Heat convection is one of the main mechanisms of heat transfer, and it involves both heat conduction and heat transportation by fluid flow; as a result, it usually requires numerical simulation for solving heat convection problems. Although the derivation of governing equations is not difficult, the solution process can be complicated and usually requires numerical discretization and iteration of differential equations. In this paper, based on neural networks, we developed a data-driven model for an extremely fast prediction of steady-state heat convection of a hot object with an arbitrary complex geometry in a two-dimensional space. According to the governing equations, the steady-state heat convection is dominated by convection and thermal diffusion terms; thus the distribution of the physical fields would exhibit stronger correlations between adjacent points. Therefore, the proposed neural network model uses convolutional neural network (CNN) layers as the encoder and deconvolutional neural network (DCNN) layers as the decoder. Compared with a fully connected (FC) network model, the CNN-based model is good for capturing and reconstructing the spatial relationships of low-rank feature spaces, such as edge intersections, parallelism, and symmetry. Furthermore, we applied the signed distance function (SDF) as the network input for representing the problem geometry, which contains more information compared with a binary image. For displaying the strong learning and generalization ability of the proposed network model, the training dataset only contains hot objects with simple geometries: triangles, quadrilaterals, pentagons, hexagons, and dodecagons, while the testing cases use arbitrary and complex geometries. According to the study, the trained network model can accurately predict the velocity and temperature field of the problems with complex geometries, which has never been seen by the network model during the model training; and the prediction speed is two orders faster than the CFD. The ability of accurate and extremely fast prediction of the network model suggests the potential of applying reduced-order network models to the applications of real-time control and fast optimization in the future.