CHEMICAL DEGRADATION OF POLYURETHANE FOAM WASTE AND ITS CROSSLINKED NATURAL RUBBER

2015 ◽  
Vol 88 (3) ◽  
pp. 437-448 ◽  
Author(s):  
Sa-Ad Riyajan ◽  
Nattanan Keawmwnee ◽  
Pramuan Tangboriboonrat
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Polyurethane Foam ◽  
Cost Effective ◽  
Chemical Degradation ◽  
Cure Rate ◽  
Elongation At Break ◽  
Environmental Friendly ◽  
Roll Mill ◽  
By Products

ABSTRACT The objective of this work was to use by-products from the chemical degradation of polyurethane foam waste (w-PUfd) and blend them with an epoxidized natural rubber (ENR), named PENR, for improving the mechanical properties of a Standard Thai rubber 5L (STR 5L). The swelling ratio in toluene of the PENR decreased as a function of w-PUfd content due to an increase in chemical interactions. After blending the PENR with the STR-5L and vulcanizing agents using two-roll mill and then compression molding at 150 °C, the effects of w-PUfd content in PENR on the properties of cured STR-5L were investigated. The cure rate index, tensile strength, and elongation at break of the cured STR-5L were improved after the addition of PENR. The swelling in toluene of cured STR-5L decreased as a function of w-PUfd in PENR. At 100 phr w-PUfd in PENR, the 20:80 PENR:STR-5L provided the highest tensile strength of ~23 MPa. These biodegradable, cured rubbers with w-PUfd content are environmental friendly and cost-effective products.

Tensile Properties and Morphology of Recycled Latex Glove Filled Epoxidized Natural Rubber (ENR50) Compounds

2014 ◽  
Vol 660 ◽  
pp. 306-311
Author(s):  
A.A. Afiratul ◽  
N.Z. Noimam ◽  
C.M. Ruzaidi ◽  
Sung Ting Sam ◽  
M.F. Omar ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
High Surface ◽  
Weight Ratio ◽  
Epoxidized Natural Rubber ◽  
Elongation At Break ◽  
Latex Glove ◽  
Roll Mill ◽  
Fine Size

The effects on the properties of recycled latex glove (RL-G) filled Epoxidized Natural Rubber (ENR 50) were studied. Both compounds were prepared by two roll mill at five different compositions of RL-G (5, 15, 25, 35 and 50 phr). The size range of RL-G particles i.e., S1 (300μm-700μm) and S2 (3cm-5cm) were used. The properties such as tensile properties (tensile strength, elongation at break, and stress at 100% elongation) and morphology studies were determined. The results indicated that the both size, S1 and S2 of recycled latex glove filled ENR 50 blends exhibited an increased in tensile strength and elongation at break for increasing weight ratio of RL-G. Scanning electron microscopy (SEM) of the fracture surfaces shows that the fine size, S1 RL-G/ENR50 exhibited high surface roughness and matrix tearing lines than the coarse size, S2 thus improving the compatibility of RL-G/ENR50 compounds. The results overall indicated that the fine size, S1of RL-G filled ENR50 contributed to the better properties such as tensile strength and surface morphology compared to the coarse size, S2 mainly at 15 phr of RL-G content.

Waste Silicon Carbide as Filler for Natural Rubber Compounds

2014 ◽  
Vol 979 ◽  
pp. 155-158 ◽  
Author(s):  
Apaipan Rattanapan ◽  
Jitrakha Paksamut ◽  
Pornsri Pakeyangkoon ◽  
Surakit Tuampoemsab
Keyword(s):  
Silicon Carbide ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Shear Viscosity ◽  
Tensile Modulus ◽  
Filler Loading ◽  
Extrudate Swell ◽  
Elongation At Break ◽  
Roll Mill ◽  
Cure Time

This work studied possibilities of using waste silicon carbide (SiC) particles from abrasive industry as alternative filler in natural rubber (NR) compounds. The rubber was prepared by using natural rubber grade STR 5L and waste silicon carbide loading of 0, 10, 20, 30 and 40 phr. Firstly, the rubber were compounded by using two roll mill and then using Oscillating Disc Rheometer for studying cure time at one hundred and fifty degree Celsius. Then, shear viscosity and extrudate swell of the compounded natural rubber were characterized by using capillary rheometer at 100°C. The result showed that the apparent shear viscosity increased slightly with increasing waste silicon carbide loading and the percentage of extrudate swell was found to be a decreasing function of the filler loading. Then, test tensile by using the prepared samples for studying tensile modulus, tensile strength and elongation at break. The result showed that tensile modulus and tensile strength increased with increasing waste silicon carbide. On the other hand, the elongation at break of the filled natural rubber decreased with increasing waste silicon carbide. Finally, bring the sample to test hardness by using shore A. Results indicated that waste silicon carbide direct variation with the indicator of hardness.

Cure and Mechanical Properties of Natural Rubber Filled Bacterial Cellulose

2016 ◽  
Vol 705 ◽  
pp. 40-44
Author(s):  
Chaiwute Vudjung
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Bacterial Cellulose ◽  
Elongation At Break ◽  
Roll Mill ◽  
Cure Time ◽  
Mooney Viscosity

Natural rubber (NR) containing the nata de coco fiber or Bacterial cellulose (BC) was prepared by co-coagulation of BC and concentrated NR latex with CaCl2 and compounded by two roll mill. The effect of BC content was the important factor in this study. It was that found tensile strength and elongation at break of NR filled BC (NR/BC) decreased with increasing BC content. The addition of BC into NR affect Mooney viscosity of NR/BC masterbatch, with increasing BC content, scorch time and cure time of their compound decreased.

Tensile Properties and Morphology of Recycled Latex Glove Filled Epoxidized Natural Rubber (ENR50) Compounds

2014 ◽  
Vol 679 ◽  
pp. 267-272 ◽  
Author(s):  
A.A. Afiratul ◽  
Nik Noriman Zulkepli ◽  
C.M. Ruzaidi ◽  
S.T. Sam ◽  
Mohd Firdaus Omar ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
High Surface ◽  
Weight Ratio ◽  
Epoxidized Natural Rubber ◽  
Elongation At Break ◽  
Latex Glove ◽  
Roll Mill ◽  
Fine Size

The effects on the properties of recycled latex glove (RL-G) filled Epoxidized Natural Rubber (ENR 50) were studied. Both compounds were prepared by two roll mill at five different compositions of RL-G (5, 15, 25, 35 and 50 phr). The size range of RL-G particles i.e., S1 (300μm-700μm) and S2 (3cm-5cm) were used. The properties such as tensile properties (tensile strength, elongation at break, and stress at 100% elongation) and morphology studies were determined. The results indicated that the both size, S1 and S2 of recycled latex glove filled ENR 50 blends exhibited an increased in tensile strength and elongation at break for increasing weight ratio of RL-G. Scanning electron microscopy (SEM) of the fracture surfaces shows that the fine size, S1 RL-G/ENR50 exhibited high surface roughness and matrix tearing lines than the coarse size, S2 thus improving the compatibility of RL-G/ENR50 compounds. The results overall indicated that the fine size, S1of RL-G filled ENR50 contributed to the better properties such as tensile strength and surface morphology compared to the coarse size, S2 mainly at 15 phr of RL-G content.

Study on Cure Characteristics and Mechanical Behaviours of Kenaf Fibre Reinforced Natural Rubber Composites

2013 ◽  
Vol 812 ◽  
pp. 66-72 ◽  
Author(s):  
Mohd Zaini Nurul Aizan ◽  
Salim Abdul Salim Zainathul Akhmar ◽  
Ahmad Mohd Muhiddin ◽  
Zainudin Nor Hazwani ◽  
Jamil Siti Sarah
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Elongation At Break ◽  
Cure Characteristics ◽  
Kenaf Fibre ◽  
Roll Mill ◽  
Natural Rubber Composites ◽  
Cure Time ◽  
Mechanical Behaviours ◽  
Fibre Loading

In recent years, natural fibres appear to be as an outstanding material to substitute the conventional reinforcement materials in polymer composites. Kenaf fibre reinforced natural rubber (KFNR) composite was prepared by incorporating of different loadings of kenaf fibre using two roll mill machines. The compound was vulcanised at 150°C according to their respective cure time. The intention of this study is to investigate the influence of kenaf fibre on cure characteristics and mechanical bahaviour of (KFNR) composites.The result showed that the higher fibre content in composites led to shorter optimum cure time, t90. It was also observed that the tensile strength and elongation at break gradually decreased with an increment in fibre loadings. However, the trend was not similar for the hardness where the hardness value was increased by the increment of fibre loadings. The study has exhibited that the optimum fibre loading for the best performance of the composite achieved was 10 phr. The Scanning Electron Microscopy micrograph clarified that fibre dispersion and adhesion were weak thus resulting low in tensile strength and elongation at break.

Pengaruh penambahan natural rubber (NR), epoxidation natural rubber (ENR-46) dan chlorprene rubber (CR) pada sifat kompon termoplastik

2020 ◽  
Vol 26 (2) ◽  
pp. 62-69
Author(s):  
Farida Ali ◽  
Tuti I. Sari ◽  
Andi A. Siahaan ◽  
Al-Kautsar D. Arya ◽  
Tri Susanto
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Vinyl Chloride ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Nitrile Butadiene Rubber ◽  
Poly Vinyl Chloride

Penelitian ini untuk mengetahui pengaruh penambahan Natural Rubber (NR) dan Epoxidation Natural Rubber (ENR-46) dengan kompatibiliser Chlorprene Rubber (CR) pada aplikasi kompon termoplastik Poly Vinyl Chloride (PVC) dan Nitrile Butadiene Rubber (NBR), variabel penelitian meliputi ENR-46/PVC/NBR/CR, NR/PVC/NBR/CR dan CR-NR/PVC/NBR, CR-ENR-46/PVC/NBR. Parameter pengujian sifat fisik-mekanik : Hardness (Shore A), Tensile Strength (Mpa), Elongation at Break (%) dan ketahanan terhadap pelarut minyak (n-Pentane, Toluene, Hexane dan Pertalite). Hasil penelitian didapatkan untuk sifat fisik-mekanik, semakin banyak penambahan NR Kekerasan kompon termoplastik akan menurun, Tensile Strength dan Elongation at Break kompon akan meningkat begitu juga dengan CR-NR. Tetapi berbanding terbalik hasilnya untuk ENR-46 dan CR-ENR-46. Pengujian Ketahanan terhadap pelarut minyak semakin banyak penambahan ENR-46 Ketahanan kompon termoplastik terhadap pelarut akan meningkat, hasil yang sama juga pada CR-ENR-46. Tetapi berbanding terbalik hasilnya dengan penambahan NR dan CR-NR pada kompon termoplastik.

scholarly journals The effects of alkanolamide addition on cure characteristics, swelling behaviour and tensile properties of silica-filled natural rubber (NR) / chloroprene rubber (CR) blends

2018 ◽  
Vol 34 ◽  
pp. 01030 ◽  
Author(s):  
Indra Surya ◽  
Syahrul Fauzi Siregar ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Tensile Modulus ◽  
Palm Stearin ◽  
Swelling Behaviour ◽  
Elongation At Break ◽  
Cure Characteristics ◽  
Chloroprene Rubber

Effects of alkanolamide (ALK) addition on cure characteristics, swelling behaviour and tensile properties of silica-filled natural rubber (NR)/chloroprene rubber (CR) blends were investigated. The ALK was synthesized from Refined Bleached Deodorized Palm Stearin (RBDPS) and diethanolamine, and incorporated into the silica-filled NR/CR blends as a non-toxic rubber additive. The ALK loadings were 0.0, 1.0, 3.0, 5.0 and 7.0 phr. It was found that the ALK exhibited shorter scorch and cure times and higher elongation at break of the silica-filled NR/CR blends. The ALK also exhibited higher torque differences, tensile modulus and tensile strength at a 1.0 phr of ALK loading and then decreased with further increases in the ALK loading. The swelling measurement proved that the 1.0 phr loading of ALK caused the highest degree in crosslink density of the silica-filled NR/CR blends.

scholarly journals Evaluation of Maleated Polyethylene in Natural Rubber and Teline monspessulana Flour Composites

2020 ◽  
Author(s):  
Oscar Palacio ◽  
Emilio Delgado
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Coupling Agent ◽  
Tensile Testing ◽  
Process Analysis ◽  
Coupling Reaction ◽  
Molding Process ◽  
Elongation At Break ◽  
Content Determination ◽  
Two Factors

The effect of the addition of maleated polyethylene (MAPE) to compounds of natural rubber (NR) and Teline monspessulana flour (TMF) previously mercerized was investigated. Two factors were analyzed: A. concentration of MAPE with five levels 2; 4; 6; 8; 10 phr (parts per hundred rubber), B. concentration of TMF with two levels 25 and 40 phr. The effect of MAPE on compatibility between NR and HTM was evaluated by tensile testing the compounds. The mixing was performed in a laboratory scale mill. The test tubes were obtained by cutting or die-cutting crosslinked peroxide sheets, these were obtained during the compression molding process. Analysis indicate that the MAPE coupling agent improved the compatibility between HTM and NR, this effect was evidenced by the values of tensile strength and elongation at break. However, the gel content determination indicates that the addition of 10 phr of MAPE crosslinking decreases due to competition with coupling reaction MAPE - HTM.

scholarly journals Thermal, Morphological and Physic-Mechanical Properties of Natural Rubber - CaCO3 Composites Using Jatropha Oil as Softener.

2018 ◽  
Vol 156 ◽  
pp. 05016 ◽  
Author(s):  
Nasruddin ◽  
Tri Susanto
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Abrasion Resistance ◽  
Compositional Analysis ◽  
Critical Issue ◽  
Green Technology ◽  
Jatropha Oil ◽  
Rubber Composites ◽  
Elongation At Break ◽  
Natural Rubber Composites

The urgency of green technology in rubber compounding has become a critical issue recently. In this research, the effect of using renewable resources in rubber compounding has been studied. Commercial Calcium Carbonate, Silica and Jatropha Oil were used in natural rubber composite. The research was designed by varying the types of commercial filler namely CaCO3 (47-51) phr, silica (47-51) phr and Jatropha Oil (4-6) phr in natural rubber composites (SIR-20). The formulas were intentionally designed for rubber tips vulcanizates. The samples were characterized by the determination of physic-mechanical, thermal (TGA) and morphological (SEM) properties. From the measured results, there is no significant effect on the tensile strength, specific gravity, and hardness on the loading of commercial CaCO3 and Silica in natural rubber composites using Jatropha Oil. However, a slight difference in elongation at break and abrasion resistance could be detected. Compared to the commercial rubber tips, the rubber tips produced in this research have higher tensile strength, elongation at break and abrasion resistance. Due to the usage of commercial CaCO3 and Silica, the SEM micrographs show rough surface because of the agglomeration. The thermogram shows clearly the compositional analysis of the rubber tips vulcanizates consist of Jatropha Oil and natural rubber, CaCO3, ash and other filler residues such as Silica.

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