Genesis of Megacrystalline Uraninite: A Case Study of the Haita Area of the Western Margin of the Yangtze Block, China

Megacrystalline uraninite (up to one centimeter in size) represents one of the most important discoveries in uranium mineralogy in the western margin of the Yangtze Block and even in China in recent years. However, the genesis of megacrystalline uraninite remains controversial. In this study, the megacrystalline uraninite found in the felsic and quartz veins in the Haita area is examined for the first time. The study examined the geochemical characteristics of uraninite in the two veins and resulted in two primary findings. (1) The genesis of the uraninite was likely intrusive and was closely related to partial melting. (2) The quartz vein and feldspar vein are cogenetic and have a simple differentiation evolution relationship. Therefore, the partial melting of felsic materials during migmatization may be the most important mechanism of uranium mineralization in the study area. Furthermore, further simple fractional crystallization may be another important mechanism for the formation of megacrystalline uraninite. This study enriches the REE database of uraninite in uranium deposits worldwide, which is meaningful for studying the genesis of megacrystalline uraninite.

Study of the Behavior of Gold and Accompanying Chemical Elements in Weathering Profile on a Quartz Vein in Mintom (South Cameroon, Central Africa)

The present study, which focuses on the behavior of gold and its accompanying chemical elements developed on an alteration profile, is carried out in a humid equatorial zone at Mintom in South Cameroon (Central Africa). The methodology used to achieve the results obtained focused on the description of the morphology of the outcrop, the petrography of the rock studied, the study of heavy minerals accompanying gold in the weathering materials on smear slides, mineralogical analysis of weathering materials by X-ray diffraction (XRD), scanning electron microscopy (SEM) analysis of gold and geochemical analyzes by ICP - AES and ICP - MS of weathering materials. The main results obtained from this methodology inform us that on the petrographic level the main rock studied is the gold-bearing quartz vein located in Zom, consisting mainly of quartz and opaque minerals. Morphologically, the weathering materials developed on this granite basement present an advanced ABC-type profile characterized by a significant thickness (4 to 6 m). The morphological and chemical characters of the gold particles have evolved from the mineralized zone to the surface. This development was marked by an increase in blunt, rounded grains. Morphoscopy and scanning electron microscopy of the gold particles have shown hollow, blunt to sub-blunt grains, non-evolved free particles, and evolved free particles, respectively. In most samples of weathered material gold is found in association with chemical elements such as Ag, Cr, Co, Cu, Ni, V and figure 10 show identical behavior between these chemical elements and gold, but particularly between silver and gold, which would testify to an identical origin. Au concentrations are very high in most samples of weathering material. Also, these samples of altered materials with a high proportion of gold (0.01 to 2.28 ppm) also present high concentrations of silver (Ag) which justifies that the occurrence or the gold deposit is associated with silver and can be exploited as a geochemical parameter to prospect for gold in the study area.

Temporal changes in pore fluid pressure during slow earthquake cycle estimated from foliation-parallel extension cracking

<p>Pore fluid pressure (P<sub>f</sub>) is of great importance to understand slow earthquake mechanics. In this study, we estimated the pore fluid pressure during the formation of foliation-parallel quartz veins filling mode I cracks in the Makimine mélange eastern Kyushu, SW Japan. The mélange preserves quartz-filled shear veins, foliation-parallel extension veins and subvertical extension tension vein arrays. The coexistence of the crack-seal veins and viscously sheared veins (aperture width of a quartz vein: a few tens of microns) may represent episodic tremor and slow slip (Ujiie et al., 2018). The foliation-parallel extension cracks can function as the fluid pathway in the mélange. We applied the stress tensor inversion approach proposed by Sato et al. (2013) to estimate stress regimes by using foliation-parallel extension vein orientations. The estimated stress is a reverse faulting stress regime with a sub-horizontal σ<sub>1</sub>-axis trending NNW–SSE and a sub-vertical σ<sub>3</sub>-axis, and the driving pore fluid pressure ratio P* (P* = (P<sub>f</sub> – σ<sub>3</sub>) / (σ<sub>1</sub> – σ<sub>3</sub>)) is ~0.1. When the pore fluid pressure exceeds σ<sub>3</sub>, veins filling mode I cracks are constructed (Jolly and Sanderson, 1997). The pore fluid pressure that exceeds σ<sub>3</sub> is the pore fluid overpressure ΔP<sub>f</sub> (ΔP<sub>f</sub> = P<sub>f</sub> – σ<sub>3</sub>). To estimate the pore fluid overpressure, we used the poro-elastic model for extension quartz vein formation (Gudmundsson, 1999). P<sub>f</sub> and ΔP<sub>f</sub> in the case of the Makimine mélange are ~280 MPa and 80–160 kPa (assuming depth = 10 km, density = 2800 kg/m<sup>3</sup>, tensile strength = 1 MPa and Young’s modulus = 7.5–15 GPa). When the pore fluid overpressure is released, the cracks are closed and the reduction of pore fluid pressure is stopped (Otsubo et al., 2020). After the pore fluid overpressure is reduced, the normalized pore pressure ratio λ* (λ* = (P<sub>f</sub> – P<sub>h</sub>) / (P<sub>l</sub> – P<sub>h</sub>), P<sub>l</sub>: lithostatic pressure; P<sub>h</sub>: hydrostatic pressure) is ~1.01 (P<sub>f</sub> > P<sub>l</sub>). The results indicate that the pore fluid pressure constantly maintains the lithostatic pressure during the extension cracking along the foliation.</p><p>References: Gudmundsson (1999) Geophys. Res. Lett., 26, 115–118; Jolly and Sanderson (1997) Jour. Struct. Geol., 19, 887–892; Otsubo et al. (2020) Sci. Rep., 10:12281; Palazzin et al. (2016) Tectonophysics, 687, 28–43; Sato et al. (2013) Tectonophysics, 588, 69–81; Ujiie et al. (2018) Geophys. Res. Lett., 45, 5371–5379, https://doi.org/10.1029/2018GL078374.</p>

The genesis of gold in Sb-As and Sb-Au ore veins, new constraints from the study of the La Bellière and La Lucette districts (Armorican Massif, France)

<p>Shear zones hosted antimony (Sb) quartz vein-type deposits are the most important sources of Sb worldwide. They have been recognized and mined since the Antiquity in the European Variscan belt, and particularly in the French Variscan Massifs, as the Armorican Massif. Among this type of deposit two subtypes are identified, i) the Sb and gold (Au) quartz vein-type (Sb-Au) as the La Lucette deposit located in the North Armorican Domain, and ii) the Sb-As quartz vein-type as those from the la Bellière district in the Ligerian domain.</p><p>The recent advances in the understanding of the Sb mineralizations in the European Variscan Belt are typically focused on the Sb ore-genesis and its regional implications, ignoring its potential valuable co-products as gold. In this study, detailed textural-mineralogical investigations coupled with geochemical analyses in rock-samples with in-situ EPMA and LA-ICPMS ore-minerals trace element analyses, were carried out for the first time in the Late-Variscan mineralizations from the La Bellière Sb-As occurrences, and the La Lucette Sb-Au deposit, to ascertain the distribution and amount of Au in the ore-minerals and provide new data on ore deposition conditions.</p><p>In the La Bellière Sb-As occurrences, no visible gold has been observed, but low-grade gold, ranging between 0.2 to 1 g/t Au, are correlated with high-grade As in rock sample. In the La Lucette Sb-Au deposit, historical assays have shown high-grade gold with an average at 40 g/t Au. EPMA and LA-ICP-MS analyses have demonstrated that gold is already present during the early time of the mineralization as invisible gold, trapped in the lattice of the Sb-rich arsenopyrites, with an average grade of 70 ppm Au in La Bellière, and at higher average grade of 223 ppm Au for La Lucette. For both type of mineralization, the early invisible gold is concentrated preferentially in the borders of the arsenopyrite crystals, and is correlated with an increase of the As content, and a decrease of the Sb and Fe. We argue that gold could be added in the arsenopyrite by substitution with the Fe and Sb at high temperature > 300 °C.</p><p>Visible gold corresponds to the economic gold ore of the Sb-Au mineralizations. In the La Lucette ore, it is emplaced in the late stages, as discrete electrum grains spatially associated with the arsenopyrites, as native gold inclusions within the stibnite, and associated with rare aurostibite. Remobilization processes of the gold-bearing arsenopyrite at lower temperature, coupled with a minor initial enrichment of the Sb-bearing ore-fluid might be responsible of the late high-grade gold ore, and the visible expression of this element. In the absence of such remobilization process with late ore-fluid-enrichment, only low-grade gold is present, under the form of invisible gold in auriferous-arsenopyrites.</p><p>The presence of a valuable gold co-product, also present in the Sb-As mineralizations, unknown until now in the French Variscan Massifs, will improve its economic attractivity. Gold potential in the huge French Sb-districts as the Vendée or the Brioude-Massiac districts must be reassessed.</p>