State-of-Health of Li-ion Battery Estimation Based on the Efficiency of the Charge Transfer Extracted from Impedance Spectra

Several studies show that impedance spectroscopy is a suitable method for online battery diagnosis and State-of-Health (SoH) estimation. However, the most common method is to model the acquired impedance spectrum with equivalent circuits and focus on the most sensitive parameters, namely the charge-transfer resistance. This paper introduces first a detailed model of a battery cell, which is then simplified and adapted to the observable spectrum behavior. Based on the physical meaning of the model parameters, we propose a novel approach for SoH assessment combining parameters of the impedance spectrum by building the ratio of the solid electrolyte interphase (SEI) resistance to the total resistance of SEI and the charge transfer. This ratio characterizes the charge-transfer efficiency at the electrodes’ surfaces and should decrease systematically with SoH. Four different cells of the same type were cycled 400 times for the method validation, and impedance spectroscopy was performed at every 50th cycle. The results show a systematic correlation between the proposed ratio and the number of cycles on individual cell parameters, which build the basis of a novel online method of SoH assessment.

PtNi Alloy Coated in Porous Nitrogen-Doped Carbon as Highly Efficient Catalysts for Hydrogen Evolution Reactions

The development of low platinum loading hydrogen evolution reaction (HER) catalysts with high activity and stability is of great significance to the practical application of hydrogen energy. This paper reports a simple method to synthesize a highly efficient HER catalyst through coating a highly dispersed PtNi alloy on porous nitrogen-doped carbon (MNC) derived from the zeolite imidazolate skeleton. The catalyst is characterized and analyzed by physical characterization methods, such as XRD, SEM, TEM, BET, XPS, and LSV, EIS, it, v-t, etc. The optimized sample exhibits an overpotential of only 26 mV at a current density of 10 mA cm−2, outperforming commercial 20 wt% Pt/C (33 mV). The synthesized catalyst shows a relatively fast HER kinetics as evidenced by the small Tafel slope of 21.5 mV dec−1 due to the small charge transfer resistance, the alloying effect between Pt and Ni, and the interaction between PtNi alloy and carrier.

Mathematical Modelling of Glyphosate Molecularly Imprinted Polymer-Based Microsensor with Multiple Phenomena

The massive and careless use of glyphosate (GLY) in agricultural production raises many questions regarding environmental pollution and health risks, it is then important to develop simple methods to detect it. Electrochemical impedance spectroscopy (EIS) is an effective analytical tool for characterizing properties at the electrode/electrolyte interface. It is useful as an analytical procedure, but it can also help in the interpretation of the involved fundamental electrochemical and electronic processes. In this study, the impedance data obtained experimentally for a microsensor based on molecularly imprinted chitosan graft on 4-aminophenylacetic acid for the detection of glyphosate was analyzed using an exact mathematical model based on physical theories. The procedure for modeling experimental responses is well explained. The analysis of the observed impedance response leads to estimations of the microscopic parameters linked to the faradic and capacitive current. The interaction of glyphosate molecules with the imprinted sites of the CS-MIPs film is observed in the high frequency range. The relative variation of the charge transfer resistance is proportional to the log of the concentration of glyphosate. The capacitance decreases as the concentration of glyphosate increases, which is explained by the discharging of the charged imprinted sites when the glyphosate molecule interacts with the imprinted sites through electrostatic interactions. The phenomenon of adsorption of the ions in the CMA film is observed in the low frequency range, this phenomenon being balanced by the electrostatic interaction of glyphosate with the imprinted sites in the CS-MIPs film.

Performance Improvement of Gold Electrode towards Methanol Electrooxidation in Akaline Medium: Enhanced Current Density Achieved with Poly(aniline-co-2-hydroxyaniline) Coating at Low Overpotential

Electronically conducting poly (aniline-co-2-hydroxyaniline) (PACHA), a copolymer of aniline and 2-hydroxyaniline (2HA), was electrochemically coated on gold substrate for methanol electrooxidation in alkaline media. The electrochemical behavior of PACHA coated gold electrode towards methanol electrooxidation was investigated via cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) for application in an alkaline fuel cell. Methanol electrooxidation was observed at two different electrode potentials depending on the concentration of the base. At the PACHA coated gold electrode, the methanol oxidation peak was observed at lower overpotential (at 0.19 V) in a solution of high base concentration (1.8 M NaOH), which was 30 mV lower than the peak for the uncoated gold electrode. In addition, the Faradic current Imax obtained on the PACHA coated electrode (20 mA) was two times higher as compared to the Faradic current Imax of the un-modified gold electrode (10 mA). In solution of lower base concentration (0.06 M NaOH), the electrooxidation of methanol became sluggish on both electrodes, as indicated by peak shifting towards positive potential and with reduced faradaic current (at 0.74 V on PACHA coated electrode; Imax 10 mA). The electrooxidation of methanol at both lower and higher electrode potentials was analyzed mechanistically and discussed in light of the literature. EIS results were interpreted using Nyquist and Bode plots. The charge transfer resistance was decreased and pseudo-capacitive behavior changed to conductive behavior when external applied potential was increased from 0.1 V to 0.4 V.

A Low Cost Fe3O4–Activated Biochar Electrode Sensor by Resource Utilization of Excess Sludge for Detecting Tetrabromobisphenol A

Owing to its ubiquity in natural water systems and the high toxicity of its accumulation in the human body, it is essential to develop simple and low-cost electrochemical sensors for the determination of 3,3′,5,5′-tetrabromobisphenol A (TBBPA). In this work, Fe3O4–activated biochar, which is based on excess sludge, was prepared and characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) and BET analysis to analyze its basic features. Subsequently, it was used to fabricate an electrochemical sensor for the detection of TBBPA. The electrochemical test results revealed that the Fe3O4–activated biochar film exhibited a larger active surface area, a lower charge transfer resistance and a higher accumulation efficiency toward TBBPA. Consequently, the peak current of TBBPA was significantly enhanced on the surface of the Fe3O4–activated biochar. The TBBPA sensing platform developed using the Fe3O4–activated biochar composite film, with relatively a lower detection limit (3.2 nM) and a wider linear range (5–1000 nM), was successfully utilized to determine TBBPA levels in water samples. In summary, the effective application of Fe3O4–activated biochar provided eco-friendly and sustainable materials for the development of a desirable high-sensitivity sensor for TBBPA detection.

Comparative Analysis of the Use of Thermal Insulation Materials Depending on Climatic Conditions and Comfort Microclimate Supply Systems

The use of thermal insulation materials to reduce the heating and cooling demand of the building in order to provide energy efficiency is the main solution. But there is a wide range of these products on the market and, therefore, the choice and application of these materials is a rather difficult task, since many factors must be taken into account, such as environmental safety, cost, durability, climatic conditions, application technology, etc. Basically, comfort microclimate systems are designed based on normative standards, where the thickness of the thermal insulation material is selected depending on the required heat transfer resistance. These values are calculated taking into account climate conditions, that is the duration of the heating period, as well as taking into account sanitary and hygienic requirements. This article discusses the thermal performance of building materials, and also provides a comparative analysis of the use of thermal insulation materials depending on climatic factors and on the system providing comfort microclimate. Based on the calculations by mathematical modeling and optimization, it is advisable to choose the thickness of the thermal insulation, taking into account the capital and operating costs of the comfort microclimate systems. Comparing the optimization data with the normative one, the energy efficiency of the building increases by 50-70% when applying the optimal thickness of the thermal insulation layer, and when the thermal insulation layer is increased, the thermal performance of the enclosing structures has improved by 30%, which contributes to energy saving.

Review— A Review on the Anode and Cathode Materials for Lithium-Ion Batteries with Improved Subzero Temperature Performance

Lithium-ion batteries (LiBs) have been widely used in a variety of applications, however they still suffer from low capacity retention, large capacity fade ratio or inability to charge efficiently at low temperatures, especially below -20 oC. The reasons behind these drawbacks originate from the nature of active materials such as the anode and the cathode, along with the composition of electrolyte solutions. In particular, from the perspective of active materials, it has been reported that the most common problems arise from the dramatic increase in the resistances, especially charge transfer resistance, and the decrease of lithium-ion diffusivity, by more than one order of magnitude. In this report, we review the most recent strategies in the development of anode and cathode materials and composites, focusing on enhanced electronic and ionic conductivities for improved low-temperature electrochemical performance. Our overview aims to provide a comprehensive comparative study of the proposed methods to overcome the low-temperature challenges in order to develop high energy-density LiBs with enhanced capacity retention, cycling stability and high-rate capability under extreme conditions.

THE USE OF NANOTECHNOLOGY FOR THE DESIGN OF BUILDING STRUCTURES

Russia has a developed industry of building materials, which today implements an energy- and resource-saving model of its development. The implementation of the state policy of resource conservation is carried out in two main directions: the first direction is to save resources in the production of materials, the second is to increase the production of energy–efficient materials that allow saving energy carriers during their operation. Modern construc-tion in Russia is guided by European construction standards, which, in turn, provides for the construction of ener-gy-saving buildings with minimal energy consumption from external sources. This is ensured by the use of struc-tural and thermal insulation materials in the construction of external walls. In modern structural and thermal insu-lation materials for energy-saving construction, high requirements are imposed on their thermal properties, me-chanical strength and comfort level. From the point of view of simultaneous satisfaction of these requirements, ceramic materials have obvious advantages over other materials, in particular cellular concretes, which, with al-most the same level of thermal conductivity, are characterized by the least hygroscopicity and significantly greater strength. An objective prospect for the development of structural and thermal insulation ceramics is the production of hollow ceramic stones with increased thermal efficiency for their use in economical single-layer external wall structures without additional insulation. The products of individual Ukrainian manufacturers and even imported analogues of the most famous European manufacturer (Wiernerberger Company, Austria), when used in single-layer walls, do not provide regulatory requirements for the heat transfer resistance of masonry for the first temper-ature zone of Russia, which occupies the majority of the territory (60%). This requires the improvement of domes-tic products in the direction of improving their thermal characteristics (reducing thermal conductivity and increas-ing thermal resistance).

Modelling the Impedance Response of Graded LiFePO4 Cathodes for Li-Ion Batteries

Graded electrodes for Li-ion batteries aim to exploit controlled variations in local electrode microstructure to improve overall battery performance, including reduced degradation rates and increased capacity at high discharge rates. However, the mechanisms by which grading might deliver performance benefit, and under what conditions, are not yet fully understood. A Li-ion battery electrochemical model (a modified Doyle-Fuller-Newman type model capable of generating impedance functions) is developed in which local microstructural changes are captured in order to understand why and when graded electrodes can offer performance benefits. Model predictions are evaluated against experimental electrochemical impedance data obtained from electrodes with micro-scale, controlled variations in microstructure. A region locally enriched with carbon at the electrode/current collector interface is shown to significantly reduce the overpotential distribution across the thickness of a LiFePO$_4$-based Li-ion battery cathode, resulting in a lower charge transfer resistance and impedance. The insights gained from the LiFePO$_4$-based electrodes are generalised to wider design principles for both uniform and graded Li-ion battery electrodes.

Synthesis and Characterization of Zn–Organic Frameworks Containing Chitosan as a Low-Cost Inhibitor for Sulfuric-Acid-Induced Steel Corrosion: Practical and Computational Exploration

In this work, a Zn–benzenetricarboxylic acid (Zn@H3BTC) organic framework coated with a dispersed layer of chitosan (CH/Zn@H3BTC) was synthesized using a solvothermal approach. The synthesized CH/Zn@H3BTC was characterized by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM), thermal gravimetric analysis (TGA), and Brunauer, Emmett, and Teller (BET) surface area. The microscopic observation and the analysis of the BET surface area of CH/Zn@H3BTC nanocomposites indicated that chitosan plays an important role in controlling the surface morphology and surface properties of the Zn@H3BTC. The obtained findings showed that the surface area and particle size diameter were in the range of 80 m2 g−1 and 800 nm, respectively. The corrosion protection characteristics of the CH/Zn@H3BTC composite in comparison to pristine chitosan on duplex steel in 2.0 M H2SO4 medium determined by electrochemical (E vs. time, PDP, and EIS) approaches exhibited that the entire charge transfer resistance of the chitosan- and CH/Zn@H3BTC-composite-protected films on the duplex steel substrate was comparatively large, at 252.4 and 364.8 Ω cm2 with protection capacities of 94.1% and 97.8%, respectively, in comparison to the unprotected metal surface (Rp = 20.6 Ω cm2), indicating the films efficiently protected the metal from corrosion. After dipping the uninhabited and protected systems, the surface topographies of the duplex steel were inspected by FESEM. We found the adsorption of the CH/Zn@H3BTC composite on the metal interface obeys the model of the Langmuir isotherm. The CH/Zn@H3BTC composite revealed outstanding adsorption on the metal interface as established by MD simulations and DFT calculations. Consequently, we found that the designed CH/Zn@H3BTC composite shows potential as an applicant inhibitor for steel protection.