Fluorescence Recognition of Anions Using a Heteroditopic Receptor: Homogenous and Two-Phase Sensing

In contrast to monotopic receptor 3, the anthracene functionalized squaramide dual-host receptor 1 is capable of selectively extracting sulfate salts, as was evidenced unambiguously by DOSY, mass spectrometry, fluorescent and ion chromatography measurements. The receptors were investigated in terms of anion and ion pair binding using the UV–vis and 1H NMR titrations method in acetonitrile. The reference anion receptor 3, lacking a crown ether unit, was found to lose the enhancement in anion binding induced by the presence of cations. Besides the ability to bind anions in an enhanced manner exhibited by ion pair receptors 2 and 4, changing the 1-aminoanthracene substituent resulted in their exhibiting a lower anion affinity than receptor 1. By using receptor 1 and adjusting the water content in organic phase it was possible to selectively detect sulfates both by “turn-off” and “turn-on” fluorescence, and to do so homogenously and under interfacial conditions. Such properties of receptor 1 have allowed the development of a new type of sensor capable of recognizing and extracting potassium sulfate from the aqueous medium across a phase boundary, resulting in an appropriate fluorescent response in the organic solution.

Shape and Size Control of Bimetallic PtX (X = Au, Ni, Sn) Nanoparticles

<p>Nanoparticles show interesting and novel properties compared to their bulk materials. These properties range from optical, magnetic, electronic to catalytic and can be influenced by shape, size and elemental composition. As the ability to control nanoparticle morphology is important in materials science these particles are actively researched. Moreover, by combining different metals multiple properties intrinsic to those elements can be accessed within a single system. This thesis describes general synthetic approaches and underlying theory in the formation of nanoparticles. Focusing on organic solution phase synthesis, pathways to control both size and shape of nanoparticles are discussed. The concept behind the formation and possible structures of bimetallic nanoparticles are explained. Additionally, a brief overview about used characterisation techniques such as transmission electron microscopy and x-ray diffraction are given. Metallic nanoparticles were formed using the organic solution phase synthesis within Fischer-Porter bottles. Elevated temperatures and the presence of hydrogen lead to thermal decomposition of the metallic precursor, reduction of formed metal ions and subsequent build-up of nanoparticles. For bimetallic nanoparticles the seed mediated growth technique is commonly used. By utilizing this technique bimetallic AuPt nanoparticles were formed. The impact of different surfactants, hydrogen pressure, precursors and reaction time upon the size, elemental composition and morphology of these bimetallic AuPt nanoparticles is investigated. The bimetallic structure is evaluated and experiments to control the growth of platinum onto the seed structures are conducted. Further research deals with the formation of hexagonal close packed (hcp) nickel nanoparticles. By altering the surfactant type and concentration nickel favours to crystallise in its hcp modification rather than its most common face-centred cubic (fcc) phase. It was found that nickel packing in this hcp crystal system is forming hourglass-shaped nanoparticles. These particles are further used in seed mediated growth experiments with a platinum precursor to achieve bimetallic nanoparticles to both exploit the catalytic activity of platinum as well as the magnetic moment of nickel. It is shown that the choice of reaction conditions is crucial to achieve growth onto the nickel surface. Moreover, it was found that these nanoparticles are only selectively coated by platinum on hcp {001} facets leading to exposure of both nickel and platinum surfaces. The key results are summarised and the exploited parameters evaluated. Also, perspectives for future research are discussed and a brief outlook for the application of the investigated bimetallic systems is given. Bimetallic tin-platinum nanoparticles were formed by coreduction of the respective tin and platinum containing metal precursors. Several metal sources for both tin and platinum were investigated upon their decomposition and the resulting nanoparticle shape and elemental composition. The formation of a bimetallic precursor containing a Pt-Sn bond is discussed. Further reaction parameters such as temperature and time are also investigated to eludicate their impact on the formed nanoparticles. Finally, the key results are summarised and the exploited parameters evaluated. Also, perspectives for future research are discussed and a brief outlook for the application of the investigated bimetallic systems is given. The discussion in Chapter 4 about selectively obtaining hcp Ni nanoparticles is shortened and a major focus is given on the platinum coating of these hourglass-shaped nanoparticles, as Lee et al. published a paper on "Shaped Ni nanoparticles with an unconventional hcp crystalline structure" (Chemical Communications, 2014, 50, 6353-6356) during the course of these studies, describing similar methods and findings as observed in this research.</p>

Shape and Size Control of Bimetallic PtX (X = Au, Ni, Sn) Nanoparticles

<p>Nanoparticles show interesting and novel properties compared to their bulk materials. These properties range from optical, magnetic, electronic to catalytic and can be influenced by shape, size and elemental composition. As the ability to control nanoparticle morphology is important in materials science these particles are actively researched. Moreover, by combining different metals multiple properties intrinsic to those elements can be accessed within a single system. This thesis describes general synthetic approaches and underlying theory in the formation of nanoparticles. Focusing on organic solution phase synthesis, pathways to control both size and shape of nanoparticles are discussed. The concept behind the formation and possible structures of bimetallic nanoparticles are explained. Additionally, a brief overview about used characterisation techniques such as transmission electron microscopy and x-ray diffraction are given. Metallic nanoparticles were formed using the organic solution phase synthesis within Fischer-Porter bottles. Elevated temperatures and the presence of hydrogen lead to thermal decomposition of the metallic precursor, reduction of formed metal ions and subsequent build-up of nanoparticles. For bimetallic nanoparticles the seed mediated growth technique is commonly used. By utilizing this technique bimetallic AuPt nanoparticles were formed. The impact of different surfactants, hydrogen pressure, precursors and reaction time upon the size, elemental composition and morphology of these bimetallic AuPt nanoparticles is investigated. The bimetallic structure is evaluated and experiments to control the growth of platinum onto the seed structures are conducted. Further research deals with the formation of hexagonal close packed (hcp) nickel nanoparticles. By altering the surfactant type and concentration nickel favours to crystallise in its hcp modification rather than its most common face-centred cubic (fcc) phase. It was found that nickel packing in this hcp crystal system is forming hourglass-shaped nanoparticles. These particles are further used in seed mediated growth experiments with a platinum precursor to achieve bimetallic nanoparticles to both exploit the catalytic activity of platinum as well as the magnetic moment of nickel. It is shown that the choice of reaction conditions is crucial to achieve growth onto the nickel surface. Moreover, it was found that these nanoparticles are only selectively coated by platinum on hcp {001} facets leading to exposure of both nickel and platinum surfaces. The key results are summarised and the exploited parameters evaluated. Also, perspectives for future research are discussed and a brief outlook for the application of the investigated bimetallic systems is given. Bimetallic tin-platinum nanoparticles were formed by coreduction of the respective tin and platinum containing metal precursors. Several metal sources for both tin and platinum were investigated upon their decomposition and the resulting nanoparticle shape and elemental composition. The formation of a bimetallic precursor containing a Pt-Sn bond is discussed. Further reaction parameters such as temperature and time are also investigated to eludicate their impact on the formed nanoparticles. Finally, the key results are summarised and the exploited parameters evaluated. Also, perspectives for future research are discussed and a brief outlook for the application of the investigated bimetallic systems is given. The discussion in Chapter 4 about selectively obtaining hcp Ni nanoparticles is shortened and a major focus is given on the platinum coating of these hourglass-shaped nanoparticles, as Lee et al. published a paper on "Shaped Ni nanoparticles with an unconventional hcp crystalline structure" (Chemical Communications, 2014, 50, 6353-6356) during the course of these studies, describing similar methods and findings as observed in this research.</p>

CRISPR-Cas9 and Food in the European Union: An Organic Solution to an Undetectable Problem for Food Business Operators

Various methods of genetic modification have been applied to plant breeding as an integral part of agriculture. This article examines a method of targeted mutagenesis – CRISPR-Cas9 – and its dysregulation in the European Union (EU). It provides clarity for food business operators relating to the traceability and labelling of food products induced using this biotechnology. In addition, it outlines policy recommendations to improve the regulation of such food products in the EU.

POTENSI BEBERAPA LARUTAN ORGANIK DALAM MENDUKUNG PRODUKSI BAWANG MERAH (Allium ascalonicum)

Red unions are one type of plant that is widely used as a spice ini cooking and cannot be replaced with other types of plants so it is needed every time. The research objective was to obtain one type of organic solution that produced the highest production of shallots and to calculate the potential production of each given organic solution. The research was carried out at the Kebun Percontohan Balai Penyuluhan Pertanian Bulango Timur in January-April 2020. The research was conducted in the form of Randomized Bloc design consisting of 8 treatments including control namely without the use of organic solutions, POC, MOL Rice, MOL Banana, ZPT red union, ZPT Tauge, PGPR Root Bamboo and PGPR Elephan Grass Root. Repeat 3 times with a plot size 1 m x 1 m. The parameters observed were fresh weight and dry weight of red union bulbs. The results showed that the highest fresh weight was obtained from the treatment of ZPT red union 14,22 ton haˉ¹) and MOL banana (14,06 ton haˉ¹). The highest dry weight of bulbs resulted from the MOL treatment of banana (9,93 ton haˉ¹) and ZPT red union (9,87 ton haˉ¹).

Are the Enrichment Nutrient Feasible to the Vermicomposting Efficiency For Water Hyacinth (E. Crassipes)?

In eutrophic environments, aquatic weeds reproduce quickly and occupy large areas, preventing multiple uses of water resources. The use of the biomass of these plants in vermicomposting represents a sustainable alternative. The enrichment of macrophyte biomass during vermicomposting was tested using inorganic NPK solution (1.75% and 3.5%) and organic solution (0.25 g/L and 0.5 g/L) to improve the quality of the compound. Biomass consumption increased as the experiment progressed, reaching the highest values at the end. The experiment without worms remained stable. The influence of E. fetida individuals the vermicomposting process of water hyacinth will depend nutrient addition. The additions improved subtly the compost quality and the consumption of biomass, besides its low-cost, easily obtained and applicable treatment. It does not have the necessary requirements for its use as a fertilizer. However, we suggest the use in association with other fertilizers, adding moisture and structuring to the soil.

The Effect of Spraying Rocket Plant Extract and Ground Addition of Organic Nutrient (Karma maxi org) on The Growth and Production of Cabbage

The experiment was carried out in open field of the research station at College of Agriculture / University of Diyala during two seasons 2018 and 2019. The aim of the study is to investigate the effect of foliar spraying with water extract of Rocket at three concentrations of 0, 50,, and 100% in and ground addition of Organic solution at three concentrations 0, 15, 20 ml. L-1 in. The Randomized Complete Block Design was used with three replicates. The results showed that spraying water extract of Rocket was superior in 100%. It was found that the highest values in stem height, number of external leaves, head diameter and head weight, and total yield for both seasons 13.36 cm, 12.57 leaf, 14.94 cm, 1.302 kg. plant-1 and 43.417 tons. H -1 For the first season, 10.92 cm, 12.64 leaves, 15.26 cm, 1.308 kg. Plant-1 and 43.618 tons. H-1) for the second season. Also, the ground addition of solution was superior at 20 ml. L-1 in all studied traits. They did not differ significantly from the 15ml.L-1 concentration. However, they differ significantly from the control treatment, which gave the lowest values for all traits and both seasons. As for the treatment of interaction which was (20 ml.L-1 and 100% of Rocket extract), it exceeded all treatments and for both seasons.were recorded 13.42 cm, 12.88 leaf, 15.77 cm, 1.351 kg. Plant-1 and 45.028 tons. H-1 for the first season, as well as 11.03 cm, 13.01 leaf, 15.80 cm, 1.383 kg. plant-1 and 46.096 tons. H-1 for the second season.