Gold coated iron oxide core shell nanostructures for oxidation of indoles and synthesis of uracil-derived spirooxindoles

Encapsulation of iron oxide (Fe3O4) based nanoparticles (NPs) with Au NPs hold promising scope for catalysis, which overcomes the hindrance of the inherent hydrophilic surface of iron species and facilitates...

Solution-phase decomposition of ferrocene into wüstite-iron oxide core-shell nanoparticles

We report an improved method for the controlled solvent-phase decomposition of ferrocene into highly crystalline monodisperse iron oxide nanoparticles at relatively low temperatures. Solution-phase decomposition of ferrocene into nanoparticles has...

Core-Shell Fe2O3@La1−xSrxFeO3−δ Material for Catalytic Oxidations: Coverage of Iron Oxide Core, Oxygen Storage Capacity and Reactivity of Surface Oxygens

A series of Fe2O3@LSF (La0.8Sr0.2FeO3−δ perovskite) core-shell materials (CSM) was prepared by infiltration of LSF precursors gel containing various complexants and their mixtures to nanocrystalline aggregates of hematite followed by thermal treatment. The content of LSF phase and amount of carboxyl groups in complexant determine the percent coverage of iron oxide core with the LSF shell. The most conformal coating core-shell material was prepared with citric acid as the complexant, contained 60 wt% LSF with 98% core coverage. The morphology of the CSM was studied by HRTEM-EELS combined with SEM-FIB for particles cross-sections. The reactivity of surface oxygen species and their amounts were determined by H2-TPR, TGA-DTG, the oxidation state of surface oxygen ions by XPS. It was found that at complete core coverage with perovskite shell, the distribution of surface oxygen species according to redox reactivity in CSM resemble pure LSF, but its lattice oxygen storage capacity is 2–2.5 times higher. At partial coverage, the distribution of surface oxygen species according to redox reactivity resembles that in iron oxide.

Dual-Functional Gold-Iron Oxide Core-Satellite Hybrid Nanoparticles for Sensitivity Enhancement in Biosensors via Nanoplasmonic and Preconcentration Effects

A common strategy to improve the sensitivity of a biosensor for detection of a low abundant analyte is to preconcentrate the analyte molecules before detection. A dual-functional gold-iron oxide core-satellite...