest impact on the ozone retrievals are cloud optical thickness, ground albedo and solar zenith angle. Clouds with different geometrical thicknesses or different cloud altitudes have a similar impact on the ozone retrievals for a given cloud optical thickness value, if the clouds are outside the field of view of the instrument. The effective radius of water droplets has a small influence on the error, i.e., less than 0.5% at altitudes above the cloud top height. Furthermore, the impact of clouds on the ozone profile retrievals was found to have a rather small dependence on the solar azimuth angle (less than 1% for all possible azimuth angles). For the most frequent cloud types the total error is below 6% above 15 km altitude, if clouds are completely neglected in the retrieval. Neglecting clouds in the ozone profile retrievals generally leads to a low bias for a low ground albedo and to a high bias for a high ground albedo, assuming that the ground albedo is well known.

Human Impact on Direct and Diffuse Solar Radiation during the Industrial Era

2007 ◽  
Vol 20 (19) ◽  
pp. 4874-4883 ◽  
Author(s):  
Maria M. Kvalevåg ◽  
Gunnar Myhre
Keyword(s):  
Water Vapor ◽  
Solar Radiation ◽  
Central Africa ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Physical Processes ◽  
Diffuse Solar Radiation ◽  
Global Dimming ◽  
Aerosol Effects ◽  
The Impact

Abstract In this study the direct and diffuse solar radiation changes are estimated, and they contribute to the understanding of the observed global dimming and the more recent global brightening during the industrial era. Using a multistream radiative transfer model, the authors calculate the impact of changes in ozone, NO2, water vapor, CH4, CO2, direct and indirect aerosol effects, contrails, and aviation-induced cirrus on solar irradiances at the surface. The results show that dimming is most pronounced in central Africa, Southeast Asia, Europe, and northeast America. Human activity during the industrial era is calculated and accounts for a decrease in direct solar radiation at the surface of up to 30 W m−2 (30%–40%) and an increase in diffuse solar radiation of up to 20 W m−2. The physical processes that lead to the changes in direct and diffuse solar radiation are found to be remarkably different and the authors explain which mechanisms are responsible for the observed changes.

scholarly journals Disk and circumsolar radiances in the presence of ice clouds

2017 ◽  
Vol 17 (11) ◽  
pp. 6865-6882 ◽  
Author(s):  
Päivi Haapanala ◽  
Petri Räisänen ◽  
Greg M. McFarquhar ◽  
Jussi Tiira ◽  
Andreas Macke ◽  
...  
Keyword(s):  
Optical Thickness ◽  
Ice Crystals ◽  
Crystal Habit ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
The Sun ◽  
Ice Crystal ◽  
Ice Clouds ◽  
Ice Cloud ◽  
The Impact

Abstract. The impact of ice clouds on solar disk and circumsolar radiances is investigated using a Monte Carlo radiative transfer model. The monochromatic direct and diffuse radiances are simulated at angles of 0 to 8° from the center of the sun. Input data for the model are derived from measurements conducted during the 2010 Small Particles in Cirrus (SPARTICUS) campaign together with state-of-the-art databases of optical properties of ice crystals and aerosols. For selected cases, the simulated radiances are compared with ground-based radiance measurements obtained by the Sun and Aureole Measurements (SAM) instrument. First, the sensitivity of the radiances to the ice cloud properties and aerosol optical thickness is addressed. The angular dependence of the disk and circumsolar radiances is found to be most sensitive to assumptions about ice crystal roughness (or, more generally, non-ideal features of ice crystals) and size distribution, with ice crystal habit playing a somewhat smaller role. Second, in comparisons with SAM data, the ice cloud optical thickness is adjusted for each case so that the simulated radiances agree closely (i.e., within 3 %) with the measured disk radiances. Circumsolar radiances at angles larger than ≈ 3° are systematically underestimated when assuming smooth ice crystals, whereas the agreement with the measurements is better when rough ice crystals are assumed. Our results suggest that it may well be possible to infer the particle roughness directly from ground-based SAM measurements. In addition, the results show the necessity of correcting the ground-based measurements of direct radiation for the presence of diffuse radiation in the instrument's field of view, in particular in the presence of ice clouds.

scholarly journals Sensitivity of thermal infrared sounders to the chemical and micro-physical properties of UTLS secondary sulphate aerosols

2015 ◽  
Vol 8 (8) ◽  
pp. 8439-8481 ◽  
Author(s):  
P. Sellitto ◽  
B. Legras
Keyword(s):  
Radiative Transfer ◽  
Physical Properties ◽  
Sulphuric Acid ◽  
Thermal Infrared ◽  
Radiative Transfer Model ◽  
Spectral Signature ◽  
Transfer Model ◽  
Absorption Bands ◽  
Sulphate Aerosols ◽  
The Impact

Abstract. Monitoring upper tropospheric-lower stratospheric (UTLS) secondary sulphate aerosols and their chemical and micro-physical properties from satellite nadir observations is crucial to better understand their formation and evolution processes and then to estimate their impact to the UTLS chemistry, and on regional and global radiative balance. Here we present a study aimed at the evaluation of the sensitivity of thermal infrared (TIR) satellite nadir observations to the chemical composition and the size distribution of idealized UTLS sulphate aerosol layers. The extinction properties of sulphuric acid/water droplets, for different sulphuric acid mixing ratios and temperatures, are systematically analysed. The extinction coefficients are derived by means of a Mie code, using refractive indexes taken from the GEISA (Gestion et Étude des Informations Spectroscopiques Atmosphériques: Management and Study of Spectroscopic Information) spectroscopic database and log-normal size distributions with different effective radii and number concentrations. IASI (Infrared Atmospheric Sounding Interferometer) pseudo-observations are generated using forward radiative transfer calculations performed with the 4A (Automatized Atmospheric Absorption Atlas) radiative transfer model, to estimate the impact of the extinction of idealized aerosol layers, at typical UTLS conditions, on the brightness temperature spectra observed by this satellite instrument. We found a marked and typical spectral signature of these aerosol layers between 700 and 1200 cm−1, due to the absorption bands of the sulphate and bi-sulphate ions and the undissociated sulphuric acid, with the main absorption peaks at 1170 and 905 cm−1. The dependence of the aerosol spectral signature to the sulphuric acid mixing ratio, and effective number concentration and radius, as well as the role of interferring parameters like the ozone, sulphur dioxide, carbon dioxide and ash absorption, and temperature and water vapour profile uncertainties, are analyzed and critically discussed.

scholarly journals Retrieval of Ice Cloud Optical Thickness and Effective Particle Size Using a Fast Infrared Radiative Transfer Model

2011 ◽  
Vol 50 (11) ◽  
pp. 2283-2297 ◽  
Author(s):  
Chenxi Wang ◽  
Ping Yang ◽  
Bryan A. Baum ◽  
Steven Platnick ◽  
Andrew K. Heidinger ◽  
...  
Keyword(s):  
Particle Size ◽  
Radiative Transfer ◽  
Optical Thickness ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Distribution Method ◽  
Ice Cloud ◽  
Effective Particle Size ◽  
Effective Particle ◽  
Cloud Optical Thickness

AbstractA computationally efficient radiative transfer model (RTM) is developed for the inference of ice cloud optical thickness and effective particle size from satellite-based infrared (IR) measurements and is aimed at potential use in operational cloud-property retrievals from multispectral satellite imagery. The RTM employs precomputed lookup tables to simulate the top-of-the-atmosphere (TOA) radiances (or brightness temperatures) at 8.5-, 11-, and 12-μm bands. For the clear-sky atmosphere, the optical thickness of each atmospheric layer resulting from gaseous absorption is derived from the correlated-k-distribution method. The cloud reflectance, transmittance, emissivity, and effective temperature are precomputed using the Discrete Ordinate Radiative Transfer model (DISORT). For an atmosphere containing a semitransparent ice cloud layer with a visible optical thickness τ smaller than 5, the TOA brightness temperature differences (BTDs) between the fast model and the more rigorous DISORT results are less than 0.1 K, whereas the BTDs are less than 0.01 K if τ is larger than 10. With the proposed RTM, the cloud optical and microphysical properties are retrieved from collocated observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) in conjunction with the Modern Era Retrospective-Analysis for Research and Applications (MERRA) data. Comparisons between the retrieved ice cloud properties (optical thickness and effective particle size) based on the present IR fast model and those from the Aqua/MODIS operational collection-5 cloud products indicate that the IR retrievals are smaller. A comparison between the IR-retrieved ice water path (IWP) and CALIOP-retrieved IWP shows robust agreement over most of the IWP range.

scholarly journals Disk and circumsolar radiances in the presence of ice clouds

2016 ◽  
Author(s):  
Päivi Haapanala ◽  
Petri Räisänen ◽  
Greg M. McFarquhar ◽  
Jussi Tiira ◽  
Andreas Macke ◽  
...  
Keyword(s):  
Optical Thickness ◽  
Ice Crystals ◽  
Crystal Habit ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
The Sun ◽  
Ice Crystal ◽  
Ice Clouds ◽  
Ice Cloud ◽  
The Impact

Abstract. The impact of ice clouds on solar-disk and circumsolar radiances is investigated using a Monte Carlo radiative transfer model. The monochromatic direct and diffuse radiances are simulated at angles of 0° to 8° from the center of the Sun. Input data for the model are derived from measurements conducted during the 2010 Small Particles in Cirrus campaign together with state-of-the-art databases of optical properties of ice crystals and aerosols. For selected cases, the simulated radiances are compared with ground-based radiance measurements with the Sun and Aureole Measurement (SAM) instrument. First, the sensitivity of the radiances to the ice cloud properties and aerosol optical thickness was addressed. The angular dependence of the disk and circumsolar radiances was found to be most sensitive to assumptions about ice crystal roughness (or, more generally, non-ideal features of ice crystals) and size distribution, with ice crystal habit playing a somewhat smaller role. Second, in the comparisons with SAM data, the ice-cloud optical thickness was adjusted for each case so that the simulated radiances agreed closely (i.e., within 3 %) with the measured disk radiances. Circumsolar radiances at angles larger than ≈ 3° were systematically underestimated when assuming smooth ice crystals, but the agreement with the measurements was better when rough ice crystals were assumed. Our results suggest that it may well be possible to infer the particle roughness (or more generally, non-ideality) directly from ground-based SAM measurements. In addition, the results show the necessity of correcting the ground-based measurements of direct radiation for the presence of diffuse radiation in the instrument's field of view, in particular in the presence of ice clouds.

scholarly journals A New Method to Retrieve Thin Cloud Optical Thickness from a Ratio of Scattering to Global Solar Irradiance

2014 ◽  
Vol 71 (4) ◽  
pp. 1521-1528 ◽  
Author(s):  
Jinhuan Qiu ◽  
Xuemei Zong
Keyword(s):  
Optical Thickness ◽  
New Method ◽  
Radiative Transfer Model ◽  
Mean Deviation ◽  
Transfer Model ◽  
Thin Cloud ◽  
Scattering Phase ◽  
Cloud Optical Thickness ◽  
The Difference ◽  
Scattering Phase Function

Abstract Three kinds of “visible” cloud optical thickness τ—matching shortwave direct, global, and scattering solar irradiances (Ids, Igs and Iss)—are defined, which are marked as τd, τg, and τs, respectively. It is found from radiation calculations that a ratio of Iss to Igs in the small-τ case has a unique characteristic: strong sensitivity to τ but weak sensitivity to the cloud scattering phase function. On the basis of this characteristic, a method to retrieve Iss-equivalent τs from the ratio is proposed. This method is validated by way of simulation and application tests, in which the Discrete Ordinate Radiative Transfer model (DISORT) is used to calculate irradiances. As shown in simulations with τ < 2, there may be unrealistically negative or grossly overestimated τ values from Igs, owing to the difference between τs and τd, while the new method can lead to a very good agreement of τs retrieval with its input. Furthermore, this method is used to retrieve small τ from the pyrheliometer and pyranometer measurements in Lhasa during 2006. It is found that τ retrieved from Igs was often negative because of cloud inhomogeneity, while the application of the new method resulted in stable yet reasonable τs values. The Iss calculations using 1293 sets of τs retrievals fit well into the Iss determinations from pyrheliometer and pyranometer measurements with an annual-mean deviation of 0.18%, but the deviation was raised to 46.4% when using τg retrievals.

scholarly journals Fast Hyper-Spectral Radiative Transfer Model Based on the Double Cluster Low-Streams Regression Method

2021 ◽  
Vol 13 (3) ◽  
pp. 434
Author(s):  
Ana del Águila ◽  
Dmitry S. Efremenko
Keyword(s):  
Radiative Transfer ◽  
Single Scattering ◽  
Atmospheric Composition ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Absorption Bands ◽  
Acceleration Techniques ◽  
Scattering Approximation ◽  
Fine Resolution ◽  
Single Scattering Approximation

Fast radiative transfer models (RTMs) are required to process a great amount of satellite-based atmospheric composition data. Specifically designed acceleration techniques can be incorporated in RTMs to simulate the reflected radiances with a fine spectral resolution, avoiding time-consuming computations on a fine resolution grid. In particular, in the cluster low-streams regression (CLSR) method, the computations on a fine resolution grid are performed by using the fast two-stream RTM, and then the spectra are corrected by using regression models between the two-stream and multi-stream RTMs. The performance enhancement due to such a scheme can be of about two orders of magnitude. In this paper, we consider a modification of the CLSR method (which is referred to as the double CLSR method), in which the single-scattering approximation is used for the computations on a fine resolution grid, while the two-stream spectra are computed by using the regression model between the two-stream RTM and the single-scattering approximation. Once the two-stream spectra are known, the CLSR method is applied the second time to restore the multi-stream spectra. Through a numerical analysis, it is shown that the double CLSR method yields an acceleration factor of about three orders of magnitude as compared to the reference multi-stream fine-resolution computations. The error of such an approach is below 0.05%. In addition, it is analysed how the CLSR method can be adopted for efficient computations for atmospheric scenarios containing aerosols. In particular, it is discussed how the precomputed data for clear sky conditions can be reused for computing the aerosol spectra in the framework of the CLSR method. The simulations are performed for the Hartley–Huggins, O2 A-, water vapour and CO2 weak absorption bands and five aerosol models from the optical properties of aerosols and clouds (OPAC) database.

scholarly journals Ozone formation under low solar radiation in eastern China

2019 ◽  
Author(s):  
Xuexi Tie ◽  
Xin Long ◽  
Guohui Li ◽  
Shuyu Zhao ◽  
Jianming Xu
Keyword(s):  
Solar Radiation ◽  
Eastern China ◽  
Threshold Level ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Oh Radicals ◽  
Chemical Production ◽  
The Past ◽  
Photochemical Production ◽  
Steady State Model

Abstract. PM2.5, a particulate matter with a diameter of 2.5 micrometers or less, is one of the major components of the air pollution in eastern China. In the past few years, China's government made strong efforts to reduce the PM2.5 pollutions. However, another important pollutant (ozone) becomes an important problem in eastern China. Ozone (O3) is produced by photochemistry, which requires solar radiation for the formation of O3. Under heavy PM2.5 pollution, the solar radiation is often depressed, and the photochemical production of O3 is prohibited. This study shows that during fall in eastern China, under heavy PM2.5 pollutions, there were often strong O3 photochemical productions, causing a co-occurrence of high PM2.5 and O3 concentrations. This co-occurrence of high PM2.5 and O3 is un-usual and is the main focus of this study. Recent measurements show that there were often high HONO surface concentrations in major Chinese mega cities, especially during daytime, with maximum concentrations ranging from 0.5 to 2 ppbv. It is also interesting to note that the high HONO concentrations were occurred during high aerosol concentration periods, suggesting that there were additional HONO surface sources in eastern China. Under the high daytime HONO concentrations, HONO can be photo-dissociated to be OH radicals, which enhance the photochemical production of O3. In order to study the above scientific issues, a radiative transfer model (TUV; Tropospheric Ultraviolet-Visible) is used in this study, and a chemical steady state model is established to calculate OH radical concentrations. The calculations show that by including the OH production of the photo-dissociated of HONO, the calculated OH concentrations are significantly higher than the values without including this production. For example, by including HONO production, the maximum of OH concentration under the high aerosol condition (AOD = 2.5) is similar to the value under low aerosol condition (AOD = 0.25) in the no-HONO case. This result suggests that even under the high aerosol condition, the chemical oxidizing process for O3 production can occurred, which explain the co-occurrence of high PM2.5 and high O3 in fall season in eastern China. However, the O3 concentrations were not significantly affected by the appearance of HONO in winter. This study shows that the seasonal variation of solar radiation plays important roles for controlling the OH production in winter. When the solar radiation is in a very low level in winter, it reaches the threshold level to prevent the OH chemical production, even by including the HONO production of OH. This study provides some important scientific highlights to better understand the O3 pollutions in eastern China.

scholarly journals The impact of residential combustion emissions on atmospheric aerosol, human health, and climate

2016 ◽  
Vol 16 (2) ◽  
pp. 873-905 ◽  
Author(s):  
E. W. Butt ◽  
A. Rap ◽  
A. Schmidt ◽  
C. E. Scott ◽  
K. J. Pringle ◽  
...  
Keyword(s):  
Eastern Europe ◽  
Human Health ◽  
Atmospheric Aerosol ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
So2 Emissions ◽  
Residential Sector ◽  
Residential Combustion ◽  
Combustion Emissions ◽  
The Impact

Abstract. Combustion of fuels in the residential sector for cooking and heating results in the emission of aerosol and aerosol precursors impacting air quality, human health, and climate. Residential emissions are dominated by the combustion of solid fuels. We use a global aerosol microphysics model to simulate the impact of residential fuel combustion on atmospheric aerosol for the year 2000. The model underestimates black carbon (BC) and organic carbon (OC) mass concentrations observed over Asia, Eastern Europe, and Africa, with better prediction when carbonaceous emissions from the residential sector are doubled. Observed seasonal variability of BC and OC concentrations are better simulated when residential emissions include a seasonal cycle. The largest contributions of residential emissions to annual surface mean particulate matter (PM2.5) concentrations are simulated for East Asia, South Asia, and Eastern Europe. We use a concentration response function to estimate the human health impact due to long-term exposure to ambient PM2.5 from residential emissions. We estimate global annual excess adult (>  30 years of age) premature mortality (due to both cardiopulmonary disease and lung cancer) to be 308 000 (113 300–497 000, 5th to 95th percentile uncertainty range) for monthly varying residential emissions and 517 000 (192 000–827 000) when residential carbonaceous emissions are doubled. Mortality due to residential emissions is greatest in Asia, with China and India accounting for 50 % of simulated global excess mortality. Using an offline radiative transfer model we estimate that residential emissions exert a global annual mean direct radiative effect between −66 and +21 mW m−2, with sensitivity to the residential emission flux and the assumed ratio of BC, OC, and SO2 emissions. Residential emissions exert a global annual mean first aerosol indirect effect of between −52 and −16 mW m−2, which is sensitive to the assumed size distribution of carbonaceous emissions. Overall, our results demonstrate that reducing residential combustion emissions would have substantial benefits for human health through reductions in ambient PM2.5 concentrations.

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