Instrumental Methods for Cage Occupancy Estimation of Gas Hydrate

Studies revealed that gas hydrate cages, especially small cages, are incompletely filled with guest gas molecules, primarily associated with pressure and gas composition. The ratio of hydrate cages occupied by guest molecules, defined as cage occupancy, is a critical parameter to estimate the resource amount of a natural gas hydrate reservoir and evaluate the storage capacity of methane or hydrogen hydrate as an energy storage medium and carbon dioxide hydrate as a carbon sequestration matrix. As the result, methods have been developed to investigate the cage occupancy of gas hydrate. In this review, several instrument methods widely applied for gas hydrate analysis are introduced, including Raman, NMR, XRD, neutron diffraction, and the approaches to estimate cage occupancy are summarized.

A Solution to Sand Production from Natural Gas Hydrate Deposits with Radial Wells: Combined Gravel Packing and Sand Screen

Sand production is one of the main problems restricting the safe, efficient and sustainable exploitation of marine natural gas hydrate. To explore the sand-control effects of gravel packing, experiments that simulate hydrate extraction in the water-rich environment were conducted with designed hydrate synthesis and exploitation devices. Three sand control completion methods, including 120 mesh sand screen, 400 mesh sand screen, 120 mesh sand screen combined with gravel packing, are adopted. Sand and gas production rates were compared under different well types and sand control completion methods. Results show that the gas production modes of radial wells and vertical wells are almost the same at the same time due to the small experimental scale and high permeability. The sand production of the vertical well with gravel packing combined with a sand-control screen is 50% lower than that of the vertical well with sand-control screens only. Radial well with gravel packing combined with sand-control screens produced 87% less sand than screen mesh alone. The cumulative gas production and recovery rates of a radial well with the composite sand control method are better than those without gravel packing in the same development time.