Symmetrization and Amplification of Germicidal Radiation Flux Produced by a Mercury Amalgam UV Lamp in Cylindrical Cavity with Diffusely Reflective Walls

The study focused on increasing the efficiency of germicidal UV radiation by using highly diffuse reflective materials such as PTFE in irradiated cavities of UV air purifiers. In a conventional cylindrically symmetric cavity with a linear amalgam mercury lamp as UV-radiation source on the axis UV-radiation, flux directed from the lamp to the walls dropped from the axis to the periphery. To increase the UV irradiation, the walls are often made mirror-reflective, but the radiation flux distribution remained radially symmetric with a maximum on the source emitting surface in this case as well. When most of the emitted light is returned to the source after one reflection, the conditions of its operation are disturbed. If the walls are made of highly diffuse reflective materials, the radiation flux density inside the cavity increases on average, and its distribution becomes uniform and highly symmetric. Thus, the effect of amplification of the radiation flux due to the highly diffuse reflectivity of the walls increases with radius and reaches a maximum at the wall. Experiments were performed to demonstrate increasing amplification of germicidal UV radiation flux with a diffuse reflection coefficient in cylindrical cavities with walls of PTFE and ePTFE. The irradiation of the cavity wall was observed to increase up to 20 times at the resonant mercury line of 253.7 nm and up to 40 times at some non-resonant lines of the visible range due to highly diffuse reflectivity of the cavity walls. The flux amplification effect was limited by the diffuse reflectivity value of the walls and absorption coefficient of the radiation emitting surface. A formula for calculating the radiation flux amplification factor in a diffusely reflecting cylindrically symmetric cavity was derived for the case of Lambertian source and reflector, including wall reflectivity and source surface absorption coefficients. The effects of heating and cooling of the mercury lamp amalgam directly affected the amplification, and symmetrization of germicidal irradiation was observed and is discussed in the paper. Numerical calculations were performed by the ray tracing method. The calculated model was verified by comparing the numerical results with those of both the approximate theoretical consideration and experiments. The promising use of diffusely reflecting cylindrical cavities for UV air purifiers is discussed. Designs of air inlet and outlet ports that allow effective locking of germicidal radiation inside the UV air purifiers were considered. The results of this work may be of interest for further developments in the UV disinfection technique.

Influence of Aluminium and Autoclaving Temperature on the Properties of Autoclaved Aerated Concrete

Autoclaved aerated concrete (AAC) prepared by the mixing of ordinary Portland cement, lime powder, sand, aluminium powder and water. This study covers the variation of physical, mechanical and functional properties of autoclaved aerated concrete with autoclaving temperature and aluminium content and compared with that of normal weight cement mortar sample. In this work, two dosage of aluminium content of 0.4% and 0.8% of the dry weight of ordinary Portland cement and three different autoclaving temperature of 160oC, 180oC and 200oC were used. AAC sample with 0.8% aluminium and 160oC temperature had unit weight of 1490kg/m3 which was lowest among all samples including the control or normal weight cement blocks. Weight reduction of AAC sample was 31.53%. AAC sample with 0.4% aluminium and 200oC autoclaving temperature gave maximum compressive and tensile strength of 19.4MPa and 1.81MPa respectively which were close to that of normal weight concrete and strength of AAC increased with autoclaving temperature and decreased with aluminium content. In this research, the functional propertiesof AAC, absorption capacity was much higher than normal weight concrete and this capacity was increased with aluminium content and with decreasing autoclaving temperature and unit weight of AAC. For AAC with 0.8% aluminium and 160oC temperature gave maximum water absorption capacity (=9.93%). Again, surface absorption rate was higher for first 12hours and with time it would be constant because of its saturated position. Journal of Engineering Science 12(3), 2021, 11-17

Adsorption of dye molecules on metallic nanoparticles: Unraveling the origins of the modified spectral absorption

<p>The enhanced optical response of molecules in the vicinity of metallic nanoparticle is the basis for many surface enhanced spectroscopies and of interest to the field of plasmonics. However, the mechanisms behind the enhancement are still a matter of debate because of the interplay between electromagnetic and chemical effects, which complicates the interpretation of spectral changes. Our ability to measure the surface absorption of dyes from very low coverage to high coverage allows us to identify the con- tribution of each effect (dye-dye interaction and dye-particle interaction) to the spectral modifications. In the course of this investigation, we also measured the adsorption isotherms of dyes in the presence of halide ions, which provides a detailed insight into the adsorption process on silver colloids.</p>

Adsorption of dye molecules on metallic nanoparticles: Unraveling the origins of the modified spectral absorption

<p>The enhanced optical response of molecules in the vicinity of metallic nanoparticle is the basis for many surface enhanced spectroscopies and of interest to the field of plasmonics. However, the mechanisms behind the enhancement are still a matter of debate because of the interplay between electromagnetic and chemical effects, which complicates the interpretation of spectral changes. Our ability to measure the surface absorption of dyes from very low coverage to high coverage allows us to identify the con- tribution of each effect (dye-dye interaction and dye-particle interaction) to the spectral modifications. In the course of this investigation, we also measured the adsorption isotherms of dyes in the presence of halide ions, which provides a detailed insight into the adsorption process on silver colloids.</p>

Electrostatic Field Enhanced Photocatalytic CO2 Conversion on BiVO4 Nanowires

The recombination loss of photo-carriers in photocatalytic systems fatally determines the energy conversion efficiency of photocatalysts. In this work, an electrostatic field was used to inhibit the recombination of photo-carriers in photocatalysts by separating photo-holes and photo-electrons in space. As a model structure, (010) facet-exposed BiVO4 nanowires were grown on PDMS-insulated piezo-substrate of piezoelectric transducer (PZT). The PZT substrate will generate an electrostatic field under a certain stress, and the photocatalytic behavior of BiVO4 nanowires is influenced by the electrostatic field. Our results showed that the photocatalytic performance of the BiVO4 nanowires in CO2 reduction in the negative electrostatic field is enhanced to 5.5-fold of that without electrostatic field. Moreover, the concentration of methane in the products was raised from 29% to 64%. The enhanced CO2 reduction efficiency is mainly attributed to the inhibited recombination loss of photo-carriers in the BiVO4 nanowires. The increased energy of photo-carriers and the enhanced surface absorption to polar molecules, which are CO in this case, were also play important roles in improving the photocatalytic activity of the photocatalyst and product selectivity. This work proposed an effective strategy to improve photo-carriers separation/transfer dynamics in the photocatalytic systems, which will also be a favorable reference for photovoltaic and photodetecting devices.

Extra-Low Dosage Graphene Oxide Cementitious Nanocomposites: A Nano- to Macroscale Approach

The impact of extra-low dosage (0.01% by weight of cement) Graphene Oxide (GO) on the properties of fresh and hardened nanocomposites was assessed. The use of a minimum amount of 2-D nanofiller would minimize costs and sustainability issues, therefore encouraging the market uptake of nanoengineered cement-based materials. GO was characterized by X-ray Photoelectron Spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), Atomic Force Microscopy (AFM), X-ray Diffraction (XRD), and Raman spectroscopy. GO consisted of stacked sheets up to 600 nm × 800 nm wide and 2 nm thick, oxygen content 31 at%. The impact of GO on the fresh admixtures was evaluated by rheology, flowability, and workability measurements. GO-modified samples were characterized by density measurements, Scanning Electron Microscopy (SEM) analysis, and compression and bending tests. Permeability was investigated using the boiling-water saturation technique, salt ponding test, and Initial Surface Absorption Test (ISAT). At 28 days, GO-nanocomposite exhibited increased density (+14%), improved compressive and flexural strength (+29% and +13%, respectively), and decreased permeability compared to the control sample. The strengthening effect dominated over the adverse effects associated with the worsening of the fresh properties; reduced permeability was mainly attributed to the refining of the pore network induced by the presence of GO.

A novel method for approximating local changes in the surface absorption for laser marking using 3D laser scanning

Laser marking is a non-contact technique, which achieves colouring by using a laser beam to increase surface oxidation. Controlling the amount of heat induced into the part is essential in ensuring the desired degree of oxidisation. However, the induced heat is not only dependent on the process parameters, but also on the surface absorption, which in turn is dependent on the material, laser wavelength, and surface quality, i.e., current degree of oxidation and contaminants as well as surface roughness. This paper proposes a method for correlating backscatter from a 3D laser scanner with the surface absorption of sheet metal parts. The purpose is to determine local changes in the surface absorption caused by surface oxidation and contamination. The method utilises a 3D laser scanner, which projects a laser line at the surface and measures the resulting backscatter at an angle. The proposed solution applies a bi-directional reflectance model to reduce the influence of varying scanning angles. The method’s sensitivity to variations in surface treatments is investigated and validated against backscatter spectroscopy measurements. The results show that the proposed method can identify changes in the absorption. However, these were, in some cases, more than 70% higher compared to spectroscopy measurements.

Experimental Study of Single-Slope Solar Still Coupled With Nanofluid-Based Volumetric Absorption Solar Collector

In the present endeavor, a conventional single-slope solar still has been modified to improve its performance by coupling it with a novel nanofluid-based volumetric absorption solar collector (NBVASC). A low-cost and thermally stable nanofluid (prepared by dispersing functionalized carbon soot nanoparticles extracted from used engine oil into paraffin oil) having high solar weighted absorptivity has been employed to volumetrically absorb the incident solar energy. This additional absorbed solar energy is provided to the solar still by circulating a heat transfer fluid in a closed loop through serpentine type heat exchangers placed inside the NBVASC and the solar still. The experiments were performed from May to July 2020, and the results of the experiments conducted on May 25 and June 9, 2020, are reported. Extensive on-sun experiments reveal that coupling NBVASC to the conventional still could lead to substantial performance enhancements—distillate productivity, thermal efficiency, and night distillate improved by 75.3%, 66.9%, and 33.9%, respectively. More importantly, solar still coupled to NBVASC was found to perform better at an optimum nanoparticle concentration of 1.25 mlL−1 (20.75% higher distillate productivity) than the solar still coupled to a surface absorption-based collector (with paraffin oil as the working fluid)—truly establishing the benefits of volumetric absorption over surface absorption under the given set of conditions. Overall, the present study represents a noteworthy step forward in realizing efficient solar energy-driven desalination systems for remote underdeveloped areas.