Dual-Cation Electrolytes Crosslinked with MXene for High-Performance Electrochromic Devices

MXene, a 2D material, is used as a filler to manufacture polymer electrolytes with high ionic conductivity because of its unique sheet shape, large specific surface area and high aspect ratio. Because MXene has numerous -OH groups on its surface, it can cause dehydration and condensation reactions with poly(4-styrenesulfonic acid) (PSSA) and consequently create pathways for the conduction of cations. The movement of Grotthuss-type hydrogen ions along the cation-conduction pathway is promoted and a high ionic conductivity can be obtained. In addition, when electrolytes composed of a conventional acid or metal salt alone is applied to an electrochromic device (ECD), it does not bring out fast response time, high coloration efficiency and transmittance contrast simultaneously. Therefore, dual-cation electrolytes are designed for high-performance ECDs. Bis(trifluoromethylsulfonyl)amine lithium salt (LiTFSI) was used as a source of lithium ions and PSSA crosslinked with MXene was used as a source of protons. Dual-Cation electrolytes crosslinked with MXene was applied to an indium tin oxide-free, all-solution-processable ECD. The effect of applying the electrolyte to the device was verified in terms of response time, coloration efficiency and transmittance contrast. The ECD with a size of 5 × 5 cm2 showed a high transmittance contrast of 66.7%, fast response time (8 s/15 s) and high coloration efficiency of 340.6 cm2/C.

Increase in Fast Response Time of the Resistance-to-Voltage Converter When Monitoring the Cable Products’ Insulation Resistance

Theoretical and experimental studies were conducted to investigate the impact of the cable capacitance during measurements of insulation resistance on the fast response time of a resistance-to-voltage converter. From a comparison of the results of simulation with the data obtained during the experiments, it was determined that the dependence characteristics of the settling time of resistance under measurement on the capacitance are identical to the analogous characteristics of electronic components of the resistance-to-voltage converter. It was experimentally proven that using T-shaped feedback in the resistance-to-voltage converter during the cable insulation resistance measurements reduces the settling time of the data by 1–3 times in comparison with a classical feedback system. Furthermore, when using the optimal parameters, the settling time of the resistance-to-voltage converter with T-shaped feedback depends to a lesser degree on the capacitance of the object under control.

A regioregular donor–acceptor copolymer allowing a high gain–bandwidth product to be obtained in photomultiplication-type organic photodiodes

A newly synthesized regioregular donor polymer is used in photomultiplication-type organic photodiodes (PM-OPDs), and its regioregularity enables face-on orientation with a low trap density, leading to a high gain and fast response time in PM-OPDs.

Ultrasensitive and fast photoresponse in graphene/silicon-on-insulator hybrid structure by manipulating the photogating effect

The hybrid structures of graphene with semiconductor materials based on photogating effect have attracted extensive interest in recent years due to the ultrahigh responsivity. However, the responsivity (or gain) was increased at the expense of response time. In this paper, we devise a mechanism which can obtain an enhanced responsivity and fast response time simultaneously by manipulating the photogating effect (MPE). This concept is demonstrated by using a graphene/silicon-on-insulator (GSOI) hybrid structure. An ultrahigh responsivity of more than 107 A/W and a fast response time of 90 µs were obtained. The specific detectivity D* was measured to be 1.46 ⨯ 1013 Jones at a wavelength of 532 nm. The Silvaco TCAD modeling was carried out to explain the manipulation effect, which was further verified by the GSOI devices with different doping levels of graphene in the experiment. The proposed mechanism provides excellent guidance for modulating carrier distribution and transport, representing a new route to improve the performance of graphene/semiconductor hybrid photodetectors.