Igneous activity in central-southern Italy: Is the subduction paradigm still valid?

ABSTRACT The Pliocene–Quaternary igneous record of the Tyrrhenian Sea area features a surprisingly large range of compositions from subalkaline to ultra-alkaline and from ultrabasic to acid. These rocks, emplaced within the basin and along its margins, are characterized by strongly SiO2-undersaturated and CaO-rich to strongly SiO2-oversaturated and peraluminous compositions, with sodic to ultrapotassic alkaline and tholeiitic to calc-alkaline and high-K calc-alkaline affinities. We focused on the different models proposed to explain the famous Roman Comagmatic Region, part of the Quaternary volcanism that spreads along the eastern side of the Tyrrhenian area, in the stretched part of the Apennines thrust-and-fold belt. We reviewed data and hypotheses proposed in the literature that infer active to fossil subduction up to models that exclude subduction entirely. Many field geology observations sustain the interpretation that the evolution of the Tyrrhenian-Apennine system was related to subduction of the western margin of Adria continental lithosphere after minor recycling of oceanic lithosphere. However, the lateral extent of the subducting slab in the last millions of years, when magmatism flared up, remains debatable. The igneous activity that developed in the last millions of years along the Tyrrhenian margin is here explained as originating from a subduction-modified mantle, regardless of whether the large-scale subduction system is still active.

Middle−Late Triassic southward-younging granitoids: Tectonic transition from subduction to collision in the Eastern Tianshan−Beishan Orogen, NW China

To constrain the closure mechanism and time of the Paleo-Asian Ocean, we report new geochronological and geochemical data for Triassic granites along a NW−SE corridor from Eastern Tianshan to Beishan, NW China. Seven granites have U-Pb ages that young southwards from 245 Ma to 234 Ma in the Kanguer accretionary complex, to 237 Ma to 234 Ma in the eastern Central Tianshan block, to 229 Ma to 223 Ma in the Liuyuan accretionary complex. Granites in the Kanguer accretionary complex formed by fractional crystallization and are peraluminous, high-K, calc-alkaline, and crust-derived. They have very low MgO (Mg# = 6−9), Cr, and Ni contents, and their high εNd(t) (+3.40) and εHf(t) (+4.49 to +11.91) isotopes indicate that the Dananhu arc crust was juvenile. The Huaniushan pluton in the Liuyuan accretionary complex displays the geochemical signatures of both A1- and A2-type granites (Y/Nb = 0.32−3.39). All other granites in the Central Tianshan block and Liuyuan accretionary complex are aluminous A2-types with high K2O+Na2O, Al, rare earth elements (REE), Zr+Nb+Y, Ga, Fe/Mg, and Y/Nb and remarkable depletions of Eu, Ba, Nb, Ta, Sr, P, and Ti. They have a broad range of MgO (Mg# = 9−59), Cr, and Ni contents, Isr (0.70741−0.70945) values, negative εNd (t) (−2.98 to −1.14), and low to moderate εHf(t) (−1.22 to +7.78), which suggests a mixture of mantle and crustal components. These 245−223 Ma granitoids show marked Nb-Ta depletions that point to a subduction origin. Notable enrichments in Nd-Hf isotopes of Late Triassic granites are likely an indication of collision. Integration with previous data enables us to conclude that the delamination of an oceanic slab and mantle upwelling induced partial melting of thickened arc crust during a tectonic transition from a multiple supra-subduction margin to a collisional setting in the Late Triassic.

High Sulfur in Primitive Arc Magmas, Its Origin and Implications

Sulfur contents in 98.5% of melt inclusions (MI) from calc-alkaline subduction basalts do not exceed 4000 ppm, whereas experimentally established limits of sulfur solubility in basaltic melts with high fO2 (characteristic of subduction zones, e.g., QFM + 2) surpass 14,000 ppm. Here we show that primitive (Mg# 62-64) subduction melts may contain high sulfur, approaching the experimental limit of sulfur solubility. Up to 11,700 ppm S was measured in olivine-hosted MI from primitive arc basalt from the 1941 eruption of the Tolbachik volcano, Kamchatka. These MI often contain magmatic sulfide globules (occasionally enriched in Cu, Ni, and platinum-group elements) and anhydrite enclosed within a brown, oxidized glass. We conclude that the ubiquitous low sulfur contents in MI may originate either from insufficient availability of sulfur in the magma generation zone or early magma degassing prior to inclusion entrapment. Our findings extend the measured range of sulfur concentrations in primitive calc-alkaline basaltic melts and demonstrate that no fundamental limit of 4000 ppm S exists for relatively oxidized subduction basalts, where the maximum sulfur content may approach the solubility limit determined by crystallization of magmatic anhydrite.

The thermo-tectonic evolution of the Suckling-Dayman metamorphic core complex, southeastern Papua New Guinea

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present. The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith. A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula. Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma. A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma. Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>

The thermo-tectonic evolution of the Suckling-Dayman metamorphic core complex, southeastern Papua New Guinea

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present. The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith. A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula. Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma. A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma. Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>

The enriched Variscan lithosphere of NE Iberia: data from postcollisional Permian calc-alkaline lamprophyre dykes of Les Guilleries

Post-collisional mafic dykes crosscut the Paleozoic metamorphic basement and late-Variscan plutons in Les Guilleries massif (Catalan Coastal Ranges, NE Iberia). The predominance of mafic phenocrysts, porphyritic texture, abundant amphibole, high MgO and volatile content, together with crustal-like trace-element patterns indicate that the dykes correspond to calc-alkaline lamprophyres, mainly spessartites. Their enrichment in LILE, HFSE and REE and initial Sr-Nd isotopic compositions (87Sr/86Sri between 0.70851 and 0.71127, epsilon Ndi between -5.23 and -4.63) are consistent with an enriched subcontinental lithospheric mantle source. U-Pb ages of matrix titanite crystals yield concordia ages of 262±7Ma, congruent with crosscutting relationships. Postmagmatic processes are evidenced by intense chloritization and albitization of the lamprophyres, together with systematic variations of Na2O vs SiO2, K2O, CaO, Ba, Rb, Cs, Pb, Sr, Tl, and Zn, and possibly the removal of F. The geochemical and geochronological data support an orogenic geochemical affinity, in accordance with the transitional tectonic regime between Variscan compression/transpression and post-collisional transtension/extension, related to the fragmentation of Pangea and thinning of the lithosphere. The lamprophyre dykes studied could represent the youngest pulse of Variscan orogenic magmatism and, therefore, mark its end in NE Iberia before the onset of the generalized Triassic extension.

Polybaric fractional crystallisation of arc magmas: an experimental study simulating trans-crustal magmatic systems

Crystallisation-driven differentiation is one fundamental mechanism proposed to control the compositional evolution of magmas. In this experimental study, we simulated polybaric fractional crystallisation of mantle-derived arc magmas. Various pressure–temperature trajectories were explored to cover a range of potential magma ascent paths and to investigate the role of decompression on phase equilibria and liquid lines of descent (LLD). Fractional crystallisation was approached in a step-wise manner by repetitively synthesising new starting materials chemically corresponding to liquids formed in previous runs. Experiments were performed at temperatures ranging from 1140 to 870 °C with 30 °C steps, and pressure was varied between 0.8 and 0.2 GPa with 0.2 GPa steps. For most fractionation paths, oxygen fugacity (fO2) was buffered close to the Ni-NiO equilibrium (NNO). An additional fractionation series was conducted at fO2 corresponding to the Re-ReO2 buffer (RRO ≈ NNO+2). High-pressure experiments (0.4–0.8 GPa) were run in piston cylinder apparatus while 0.2 GPa runs were conducted in externally heated pressure vessels. Resulting liquid lines of descent follow calc-alkaline differentiation trends where the onset of pronounced silica enrichment coincides with the saturation of amphibole and/or Fe–Ti–oxide. Both pressure and fO2 exert crucial control on the stability fields of olivine, pyroxene, amphibole, plagioclase, and Fe–Ti–oxide phases and on the differentiation behaviour of arc magmas. Key observations are a shift of the olivine–clinopyroxene cotectic towards more clinopyroxene-rich liquid composition, an expansion of the plagioclase stability field and a decrease of amphibole stability with decreasing pressure. Decompression-dominated ascent trajectories result in liquid lines of descent approaching the metaluminous compositional range observed for typical arc volcanic rocks, while differentiation trends obtained for cooling-dominated trajectories evolve to peraluminous compositions, similar to isobaric liquid lines of descent at elevated pressures. Experiments buffered at RRO provide a closer match with natural calc-alkaline differentiation trends compared to fO2 conditions close to NNO. We conclude that decompression-dominated fractionation at oxidising conditions represents one possible scenario for arc magma differentiation.