Effect of elevated tropospheric ozone on soil carbon and nitrogen: A meta-analysis

Elevated tropospheric ozone concentration ([O3]) may substantially influence the belowground processes of the terrestrial ecosystem. Nevertheless, a comprehensive and quantitative understanding of the responses of soil C and N dynamics to elevated [O3] remains elusive. In this study, the results of 41 peer-reviewed studies were synthesized using meta-analytic techniques, to quantify the impact of O3 on ten variables associated with soil C and N, i.e., total C (TC, including soil organic C), total N (TN), dissolved organic C (DOC), ammonia N (NH4 +), nitrate N (NO3 -), microbial biomass C (MBC) and N (MBN), rates of nitrification (NTF) and denitrification (DNF), as well as C/N ratio. The results depicted that all these variables showed significant changes (P < 0.05) with [O3] increased by 27.6 ± 18.7 nL/L (mean ± SD), including decreases in TC, DOC, TN, NH4 +, MBC, MBN and NTF, and increases in C/N, NO3 - and DNF. The effect sizes of TN, NTF, and DNF were significantly correlated with O3 fumigation level and experimental duration (P < 0.05). Soil pH and climate were essential in analyses of O3 impacts on soil C and N. However, the responses of most variables to elevated [O3] were generally independent of O3 fumigation method, terrestrial ecosystem type, and additional [CO2] exposure. The altered soil C and N dynamics under elevated [O3] may reduce its C sink capacity, and change soil N availability thus impact plant growth and enhance soil N losses.

Impact of Eastern and Central Pacific El Niño on Lower Tropospheric Ozone in China

Tropospheric ozone is an essential atmospheric component as it plays a significant role in influencing radiation equilibrium and ecological health. It is affected not only by anthropogenic activities but also by natural climate variabilities. Here we examine the tropospheric ozone change in China associated with the Eastern Pacific (EP) and Central Pacific (CP) El Niño using satellite observations from 2007 to 2017 and GEOS-Chem simulations from 1980 to 2017. GEOS-Chem simulations reasonably reproduce the satellite-retrieved lower tropospheric ozone (LTO) changes despite a slight underestimation. Results show that El Niño generally exerts negative impacts on LTO concentration in China, except for southeastern China during the pre-CP El Niño autumn and post-EP El Niño summer. The budget analysis further indicates that for both events, LTO changes are dominated by the transport process controlled by circulation patterns and the chemical process influenced by local meteorological anomalies associated with El Niño, especially the solar radiation and relative humidity changes. The differences between EP and CP-induced LTO changes mostly lie in southern China. The different strengths, positions, and duration of western North Pacific anomalous anticyclone (WNPAC) induced by tropical warming are likely responsible for the different EP and CP LTO changes. During the post-EP El Niño summer, the Indian ocean capacitor also plays an important role in controlling LTO changes over southern China.

Ozone variation over tropics: Trends revealed from Dobson measurement over Indian stations

. Variations in ozone amounts have been studied using data obtained with Dobson spectrophotometers during 1966-1988 at Srinagar, New Delhi, Pune and Kodaikanal. Yearly average values of total ozone , and its vertical distribution by the Umkehr method in layers 1 to 9 have been computed. Departures from compo- site avarage value for the period (1966-1988) have been computed for both total ozone and its vertical distribution. The variation over New Delhi and Pune have been compared with those at Arosa reported by Dutsch {1989). The observed variations in the ozone distribution at New Delhi and Pune can be explained, as being within normal interannual changes. Tropospheric ozone in layer lover New Delhi shows some effects of an anthropogenic nature, on the other hand Pune does not exhibit in any influence of pollutants in any layer, either in the troposphere or stratosphert.

Tropospheric ozone production and chemical regime analysis during the COVID-19 lockdown over Europe

The COVID-19 (Coronavirus disease 2019) European lockdowns have lead to a significant reduction in the emissions of primary pollutants such as NO (nitric oxide) and NO2 (nitrogen dioxide). As most photochemical processes are related to nitrogen oxide (NOx ≡ NO + NO2) chemistry, this event has presented an exceptional opportunity to investigate its effects on air quality and secondary pollutants, such as tropospheric ozone (O3). In this study, we present the effects of the COVID-19 lockdown on atmospheric trace gas concentrations, net ozone production rates (NOPR) and the dominant chemical regime throughout the troposphere based on three different research aircraft campaigns across Europe. These are the UTOPIHAN campaigns in 2003 and 2004, the HOOVER campaigns in 2006 and 2007 and the BLUESKY campaign in 2020, the latter performed during the COVID-19 lockdown. We present in situ observations and simulation results from the ECHAM5/MESSy Atmospheric Chemistry model which allows for scenario calculations with business as usual emissions during the BLUESKY campaign, referred to as "no-lockdown scenario". We show that the COVID-19 lockdown reduced NO and NO2 mixing ratios in the upper troposphere by around 55 % compared to the no-lockdown scenario due to reduced air traffic. O3 production and loss terms reflected this reduction with a deceleration in O3 cycling due to reduced mixing ratios of NOx while NOPRs were largely unaffected. We also study the role of methyl peroxyradicals forming HCHO (αCH3O2) to show that the COVID-19 lockdown shifted the chemistry in the upper troposphere/tropopause region to a NOx limited regime during BLUESKY. In comparison, we find a VOC limited regime to be dominant during UTOPIHAN.