Operando XAS of a Bifunctional Gas Diffusion Electrode for Zn-Air Batteries under Realistic Application Conditions

In this study, operando X-ray absorption spectroscopy (XAS) measurements were carried out on a newly developed O2 bi-functional gas diffusion electrode (GDE) for rechargeable Zn-air batteries, consisting of a mixture of α-MnO2 and carbon black. The architecture and composition of the GDE, as well as the electrochemical cell, were designed to achieve optimum edge-jumps and signal-to-noise ratio in the absorption spectra for the Mn K-edge at current densities that are relevant for practical conditions. Herein, we reported the chemical changes that occur on the MnO2 component when the GDE is tested under normal operating conditions, during both battery discharge (ORR) and charge (OER), on the background of more critical conditions that simulate oxygen starvation in a flooded electrode.

Cu- and Fe-speciation in a composite zeolite catalyst for selective catalytic reduction of NOx: insights from operando XAS

Cu-SAPO-34 (Cu-CZC) and Fe-mordenite (Fe-MOR) and their mechanical mixture (50 : 50) have been exhaustively investigated by means of operando X-ray absorption spectroscopy under NH3-SCR conditions.

Incident-angle dependent operando XAS cell design: investigation of the electrochemical cells under operating conditions at various incidence angles

Bias and time-dependent changes in the oxidation state and the atomic environment of the atoms of a working electrode occur on the gas/electrode interface.