In this study, determination of droplets in the presence of blended mixture of surfactants (Span 80 and Tween 80) and nanoparticles, iron (III) oxide (Fe2O3) were investigated using a single stage mixer-settler extractor with 4-pitched flat blade impeller on one shaft employment. Additionally, the influence of Fe2O3 and blended surfactant mixture of Span 80 and Tween 80 on the dispersion of emulsion in terms of Sauter diameter (D32) measurement was compared with new correlations. Results indicate that the presence of Fe2O3 in the blended mixture of surfactant simultaneously decreased in D32 by 79 % and the stability of the emulsion system was enhanced. Overall, empirical correlation for droplet size at different conditions are obtained, and the modified correlation for D32 is presented. The correlation found is D32/DI =0.02265(3.419Φi−1)We-0.6. The calculated average absolute relative deviation (%AARD) is 2.69 %, thus indicating a good accuracy and acceptability between the presented correlation and experimental data.