Design of Magnesia–Spinel Bricks for Improved Coating Adherence in Cement Rotary Kilns

It is well known that doloma bricks present better coating adherence than magnesia–spinel bricks when applied in cement rotary kilns, which is related to the different coating formation mechanism. The coating has an essential role in prolonged operation by protecting the refractory lining; thus, it is important to improve its adherence on magnesia–spinel refractories. The objective of this investigation is to study different compositions of magnesia–spinel bricks, achieved by varying additives used (calcined alumina, limestone, hematite and zirconia) and firing temperature (1500 °C and 1700 °C), to enhance the coating adherence measured by the sandwich test. The results have pointed out that the use of higher firing temperature contributes positively to physical adherence due to well-sintered refractory structure and elevated permeability, attaining coating strength superior to 2 MPa. For the chemical adherence, the addition of 2 wt.% of limestone increased the coating strength to 3 MPa, but resulted in a drop in hot properties. In this context, the most suitable approach to improve adherence of clinker coating and maintain hot properties in suitable levels is to increase the firing temperature.

Operation influence on structural and phase condition of 0.12C-1Cr-1Mo-1V-Fe steel

By the method of transmission electron diffraction microscopy the study of 0.12C-1Cr-1Mo-1V-Fe steel samples subjected to various long-term operation was conducted: 1) on the unfinished sample, 2) after prolonged operation without sample destruction, and 3) after prolonged operation brought to sample destruction. For each sample the phase composition was determined and the change in morphology of the structure was studied. It is established that operation of steel leads, firstly, to the destruction of plate pearlite and intensive ferrite fragmentation, secondly, to the redistribution of carbide component and, thirdly, to elastic distortion of the crystal lattice.