Leveraging bipolar effect to enhance transverse thermoelectricity in semimetal Mg2Pb for cryogenic heat pumping

Toward high-performance thermoelectric energy conversion, the electrons and holes must work jointly like two wheels of a cart: if not longitudinally, then transversely. The bipolar effect — the main performance restriction in the traditional longitudinal thermoelectricity, can be manipulated to be a performance enhancer in the transverse thermoelectricity. Here, we demonstrate this idea in semimetal Mg2Pb. At 30 K, a giant transverse thermoelectric power factor as high as 400 μWcm−1K−2 is achieved, a 3 orders-of-magnitude enhancement than the longitudinal configuration. The resultant specific heat pumping power is ~ 1 Wg−1, higher than those of existing techniques at 10~100 K. A large number of semimetals and narrow-gap semiconductors making poor longitudinal thermoelectrics due to severe bipolar effect are thus revived to fill the conspicuous gap of thermoelectric materials for solid-state applications.

Design and Thermodynamic Analysis of Waste Heat-Driven Zeolite–Water Continuous-Adsorption Refrigeration and Heat Pump System for Ships

Strict International Maritime Organization (IMO) rules enable ships to maximize fuel consumption and compliance with the climate. Cooling and heat-pumping technology powered by waste heat makes a substantial contribution to lowering ship gas emissions. This study explores, technically studies, and thermodynamically analyzes the efficiency of ongoing adsorption refrigeration and heating systems using a zeolite–water pair onboard a naval surface ship. An updated Dubin-in-Astakhov equation calculates the equilibrium adsorption potential of the operating pair used in the system. The coefficient of performance (COP) and specific cooling power (SCP)/specific heating power (SHP) values were between 0.109 and 0.384 and between 69.13 and 193.58 W kg−1 for cooling mode, and between 66.16 and 185.26 W kg−1 based on exhaust gas temperature and regeneration, respectively. Up to 27.64% and 52.91% met the cooling and heating load of the case vessel at a full load by the zeolite–water-adsorbed refrigeration/heat-pumping system. The COP of the heat pump and cooling systems was compared to that of adsorption cooling/heat pumps in the literature.

Is Barocaloric an Eco-Friendly Technology? A TEWI Comparison with Vapor Compression under Different Operation Modes

Barocaloric is a solid-state not-in-kind technology, for cooling and heat pumping, rising as an alternative to the vapor compression systems. The former is based on solid-state refrigerants and the latter on fluid ones. The reference thermodynamical cycle is called active barocaloric regenerative refrigeration (or heat pumping cycle). The main advantage of this technology is to not employ greenhouse gases, which can be toxic or damaging for the environment and that can contribute to increasing global warming. In this paper, the environmental impact of barocaloric technology was evaluated through a Total Equivalent Warming Impact (TEWI) analysis carried out with the help of a numerical 2D model solved through a finite element method. Specifically, we propose a wide investigation on the environmental impact of barocaloric technology in terms of TEWI index, also making a comparison with a vapor compression plant. The analysis focuses on both the cooling and heat pump operation modes, under different working conditions and auxiliary fluids. The results revealed that a barocaloric system based on ABR cycle could provide a reduction of the environmental impact with respect to a vapor compression system. The addition of nanofluids contributes in reducing the environmental impact up to –62%.